Precipitation over sea: Validation against shipboard in-situ measurements

The satellite derived HOAPS (Hamburg Ocean Atmosphere Parameters and Fluxes from Satellite data) and ECMWF (European Centre for Medium-Range Weather Forecasts) ERA-Interim reanalysis data sets have been validated against in-situ precipitation measurements from ship rain gauges and optical disdrometers over the open-ocean by applying a statistical analysis for binary forecasts. For this purpose collocated pairs of data were merged within a certain temporal and spatial threshold into single events, according to the satellites' overpass, the observation and the forecast times. HOAPS detects the frequency of precipitation well, while ERA-Interim strongly overestimates it, especially in the tropics and subtropics. Although precipitation rates are difficult to compare because along-track point measurements are collocated with areal estimates and the numbers of available data are limited, we find that HOAPS underestimates precipitation rates, while ERA-Interim's Atlantic-wide average precipitation rate is close to measurements. However, regionally averaged over latitudinal belts, there are deviations between the observed mean precipitation rates and ERA-Interim. The most obvious ERA-Interim feature is an overestimation of precipitation in the area of the intertropical convergence zone and the southern sub-tropics over the Atlantic Ocean. For a limited number of snow measurements by optical disdrometers it can be concluded that both HOAPS and ERA-Interim are suitable to detect the occurrence of solid precipitation.

Downwelling spectral irradiance as measured in different depths, remote sensing reflectance and phytoplankton pigment concentration during POLARSTERN cruises ANT-XXIV/1, ANT-XXIV/4, ANT-XXVI/4 and Maria S. Merian cruise MSM18/3

The composition and abundance of algal pigments provide information on phytoplankton community characteristics such as photoacclimation, overall biomass and taxonomic composition. In particular, pigments play a major role in photoprotection and in the light-driven part of photosynthesis. Most phytoplankton pigments can be measured by high-performance liquid chromatography (HPLC) techniques applied to filtered water samples. This method, as well as other laboratory analyses, is time consuming and therefore limits the number of samples that can be processed in a given time. In order to receive information on phytoplankton pigment composition with a higher temporal and spatial resolution, we have developed a method to assess pigment concentrations from continuous optical measurements. The method applies an empirical orthogonal function (EOF) analysis to remote-sensing reflectance data derived from ship-based hyperspectral underwater radiometry and from multispectral satellite data (using the Medium Resolution Imaging Spectrometer - MERIS - Polymer product developed by Steinmetz et al., 2011, doi:10.1364/OE.19.009783) measured in the Atlantic Ocean. Subsequently we developed multiple linear regression models with measured (collocated) pigment concentrations as the response variable and EOF loadings as predictor variables. The model results show that surface concentrations of a suite of pigments and pigment groups can be well predicted from the ship-based reflectance measurements, even when only a multispectral resolution is chosen (i.e., eight bands, similar to those used by MERIS). Based on the MERIS reflectance data, concentrations of total and monovinyl chlorophyll a and the groups of photoprotective and photosynthetic carotenoids can be predicted with high quality. As a demonstration of the utility of the approach, the fitted model based on satellite reflectance data as input was applied to 1 month of MERIS Polymer data to predict the concentration of those pigment groups for the whole eastern tropical Atlantic area. Bootstrapping explorations of cross-validation error indicate that the method can produce reliable predictions with relatively small data sets (e.g., < 50 collocated values of reflectance and pigment concentration). The method allows for the derivation of time series from continuous reflectance data of various pigment groups at various regions, which can be used to study variability and change of phytoplankton composition and photophysiology.