Hydrographic measurements from C.S.S. Hudson Cruise 82-002, Canadian Technical Report of Hydrography and Ocean Sciences No. 118, 112 pp (digital version)

This archive consists of the hydrographic data collected on Cruise 82-002 of C.S.S. Hudson, April 11 to May 2, 1982. 78 stations were occupied on a line running near 48°N from the mouth of the English Channel to the Grand Banks of Newfoundland. Pressure, temperature and salinity were measured by a Guildline digital CTP system. Salinity, dissolved oxygen, silicate, nitrate and phosphate were measured from water samples collected on the CTP upcasts. CTP and discrete bottle data and associated derived parameters are tabulated at standard levels. This is the digital version of the printed report (of 1989, see further details), published in 2006 with the information system Pangaea.

Concentrations of natural and anthropogenic organohalogens in water and air samples in the Canadian Arctic during IPY (2007-2008)

Shipboard measurements of organohalogen compounds in air and surface seawater were conducted in the Canadian Arctic in 2007-2008. Study areas included the Labrador Sea, Hudson Bay, and the southern Beaufort Sea. High volume air samples were collected at deck level (6 m), while low volume samples were taken at 1 and 15 m above the water or ice surface. Water samples were taken within 7 m. Water concentration ranges (pg/L) were as follows: alpha-hexachlorocyclohexane (alpha-HCH) 465-1013, gamma-HCH 150-254, hexachlorobenzene (HCB) 4.0-6.4, 2,4-dibromoanisole (DBA) 8.5-38, and 2,4,6-tribromoanisole (TBA) 4.7-163. Air concentration ranges (pg/m**3) were as follows: alpha-HCH 7.5-48, gamma-HCH 2.1-7.7, HCB 48-71, DBA 4.8-25, and TBA 6.4-39. Fugacity gradients predicted net deposition of HCB in all areas, while exchange directions varied for the other chemicals by season and locations. Net evasion of alpha-HCH from Hudson Bay and the Beaufort Sea during open water conditions was shown by air concentrations that averaged 14% higher at 1 m than 15 m. No significant difference between the two heights was found over ice cover. The alpha-HCH in air over the Beaufort Sea was racemic in winter (mean enantiomer fraction, EF = 0.504 ± 0.008) and nonracemic in late spring-early summer (mean EF = 0.476 ± 0.010). This decrease in EF was accompanied by a rise in air concentrations due to volatilization of nonracemic alpha-HCH from surface water (EF = 0.457 ± 0.019). Fluxes of chemicals during the southern Beaufort Sea open water season (i.e., Leg 9) were estimated using the Whitman two-film model, where volatilization fluxes are positive and deposition fluxes are negative. The means ± SD (and ranges) of net fluxes (ng/m**2/d) were as follows: alpha-HCH 6.8 ± 3.2 (2.7-13), gamma-HCH 0.76 ± 0.40 (0.26-1.4), HCB -9.6 ± 2.7 (-6.1 to -15), DBA 1.2 ± 0.69 (0.04-2.0), and TBA 0.46 ± 1.1 ng/m**2/d (-1.6 to 2.0).

Chemical and isotopic composition of seawater and waters from thermal spring sites of the Yankicha Island and Kraternaya Bay

A study of chemical and isotopic composition of coastal thermal springs and waters of the Kraternaya Bay, Yankicha Island, revealed that the total mineralization and concentrations of d18O and d2H decrease from the thermal spring site I to V. These waters are of marine origin with various proportions of local meteoric water. Thermal waters of the site VI have considerably altered chemical and isotopic composition due to high temperatures of surrounding rocks. Base temperatures calculated for this area were 130-200°C. Coastal thermal springs affect isotopic composition of water throughout the bay.

Annotated record of the detailed examination of Mn and phosphate deposits from GOS74 Expedition stations

The purpose of the cruise was to map the manganese rich pavements of the Blake Plateau area which had been extensively investigated by ships of the Woods Hole Oceanographic Institution since 1956. From August until September 1965, 112 sites were sampled from R/V Gosnold on a joint USGS-WHOI expedition. At most of the stations on the Blake pavement, large slabs of manganese were recovered along with phosphate rich nodules.

Chemical and mineral compositions of hydrothermal sulfide deposits from the Lucky Strike hydrothermal field, Mid-Atlantic Ridge

Several hydrothermal sulfide structures were sampled using the Mir manned submersibles in the relatively shallow Lucky Strike vent field, Mid-Atlantic Ridge. Bathymetric position of these structures varies by approximately 100 m. Investigation of chemical and mineral compositions of hydrothermal ore occurrences led to the conclusion that the initial high-temperature ore-bearing solution ascending toward the surface became unstable and experienced phase separation beneath the ocean floor. The phase separation was responsible for bathymetric control of hydrothermal ore formation within the field.