Abundance patterns and isotopic signals of morphotypes of Globigerinoides ruber

The chemical composition of shells of the planktonic foraminifer Globigerinoides ruber (white) is frequently used to determine past sea surface conditions. Recently, it has been shown that arbitrarily defined morphotypes within this species exhibit different chemical and isotopic signatures. Here, we investigate the occurrence through time and in space of morphological types of G. ruber (white) in late Quaternary and Holocene sediments of the central and the eastern Mediterranean Sea. In 115 samples representing two distinct time intervals (MIS 1-2 and MIS 9-12) at ODP Site 964 and the piston core GeoTü-SL96, we have defined three morphological types within this species and determined their relative abundances and stable isotopic composition. A quantitative analysis of morphological variation within G. ruber (white) in four samples revealed that the subjectively defined morphotypes occupy separate segments of a continuous and homogenous morphospace. We further show that the abundance of the morphotypes changes significantly between glacials and interglacials and that the three morphotypes of G. ruber show significant offsets in their stable isotopic composition. These offsets are consistent within glacial and interglacial stages but their sign is systematically reversed between the two Sites. Since the isotopic shifts among the three G. ruber morphotypes are systematic and often exceed 1per mil, their understanding is essential for the interpretation of all G. ruber-based proxy records for the paleoceanographic development of the Mediterranean during the late Quaternary.

(Table 1) Abundance of tunicate spicules along the Great Barrier Reef-Queensland Plateau transect

The abundance patterns of tunicate spicules are documented for the Pliocene-Pleistocene sediments at seven sites along the Great Barrier Reef-Queensland Plateau transect. The spatial distribution pattern indicates that tunicate spicules were limited to waters shallower than 900 m. The occurrences of tunicate spicules at Sites 822 and 823 that are deeper than 900 m are ascribed to downslope transport, and their distribution patterns can be used to monitor downslope transport processes. The first common occurrence of tunicate spicules at Sites 822 and 823 around 1.6 Ma may suggest the initiation of the central Great Barrier Reef at this time. The morphology of tunicate spicules varies greatly and appears to be gradational among different forms. Older tunicate assemblages are less diverse than those in younger sediments, presumably because of diagenesis. Tunicate spicules do not appear to be a promising biostratigraphic tool for the Pliocene-Pleistocene.

Early and Middle Miocene calcareous nannofossil distribution in the North Atlantic Ocean

Deep Sea Drilling Project Site 563, located on the west flank of the northern Mid-Atlantic Ridge, recovered a long Miocene section from which magnetostratigraphic and isotopic stratigraphy are available. Quantitative analyses of calcareous nannofossil assemblages have been performed in the Lower and Middle Miocene sediments from Site 563. The abundance patterns of the identified species allow us to determine several bioevents for this time interval. The recognized biohorizons, related to the available magnetostratigraphy, provide new data on the biostratigraphic value of many species and on the synchroneity of the events over a wide geographic area. Relations with the oxygen isotope stratigraphy are also reported. Sphenolith distribution is examined in particular detail due to their biostratigraphic importance in the Early Miocene. In particular the recently described species Sphenolithus procerus, Sphenolithus tintinnabulum and Sphenolithus multispinatus can be useful to subdivide the Lower Miocene zones NN2 and NN3. A large variety of Reticulofenestra pseudoumbilicus has been identified within zones NN6 and NN7.

Calcareous nannofossils and planktic foraminiferal assemblages of ODP Hole 198-1210A

Calcareous nannofossil and planktic foraminiferal assemblages from ODP Hole 1210A in the northwestern Pacific Ocean were used to reconstruct surface-water conditions for the past 500 kyr. Stratigraphic control was provided by calcareous nannofossil events that are thought to be synchronous over a broad range of latitudes. Calcareous nannofossil and planktic foraminiferal assemblages and abundance patterns indicate the unlikelihood of long term (Milankovitch-scale) latitudinal shifts of the Kuroshio Extension over the last 500 kyr and illustrate two successive surface water-mass states, one that prevailed prior to 300 ka and one that existed after 300 ka. The relative abundance of very small placoliths and the absolute abundance of the upper photic zone (UPZ) coccolith species decrease abruptly at approximately 300 ka. The relative abundance of the lower photic zone (LPZ) species Florisphaera profunda greatly increases at the same time, although intervals during which the relative abundance of this taxon is very low or absent also occur prior to 300 ka. The absolute abundance of planktic foraminifera gradually increased after the 300-ka boundary, including peaks of Globoconella inflata. These assemblage and abundance changes suggest significant modifications to the surface water-mass structure. Surface water was weakly stratified prior to 300 ka, but alternated between intensely stratified and vertically mixed after 300 ka. Changes in the surface water-mass structure suggest an intensification of the East Asian summer and winter monsoon after 300 ka.

Eocene-Oligocene calcareous nannofossils from ODP sites 115-711 and 120-748 in the Indian Ocean

An Eocene-Oligocene calcareous nannofossil biostratigraphic framework for Ocean Drilling Program (ODP) Site 748 in the southern Indian Ocean is established, which provides a foundation for this and future quantitative biogeographic studies. This biostratigraphic analysis, together with quantitative nannofossil data, enables a reinterpretation of the preliminary magnetostratigraphy and a new placement for magnetic Subchron CBN in the lowermost Oligocene. Calcareous nannofossil species diversity is low at Site 748 relative to lower latitude sites, with about 13 taxa in the middle Eocene, gradually decreasing to about 6 in the late Oligocene. There is, however, no apparent mass extinction at any stratigraphic level. Similarly, no mass extinctions were recorded at or near the Eocene/Oligocene boundary at Site 711 in the equatorial Indian Ocean. Species diversity at the equatorial site is significantly higher than at Site 748, with a maximum of 39 species in the middle Eocene and a minimum of 14 species in the late Oligocene. The abundance patterns of nannofossil taxa are also quite different at the two sites, with chiasmoliths, Isthmolithus recurvus, and Reticulofenestra daviesii abundant and restricted to the high-latitude site and Coccolithus formosus, discoasters, and sphenoliths abundant at the equatorial site but impoverished at the high-latitude site. This indicates a significant latitudinal biogeographic gradient between the equatorial site and the high-latitude site in the Indian Ocean for the middle Eocene-Oligocene interval. The abundance change of warm-water taxa is similar to that of species diversity at Site 711. There is a general trend of decreasing abundance of warm-water taxa from the middle Eocene through the early Oligocene at Site 711, suggesting a gradual cooling of the surface waters in the equatorial Indian Ocean. The abundance of warm-water taxa increased in the late Oligocene, in association with an increase in species diversity, and this may reflect a warming of the surface waters in the late Oligocene. An abrupt increase in the abundance of cool-water taxa (from ~20% to over 90%) occurred from 36.3 to 35.9 Ma at high-latitude Site 748. Coincident with this event was a ~1.0 per mil positive shift in the delta18O value of planktonic foraminifers and the occurrence of ice-rafted debris. This abrupt change in the nannofossil population is a useful biostratigraphic event for locating the bottom of magnetic Subchron C13N in the Southern Ocean. The sharp increase in cool-water taxa coeval with a large positive shift in delta18O values suggests that the high-latitude surface waters drastically cooled around 36.3-35.9 Ma. The temperature drop is estimated to be 4°C or more at Site 748 based on the nannofossil population change relative to the latitudinal biogeographic gradient established in the South Atlantic Ocean during previous studies. Consequently, much of the delta18O increase at Site 748 appears to be due to a temperature drop in the high latitudes rather than an ice-volume signal. The ~0.1 per mil delta18O increase not accounted for by the temperature drop is attributed to an ice-volume increase of 4.6 * 10**3 km**3, or 20% the size of the present Antarctic ice sheet.

Eocene-Oligocene calcareous nannofossil events of ODP Sites from the Southern Ocean

The evolution of the Southern Ocean climate during the late Eocene-late Oligocene interval is examined through highresolution, quantitative calcareous nannofossil analyses on samples from the Southern Ocean sections on Maud Rise and Kerguelen Plateau. We determined the abundance patterns of the counted species to clarify the biostratigraphy, which we correlated with high-resolution magnetostratigraphy [Roberts, A.P., Bicknell, S.J., Byatt, J., Bohaty, S.M., Florindo, F., Harwood, D.M., 2003a. Magnetostratigraphic calibration of Southern Ocean diatom datums from the Eocene-Oligocene of Kerguelen Plateau (Ocean Drilling Program Sites 744 and 748). In: Florindo, F., Cooper, A.K., O'Brien, P.A. (Eds.), Antarctic Cenozoic Palaeoenvironments: Geologic Record and Models. Palaeogeogr., Palaeoclimatol., Palaeoecol. 198 145-168; Florindo, F., Roberts, A.P., in press. Eocene-Oligocene magnetobiochronology of ODP Sites 689 and 690, Maud Rise, Weddell Sea, Antarctica. Geol. Soc. Am. Bull.], and used this data to interpret paleoceanographic changes through the late Eocene to late Oligocene. Percentage plots of the individual species, compared with R-mode principal component and cluster analysis results, allowed us to divide the assemblages into three groups: temperate-water taxa, cool-water taxa, and no temperature-affinity taxa. We attempt correlations between these paleoecological groups and the major sea-surface temperature (SST) variations with tectonic and paleoceanographic changes in the Southern Ocean. During the late Eocene, the nannofossil assemblage data reveal that there were several minor SST decreases (coolings) from 36 to 34 Ma, before the Eocene/Oligocene (E/O) boundary. A sharp cooling event, dated at 33.54 Ma (earliest Oligocene), occurred about 160 kyr after the E/O boundary, which is dated at 33.7 Ma. Relatively stable, cool conditions are interpreted to persist until the latest Oligocene, when an increase in abundance of temperate-water taxa, which corresponds to an antithetical decrease in abundance of cool-water indicators, is recorded. On the basis of our dating, the opening of the Drake Passage, allowing shallow-water circulation, began by 33.54 Ma at the latest, while the establishment of deep-water connections through the Tasmanian Gateway occurred at 33 Ma, as suggested by Exon et al. [Proc. ODP, Init. Rep. 189 (2001) 1].

Age estimates of Discoaster datums and corresponding isotope stages (Table 2)

High-resolution records (2 7 kyr) of Upper Pliocene Discoaster abundances obtained from six ODP/DSDP sites are assessed independently using oxygen isotope stratigraphy. Four Atlantic Ocean sites (DSDP Sites 552 and 607, and ODP Sites 659 and 662) comprise a transect from 56°N to 1°S and provide a record of latitudinal variations in Diseoaster biogeography. Low-latitude sites in the Atlantic (ODP Site 662), Pacific (ODP Site 677), and Indian (ODP Site 709) oceans provide additional information about variability in Discoaster abundance patterns within the equatorial region. A common chronology, based on the astronomical time scale developed for ODP Site 677, has been established for all the sites. By integrating oxygen isotope data and Discoaster abundance records at each site we are able to independently evaluate the temporal and spatial distribution of D. brouweri and D. triradiatus in the 500 kyr prior to the extinction of the discoasters near the base of the Olduvai subchron. Major decreases in abundance are evident during some of the more intense late Pliocene glacial events. In particular, glacial isotope stages 82, 96, 98 and 100 are associated with distinct abundance minima. At these times, large-scale changes in surface hydrographic conditions appear to have suppressed Discoaster numbers on a global scale. The increase in abundance of D. triradiatus, which precedes the extinction of the discoasters by around 200 kyr, may also be related to the intensification of environmental pressures that accompanied the build-up of Northern Hemisphere ice sheets during the late Pliocene. In spite of contrasting geographic and oceanographic settings, the various D. brouweri and D. triradiatus records are remarkably similar. This demonstrates that the acme and extinction events are excellent biostratigraphic datums. The simultaneous extinction of D. brouweri and D. triradiatus at 1.95 Ma were synchronous events at both a regional scale within the Atlantic, and on a global scale between the three major oceans. However, the start of the D. triradiatus acme appears to have been diachronous, occurring some 40 kyr earlier in the Atlantic than in the Indo-Pacific, and hence the stratigraphic usefulness of this datum is regional rather than global.

Carbonat-free sediment components of ODP Leg 115 holes

From the equatorial Indian Ocean, carbonate-free portions of sediment samples of Paleocene to Miocene calcareous oozes and chalks from Sites 707, 709, and 711 were studied using X-ray diffraction measurements and the scanning electron microscope. Downhole variations in biogenic opal, quartz, barite, and clinoptilolite were investigated. The abundance patterns of these major mineral phases show several similarities and may be used for additional lithologic correlations. Variations in biogenic opal contents reflect biogenic silica productivity. Beside the general pattern, a succession in biogenic silica decrease through time is generally recorded since the Oligocene. This succession started earliest at northernmost Site 711 and latest at southernmost Site 707, including Site 709 within these two. Opal-A variations as well as the barite distribution may be influenced by the paleoposition of the sites in relation to the high-productivity zone, which today lies south of the equator. Authigenic clinoptilolite apparently formed in two different modes. In deeper sediment intervals, clinoptilolite was the last mineral phase formed associated with enhanced silica diagenesis. In late Oligocene to middle Miocene sediments, clinoptilolite was the only authigenic silica phase encountered where otherwise strong opal dissolution was observed. The sponge spicules showed special dissolution features probably related to microbiological activity. Silica concretions mainly composed of opal-CT and authigenic quartz occur in carbonate-rich environments and are formed during later diagenesis when burial depth causes the sediments to reach higher temperatures. Opal-CT concretions in carbonate-free siliceous oozes were found at Site 711 and are probably formed during an early stage of silica diagenesis.

Paleocene and Eocene nannofossil datums from Shatsky Rise and Walvis Ridge

The precision of late Paleocene to middle Eocene nannofossil datums is investigated by means of quantitative methods and correlated to the magnetic polarity stratigraphy, using sequences from the Northwest Pacific, Southeast Atlantic and Italy. It is the rule rather than the exception to find tails of very reduced abundances prior to, or after, a range of consistent and higher abundances. The absolutely first or final occurrence of a species, therefore, seldom provides a synchronous datum when material from different geographic areas are compared. On the other band, synchroneity is often confirmed when the initial sharp rise or the final sharp decline in abundance is used as datum level. The use of datums not employed in the two principal existing nannofossil zonal schemes can substantially improve the biostratigraphic resolution. Two established zonal markers show abundance patterns making them unsuitable as datums: the first occurrences of Ellipsolithus macellus (base NP4, diachronous) and Tribrachiatus nunnii (base NP10 and Paleocene/Eocene boundary, too rare and too short range in open ocean sections). The first occurrence of either Fasciculithus spp. or Sphenolithus spp. is a better marker near the base of NP4. The first occurrence of Discoaster diastypus at 56.6 Ma represents a suitable replacement for recognition of the Paleocene/Eocene boundary.

Geochemistry of ODP Hole 135-839B lavas

Four petrographic lava types occur, ranging from aphyric to moderately phyric clinopyroxene-olivine tholeiitic basalts (Unit 1); olivine-clinopyroxene picritic basalts, sparsely to strongly olivine-phyric (Unit 3-type); olivine-clinopyroxene basalts (clinopyroxene dominant) (Unit 4); and moderately to strongly phyric two-pyroxene-plagioclase basaltic andesites (Unit 9-type). The olivine phyric lavas contain forsteritic olivines (extending to Fo92), and very magnesian Cr-rich spinels similar to those occurring in boninitic lavas. The basaltic andesites are mineralogically and petrographically indistinguishable from the modern Tofua Arc basaltic andesites, one notable feature being the highly calcic cores in plagioclase phenocrysts (up to An95). The forsteritic olivines, the Cr-spinels, and the calcic plagioclases are unlikely to have been precipitated in the lava compositions in which they occur, and are thought to have been incorporated from highly primitive melts by way of mixing processes (as advocated by Allan, this volume). Notwithstanding the evidence for mixing, the major element chemistries of the Unit 1- and Unit 9-type lavas are shown to be consistent with the derivation of the Unit 9-type basaltic andesites by means of fractional crystallization, through magmas of similar chemistry to Unit 1. Some trace element discrepancies in the modeling, and the relative volcanic stratigraphy of Site 839, however, preclude a direct liquid line of descent between the actual recovered units. Trace element data as well as TiO2 and Na2O data clearly illustrate the arc-like affinities of the magmas, with strong highfield-strength element depletion and large-ion-lithophile element enrichment. The abundance patterns are very close to those of the Tofua and Kermadec arc magmas, and also Valu Fa. Pb-, Sr-, and Nd-isotopic compositions indicate closest affinities with a "Pacific" MORB source, apparently characteristic of the western, older part of the Lau Basin. A subduction-related isotopic contribution is, however, inferred. The sources of the Site 839 magmas are thus inferred to be similar to, but less depleted geochemically, than those of the modern Tofua Arc magmas. The Site 839 sequence is interpreted as an older remnant of a volcanic construct of the "proto-Tofua arc", originally developed adjacent to the Tonga Ridge. Opening of the eastern Lau Basin, because of southward migrating propagators, has split and isolated the sequence, leaving it stranded within the modern Lau Basin.