Age models of sediment cores from the Southern Ocean

Recent geochemical models invoke ocean alkalinity changes, particularly in the surface Southern Ocean, to explain glacial age pCO2 reduction. In such models, alkalinity increases in glacial periods are driven by reductions in North Atlantic Deep Water (NADW) supply, which lead to increases in deep-water nutrients and dissolution of carbonate sediments, and to increased alkalinity of Circumpolar Deep Water upwelling in the surface Southern Ocean. We use cores from the Southeast Indian Ridge and from the deep Cape Basin in the South Atlantic to show that carbonate dissolution was enhanced during glacial stages in areas now bathed by Circumpolar Deep Water. This suggests that deep Southern Ocean carbonate ion concentrations were lower in glacial stages than in interglacials, rather than higher as suggested by the polar alkalinity model [Broecker and Peng, 1989, doi:10.1029/GB001i001p00015]. Our observations show that changes in Southern Ocean CaCO3 preservation are coherent with changes in the relative flux of NADW, suggesting that Southern Ocean carbonate chemistry is closely linked to changes in deepwater circulation. The pattern of enhanced dissolution in glacials is consistent with a reduction in the supply of nutrient-depleted water (NADW) to the Southern Ocean and with an increase of nutrients in deep water masses. Carbonate mass accumulation rates on the Southeast Indian Ridge (3200-3800 m), and in relatively shallow cores (<3000 m) from the Kerguelen Plateau and the South Pacific were significantly reduced during glacial stages, by about 50%. The reduced carbonate mass accumulation rates and enhanced dissolution during glacials may be partly due to decreases in CaCO3:Corg flux ratios, acting as another mechanism which would raise the alkalinity of Southern Ocean surface waters. The polar alkalinity model assumes that the ratio of organic carbon to carbonate production on surface alkalinity is constant. Even if overall productivity in the Southern Ocean were held constant, a decrease in the CaCO3:Corg ratio would result in increased alkalinity and reduced pCO2 in Southern Ocean surface waters during glacials. This ecologically driven surface alkalinity change may enhance deepwater-mediated changes in alkalinity, and amplify rapid changes in pCO2.

(Table 1) Distribution of ichthyolith subtypes at DSDP Hole 62-464

At Site 464, a 308-meter-deep hole was drilled on the Hess Rise (39°51.64'N, 173°53.33'E; water depth 4637 m). The upper strata consist of siliceous clay and oozes of Pleistocene, Pliocene, and possibly latest Miocene ages (36 m) and the lower strata are Albian chert, chalk, and marlstone (219 m). The middle part of the stratigraphic section is pelagic brown clay (53 m) which is essentially barren of microfossils except for ichthyoliths. At the base of this middle unit in Core 10 is a recrystallized Cretaceous radiolarian assemblage and an impoverished late Miocene nannofossil assemblage. Fifteen samples from Cores 6 through 10 in the middle unit and three samples from the overlying siliceous clay were examined for ichthyoliths.

Planktonic foraminiferal flux in the Subantarctic

Sediment trap moorings deployed during 1997 and 1998 in the Subantarctic to Polar Frontal regions of the Southern Ocean reveal distinct seasonality in foraminiferal flux. Foraminiferal assemblages vary between each site, yet major species exhibit very similar patterns of seasonal succession which can be associated with changes in mixed layer depth. Enhanced foraminiferal productivity is also associated with periods of high biogenic silica and particulate organic carbon flux. On a broader scale, foraminiferal assemblages are strongly delineated by temperature. Temperature estimates derived from the assemblages using the modern analog technique (MAT) are mostly within 2.5°C of the satellite advanced very high resolution radiometer temperatures observed during the deployment period. This indicates that core top sediments included in the MAT database do reflect modern observed conditions at the sea surface, providing a robust technique for estimating past temperature change from foraminiferal assemblages in Southern Ocean environments.

Pliocene foraminifera and SST changes in ODP Site 184-1125

Planktonic foraminiferal census counts were converted to sea surface temperature (SST) estimates using the modern analogue technique (MAT) for the middle-late Pliocene (4.0-2.37 Ma) in ODP Site 1125, north side of Chatham Rise, SW Pacific Ocean. MAT SST(warm) records range between 8°C and 20.5°C, and MAT SST(cold) records parallel that pattern but with a temperature range of 5-15°C. The modern position of Site 1125 is just north of the Subtropical Front and has an annual temperature range of ~14-18°C. Pliocene warmest temperatures are 1-2° warmer than modern summers, whereas cold season SST records are up to 6-10°C cooler than modern winters. Overall average temperatures at the site are 2-3°C cooler than modern temperatures during a time of sustained global warmth. Three major cold excursions centred on 3.35, 3.0, and 2.8 Ma showed warm season temperatures over 5°C colder than the last glacial maximum, experiencing temperatures typical of modern subantarctic waters. Two minor cold excursions at 2.7 Ma and 2.4 Ma experienced temperatures cooler than modern winters but not as cold as last glacial conditions. Cold season SSTs show a shift to warmer climate upward through the study interval, whereas warm season estimates remain essentially unchanged. We interpret the strong regional cooling of subtropical Southwest Pacific water through the middle-late Pliocene as having been caused by increased upwelling. It is also possible that the subtropical frontal zone moved north over the site in the Pliocene, however, this is considered the least likely interpretation. Our record of cool conditions in the Southwest Pacific corroborate evidence of cooler than modern conditions in other regions of the western Pacific through the mid-Pliocene despite overall global warming.

Preliminary ichthyolith biostratigraphy and age profiles at DSDP Sites 91-595 and 91-596

Seventy meters of Cenozoic and Mesozoic pelagic clay cored at DSDP Sites 595 and 596 provide the basis for a preliminary analysis of ichthyolith biostratigraphy in the southwest Pacific. A most likely order of the more reliable ichthyolith events is compared with a synthesis of ichthyolith biostratigraphy in the North Pacific and with dated composite ranges. The resultant preliminary ichthyolith stratigraphy suggests that the Cenozoic is represented by the upper 20 m at Site 596 and 16 to 22 m at Site 595. Mixing of taxa precludes a clear recognition of the Cretaceous/Tertiary boundary at Site 595. The occurrence of 13 newly described subtypes is recorded in Mesozoic sediments at Sites 595 and 596. These new subtypes and previously described Mesozoic forms may be useful for recognizing Mesozoic subdivisions when their occurrences in sequences dated by other microfossils are investigated.

Radiolarians from ODP Leg 134 sites

In the cores obtained during Leg 134 of the Ocean Drilling Program, radiolarians occur intermittently and usually in a poor state of preservation, apparently as a result of the region having been at or near the boundary between the equatorial current system and the south-central Pacific water mass during most of the Cenozoic. A few well-preserved assemblages provide a record of the Quaternary forms, and some displaced middle and lower Eocene clasts preserve a record of radiolarians near that subepochal boundary. There are less satisfactory records of middle Miocene and early Miocene to late Oligocene forms.

Salinity and SO4 and Br enrichment of seawater and frost flowers near Barrow, Alaska

Frost flowers have been proposed to be the major source of sea-salt aerosol to the atmosphere during polar winter and a source of reactive bromine during polar springtime. However little is known about their bulk chemical composition or microstructure, two important factors that may affect their ability to produce aerosols and provide chemically reactive surfaces for exchange with the atmosphere. Therefore, we chemically analyzed 28 samples of frost flowers and parts of frost flowers collected from sea ice off of northern Alaska. Our results support the proposed mechanism for frost flower growth that suggests water vapor deposition forms an ice skeleton that wicks brine present on newly grown sea ice. We measured a high variability in sulfate enrichment factors (with respect to chloride) in frost flowers and seawater from the vicinity of freezing sea ice. The variability in sulfate indicates that mirabilite precipitation (Na2SO4 x 10 H2O) occurs during frost flower growth. Brine wicked up by frost flowers is typically sulfate depleted, in agreement with the theory that frost flowers are related to sulfate-depleted aerosol observed in Antarctica. The bromide enrichment factors we measured in frost flowers are within error of seawater composition, constraining the direct reactive losses of bromide from frost flowers. We combined the chemical composition measurements with temperature observations to create a conceptual model of possible scenarios for frost flower microstructure development.