(Table 1) Organic petrography and Rock-Eval pyrolysis at DSDP Hole 79-547B

A lenticle of organic matter in a piece of dolomite rock embedded in Triassic sandy mudstone of Core 547B-35 (DSDP Leg 79) was identified as inertinite-rich coal by organic petrography and analytical pyrolysis. About 95% of the organic matter recognized under the microscope consists of pyrofusinite, degradofusinite, and inertodetrinite. Gaseous hydrocarbons evolved during pyrolysis are rich in methane and are characteristic of inertinitic material. The organic matter is suggested to be a piece of redeposited Permian Gondwana coal.

(Table 1) Maceral composition and organic carbon chemistry of ODP Leg 104 samples

The Cenozoic sediments sampled in ODP Leg 104 on the Vøring Plateau show a distinct variability of the total organic carbon content (TOC) and the accumulation rates of TOC. Based on the geochemical and organic-petrographic characterization of the sedimentary organic matter (OM), the allochthonous and autochthonous proportion of the OM could be quantified. The results clearly demonstrate that high TOC percentages and TOC accumulation rates in Cenozoic sediment sections display a generally high input of allochthonous organic matter. Oxidized and partly well-rounded organic particles built up the main portion of OM within the Miocene, TOC-rich sediments. The most probable source of this oxidized OM are reworked sediments from the Scandinavian shelf. Changes in the input of these organic particles are to some degree correlative with sea-level changes. The Cenozoic accumulation of autochthonous OM is low and does not reveal a clear variation during the Miocene and early Pliocene. In spite of a high accumulation rate of biogenic opal during the Early Miocene, the accumulation rate of autochthonous TOC is low. The autochthonous particle assemblage is dominated by relatively inert OM, like dinoflagellate cysts. This points to an intensive biological and/or early diagenetic degradation of the marine OM under well oxidized bottom water conditions during the last 23 Myr. Nevertheless, a continuation of marine OM degradation during later stages of diagenesis cannot be excluded. A prominent dominance of allochthonous OM over autochthonous is documented with the beginning of the Pliocene. At 2.45 Ma the episodic occurrence of ice-rafted, thermally mature OM reflects the onset of the glacial erosion of Mesozoic, coal and black shale bearing sediments on the Scandinavian and Barents Sea shelves. The first occurrence of these, in view of the actual burial depth, thermally overmature OM particles is, therefore, a marker for the beginning of the strong Scandinavian glaciation and the advance of the glacial front toward the shelves.

Chemical characteristics of coal pebbles and Barzas-type coals

Coal pebbles found in 1994 in the Greham Bell Island (Franz Josef Land Archipelago) are made up of Barzas-type cuticular liptobiolith. The coal belongs to the initial stage of catagenesis and is characterized by high content of cutinite (up to 70%) with very low reflectance (Ro = 0.1%). Maceration products show some tegillate elements of Arthropoda and individual Devonian spores. It is supposed that plant cuticle and Arthropoda exocuticle are present in this coal. Obtained data suggest presence of Paleozoic rocks in the sedimentary sequence, although they are not yet recovered. These data complement available information on distribution of specific Devonian coals and allow to have a new insight into zoogenic material involved in coal formation.

Characteristics, pyrolysis, age, lithology, sedimentation rate, organic matter, and thermal alteration index at DSDP Leg 67 Holes

Marine-derived amorphous organic matter dominates hemipelagic and trench sediments in and around the Middle America Trench. These sediments contain, on the average, 1% to 2% total organic carbon (TOC), with a maximum of 4.8%. Their organic facies and richness reflect (1) the small land area of Guatemala, which contributes small amounts of higher land plant remains, and (2) high levels of marine productivity and regionally low levels of dissolved oxygen, which encourage deposition and preservation of marine organic remains. These sediments have good potential for oil but are now immature. For this reason, gaseous hydrocarbons like the ethane identified in the deep parts of the section, as at Sites 496 and 497, are probably migrating from a mature section at depth. The pelagic sediments of the downgoing Cocos Plate are lean in organic carbon and have no petroleum potential

Organic geochemistry of Cretaceous black shales at DSDP Hole 75-530A

Five-hundred ten meters of Cretaceous sediments were drilled north of the Walvis escarpment in Hole 530A during Leg 75. An immature stage of evolution for organic matter can be assigned to all the samples studied. Black shales are interbedded with red and green claystone in the bottom sedimentary unit, Unit 8, which is of Coniacian to late Albian age. The richest organic carbon contents and petroleum potentials occur in the black shales. Detrital organic matter is present throughout the various members of a sequence, mixed with largely oxidized organic matter in the gray and green claystone or marlstone members on both sides. Detrital organic matter also characterizes the black streaks observed in the claystones. Vertical discontinuities in organic matter distribution are assigned to slumping. Several types of black shales can be identified, according to their content of detrital organic matter, the more detrital black levels corresponding to the Albian-Cenomanian period. Cyclic variations of organic matter observed for a sequence can occur for a set of sequences and even for some consecutive sets of sequences. Climatic factors are proposed to account for the cyclic sedimentation and distribution of organic matter for every sequence that includes a black bed.

Low-molecular-weight hydrocarbon concentrations, organic carbon contents, and Rock-Eval pyrolysis hydrogen indices at DSDP Holes 75-530A and 75-532

A series of C2-C8 hydrocarbons (including saturated, aromatic, and olefinic compounds) from deep-frozen core samples taken during DSDP Leg 75 (Holes 530A and 532) were analyzed by a combined hydrogen-stripping/thermovaporization method. Concentrations representing both hydrocarbons dissolved in the pore water and adsorbed on the mineral surfaces vary in Hole 530A from about 10 to 15,000 ng/g of dry sediment weight depending on the lithology (organic-carbon-lean calcareous oozes versus "black shales"). Likewise, the organic-carbon-normalized C2-C8 hydrocarbon concentrations vary from 3,500 to 93,100 ng/g Corg, reflecting drastic differences in the hydrogen contents and hence the hydrocarbon potential of the kerogens. The highest concentrations measured of nearly 10**5 ng/g Corg are about two orders of magnitude below those usually encountered in Type-II kerogen-bearing source beds in the main phase of petroleum generation. Therefore, it was concluded that Hole 530A sediments, even at 1100 m depth, are in an early stage of evolution. The corresponding data from Hole 532 indicated lower amounts (3,000-9,000 ng/g Corg), which is in accordance with the shallow burial depth and immaturity of these Pliocene/late Miocene sediments. Significant changes in the light hydrocarbon composition with depth were attributed either to changes in kerogen type or to maturity related effects. Redistribution pheonomena, possibly the result of diffusion, were recognized only sporadically in Hole 530A, where several organic-carbon lean samples were enriched by migrated gaseous hydrocarbons. The core samples from Hole 530A were found to be severely contaminated by large quantities of acetone, which is routinely used as a solvent during sampling procedures on board Glomar Challenger.

Analysis of macerals in sediment core 159-959C

Organic petrologic and geochemical analyses were performed on modern and Quaternary organic carbon-poor deep sea sediments from the Equatorial Atlantic. The study area covers depositional settings from the West African margin (ODP Site 959) through the Equatorial Divergence (ODP Site 663) to the pelagic Equatorial Atlantic. Response of organic matter (OM) deposition to Quaternary climatic cycles is discussed for ODP Sites 959 and 663. The results are finally compared to a concept established for fossil deep sea environments [Littke and Sachsenhofer, 1994 doi:10.1021/ef00048a041]. Organic geochemical results obtained from Equatorial Atlantic deep sea deposits provide new aspects on the distribution of sedimentary OM in response to continental distance, atmospheric and oceanographic circulation, and depositional processes controlling sedimentation under modern and past glacial-interglacial conditions. The inventory of macerals in deep sea deposits is limited due to mechanical breakdown of particles, degree of oxidation, and selective remineralization of labile (mostly marine) OM. Nevertheless, organic petrology has a great potential for paleoenvironmental studies, especially as a proxy to assess quantitative information on the relative abundance of marine vs. terrigenous OM. Discrepancies between quantitative data obtained from microscopic and isotopic (delta13Corg) analyses were observed depending on the stratigraphic level and depositional setting. Strongest offset between both records was found close to the continent and during glacial periods, suggesting a coupling with wind-born terrigenous OM from central Africa. Since African dust source areas are covered by C4 grass plants, supply of isotopically heavy OM is assumed to have caused the difference between microscopic and isotopic records.

Carbonate, organic carbon, pyrolysis and composition of the extracts at DSDP Holes 76-534A and 44-391

The geochemical studies of Sites 534 and 391 and their comparison allow us to improve the chemical characterization of different geological formations dating from the early Callovian to the Maestrichtian along the continental margin of eastern North America. Three of the formations are favorable for the preservation of organic matter: (1) the unnamed formation (middle Callovian to Oxfordian), (2) the Blake-Bahama Formation (Berriasian to Barremian), and (3) the Hatteras Formation (Aptian to Cenomanian). The organic matter is mainly detrital, except for a few organic-rich layers where a contribution of aquatic material occurs. In these organic-rich layers, the petroleum potential is medium to good. Maturation has not quite reached the beginning of the oil window even for the deepest organic material.

Calcium carbonate, isotopes and Rock-Eval pyrolysis at DSDP Holes 77-535 and 77-540

At DSDP Sites 534 (Central Atlantic) and 535 and 540 (Gulf of Mexico), and in the Vocontian Basin (France), Lower Cretaceous deposits show a very pronounced alternation of limestone and marl. This rhythm characterizes the pelagic background sedimentation and is independent of detritic intercalations related to contour and turbidity currents. Bed-scale cycles, estimated to be 6000-26,000 yr. long, comprise major and minor units. Their biological and mineralogic components, burrowing, heavy isotopes C and O, and some geochemical indicators, vary in close correlation with CaCO3 content. Vertical changes of frequency and asymmetry of the cycles are connected with fluctuations of the sedimentation rate. Plots of cycle thickness ("cyclograms") permit detailed correlations of the three areas and improve the stratigraphic subdivision of Neocomian deposits at the DSDP sites. Small-scale alternations, only observed in DSDP cores, comprise centimetric to millimetric banding and millimetric to micrometric lamination, here interpreted as varvelike alternations between laminae that are rich in calcareous plankton and others rich in clay. The laminations are estimated to correspond to cycles approximately 1,3, and 13 yr. in duration. The cyclic patterns appear to be governed by an interplay of continental and oceanic processes. Oceanic controls express themselves in variations of the biogenic carbonate flux, which depends on variations of such elements as temperature, oxygenation, salinity, and nutrient content. Continental controls modulate the influxes of terrigenous material, organic matter, and nutrients derived from cyclic erosion on land. Among the possible causes of cyclic sedimentation, episodic carbonate dissolution has been ruled out in favor of climatic fluctuations with a large range of periods. Such fluctuations are consistent with the great geographic extension shown by alternation controls and with the continuous spectrum of scales that characterizes limestone-marl cycles. The climatic variations induced by the Earth's orbital parameters (Milankovitch cycles) could be connected to bed-interbed alternations.

Organic facies of Cenozoic and Cretaceous sediments at DSDP Leg 80 Holes

The organic facies of Cenozoic sediments cored at DSDP Sites 548-551 along the Celtic Sea margin of the northern North Atlantic (Goban Spur) is dominated by terrestrially derived plant remains and charcoal. Similar organic facies also occur in the Lower and Upper Cretaceous sections at these sites. Mid-Cretaceous (uppermost Albian-Turonian) sediments at Sites 549-551, however, record two different periods of enrichment in organic material, wherein marine organic matter was mixed with terrestrial components. The earlier period is represented only in the uppermost Albianmiddle Cenomanian section at the most seaward site, 550. Here, dark laminated marly chalks rich in organic matter occur rhythmically interbedded with light-colored, bioturbated marly chalks poor in organic matter, suggesting that bottom waters alternated between oxidizing and reducing conditions. A later period of enrichment in organic material is recorded in the upper Cenomanian-Turonian sections at Sites 549 and 551 as a single, laminated black mudstone interval containing biogenic siliceous debris. It was deposited along the margin during a time of oxygen deficiency associated with upwelling-induced intensification and expansion of the mid-water oxygen-minimum layer. In both the earlier and later events, variations in productivity appear to have been the immediate cause of oxygen depletion in the bottom waters.

Geochemistry and pyrolysis at DSDP Hole 77-535

There are substantial differences in the character of organic matter contained in the Pleistocene and Cretaceous sedimentary sequences of DSDP Site 535. The argillaceous Pleistocene section contains type III, gas-prone organic matter whereas the calcareous Cretaceous section is dominated by type II, oil-prone organic matter. A more detailed investigation of the Cretaceous section reveals that the finely laminated limestones of Valanginian to Barremian age are of good to excellent source quality. The indigenous organic matter contained within this organically rich section is thermally immature, not having undergone sufficient thermal diagenesis for the generation and expulsion of hydrocarbons. Within this stratigraphic section, however, staining by mature hydrocarbons was detected. These stains are associated with a fractured interval. These fractures may in turn represent potential migration pathways.

Organic facies variations in the Mesozoic South Atlantic DSDP Holes

Visual kerogen and total organic carbon determinations indicate that there are two periods of organic enrichment events in the Mesozoic sediments of the South Atlantic. The first period, from the Late Jurassic through the late Aptian, is recorded in sediments from the Falkland Plateau, the Cape Basin, and the Angola Basin. Apparently, salinity stratification in the restricted basin, coupled with rising sea level, led to bottom water anoxia and organic enrichment. The second event, from the late Albian to the Santonian period, is recorded in sediments from the Angola Basin and the Sao Paulo Plateau. It appears to have been caused by development of an anoxic oxygen minimum zone at midwater depths. Organic matter sedimentation in the Mesozoic South Atlantic is controlled by geologic, climatic, eustatic, and Oceanographic factors.