Radiosonde profiles and meteorological observations during Atlantic Expedition M2 in 1965 (IQSY) of RV "Meteor"

A radiosonde is described for measuring the upward and downward fluxes of visible light in the atmosphere. Photoresistors are used as sensors, the optical center of the spectral range beeing at 0.55 µ. The results of these flux-measurements obtained during the Atlantic Expedition 1965 with the research vessel "Meteor" are presented. The datas have been divided into three groups according to the amount of cloudiness. In group a) (small cloudiness) the extinction coefficient of the prevailing linear radiation is derived as a function of the height. Characteristics of airmasses of maritime or continental origin are shown. In group b) (cloud covered sky) microphysical quantities are determined from the radiative lapse rate in the clouds. The average radius of droplets is found to lie between 5.5 µm and 14.4 µm. The albedo of cloud surfaces varies between 25% and 54%, the transmission values are between 58% and 73%. One ascent through a Cirrus cloud of considerable vertical thickness is treated seperately. The observed distribution of extinction is compared with theoretical values in water clouds leading to the same order of magnitude. The relation between the albedo of the surface of the sea and the amount of cloudiness is discussed.

An approach for particle sinking velocity measurements in the 3-400 µm size range and considerations on the effect of temperature on sinking rates

The flux of organic particles below the mixed layer is one major pathway of carbon from the surface into the deep ocean. The magnitude of this export flux depends on two major processes-remineralization rates and sinking velocities. Here, we present an efficient method to measure sinking velocities of particles in the size range from approximately 3-400 µm by means of video microscopy (FlowCAM®). The method allows rapid measurement and automated analysis of mixed samples and was tested with polystyrene beads, different phytoplankton species, and sediment trap material. Sinking velocities of polystyrene beads were close to theoretical values calculated from Stokes' Law. Sinking velocities of the investigated phytoplankton species were in reasonable agreement with published literature values and sinking velocities of material collected in sediment trap increased with particle size. Temperature had a strong effect on sinking velocities due to its influence on seawater viscosity and density. An increase in 9 °C led to a measured increase in sinking velocities of 40 %. According to this temperature effect, an average temperature increase in 2 °C as projected for the sea surface by the end of this century could increase sinking velocities by about 6 % which might have feedbacks on carbon export into the deep ocean.

Heat flow values in the Sea of Okhotsk region

Tectonic structure and anomalous distributions of geophysical fields of the Sea of Okhotsk region are considered; the lack of reliable data on age of the lithosphere beneath basins of various origin in the Sea of Okhotsk is noted. Model calculations based on geological and geophysical data yielded 65 Ma (Cretaceous-Paleocene boundary) age for the Central Okhotsk rise underlain by the continental lithosphere. This estimate agrees with the age (the end of Cretaceous) derived from seismostratigraphic data. A comparative analysis of theoretical and measured heat flows in the Akademii Nauk Rise, underlain by the thinned continental crust, is performed. The analysis points to a higher (by 20%) value of the measured thermal background of the rise, which is consistent with high negative gradient of gravity anomalies in this area. Calculations yielded 36 Ma (Early Oligocene) age and lithosphere thickness of 50 km for the South Okhotsk depression, whose seafloor was formed by processes of back-arc spreading. The estimated age of the depression is supported by kinematic data on the region; the calculated thickness of the lithosphere coincides with the value estimated from data of magnetotelluric sounding here. This indicates that formation time (36 Ma) of the South Okhotsk depression was estimated correctly. Numerical modeling performed for determination of the basement age of rifting basins in the Sea of Okhotsk gave the following estimates: 18 Ma (Early Miocene) for the Deryugin Basin, 12 Ma (Middle Miocene) for the TINRO Basin, and 23 Ma (Late Oligocene) for the West Kamchatka Trough. These estimates agree with formation time (Oligocene-Quaternary) of the sedimentary cover in rifting basins of the Sea of Okhotsk derived from geological and geophysical data. Model temperature estimates are obtained for lithologic and stratigraphic boundaries of the sedimentary cover in the Deryugin and TINRO Basins and the West Kamchatka Trough; the temperature analysis indicates that the latter two structures are promising for oil and hydrocarbon gas generation; the West Kamchatka Trough possesses better reservoir properties compared to the TINRO and Deryugin Basins. The latter is promising for generation of hydrocarbon gas. Paleogeodynamic reconstructions of the Sea of Okhotsk region evolution are obtained for times of 90, 66, and 36 Ma on the base of kinematic, geomagnetic, structural, tectonic, geothermal, and other geological and geophysical data.

(Table 1) Determined and theoretical chemical composition of thaumasite of ODP Hole 135-841B

Hole 841B was drilled in the forearc region of the Lau Basin at a water depth of 4810 m. The hole penetrated a roughly 500-m-thick series of Miocene volcanic sediments with a number of basaltic to andesitic units (sills?) varying in thickness between 7 cm and 17 m. The volcanics are slightly to moderately altered and contain analcite, chabazite, natrolite-thompsonite, heulandite (?), prehnite, and quartz as secondary phases. In addition, thaumasite [Ca3Si(OH)6 * 12H2O](SO4)(CO3) was identified in the altered sequence. Sulfur isotope data of two thaumasite separates (+23.5 per mil and +21.1 per mil d34S) indicate a seawater origin of the sulfate sulfur. It is suggested that thaumasite is a product of low-temperature (<60 °C), seawater-derived CaCl2-rich fluids that were almost identical in composition to those presently circulating in the sub-seafloor.

Geochemical analyses and Delta47 values in shallow water corals

Geochemical variations in shallow water corals provide a valuable archive of paleoclimatic information. However, biological effects can complicate the interpretation of these proxies, forcing their application to rely on empirical calibrations. Carbonate clumped isotope thermometry (Delta47) is a novel paleotemperature proxy based on the temperature dependent "clumping" of 13C-18O bonds. Similar ?47-temperature relationships in inorganically precipitated calcite and a suite of biogenic carbonates provide evidence that carbonate clumped isotope variability may record absolute temperature without a biological influence. However, large departures from expected values in the winter growth of a hermatypic coral provided early evidence for possible Delta47 vital effects. Here, we present the first systematic survey of Delta47 in shallow water corals. Sub-annual Red Sea Delta47 in two Porites corals shows a temperature dependence similar to inorganic precipitation experiments, but with a systematic offset toward higher Delta47 values that consistently underestimate temperature by ~8 °C. Additional analyses of Porites, Siderastrea, Astrangia and Caryophyllia corals argue against a number of potential mechanisms as the leading cause for this apparent Delta47 vital effect including: salinity, organic matter contamination, alteration during sampling, the presence or absence of symbionts, and interlaboratory differences in analytical protocols. However, intra- and inter-coral comparisons suggest that the deviation from expected Delta47 increases with calcification rate. Theoretical calculations suggest this apparent link with calcification rate is inconsistent with pH-dependent changes in dissolved inorganic carbon speciation and with kinetic effects associated with CO2 diffusion into the calcifying space. However, the link with calcification rate may be related to fractionation during the hydration/hydroxylation of CO2 within the calcifying space. Although the vital effects we describe will complicate the interpretation of Delta47 as a paleothermometer in shallow water corals, it may still be a valuable paleoclimate proxy, particularly when applied as part of a multi-proxy approach.