Mineralogic, elemental, and stable isotopic composition of bulk carbonate sediments from ODP Leg 166 sites

An intensive mineralogic and geochemical investigation was conducted on sediments recovered during Ocean Drilling Program Leg 166 from the western Great Bahama Bank at Sites 1006, 1008, and 1009. Pleistocene through middle Miocene sediments recovered from Site 1006, the distal location on the Leg 166 transect, are a mixture of bank-derived and pelagic carbonates with lesser and varying amounts of siliciclastic clays. A thick sequence of Pleistocene periplatform carbonates was recovered near the platform edge at Sites 1008 and 1009. Detailed bulk mineralogic, elemental (Ca, Mg, Sr, and Na), and stable isotopic (d18O and d13C) analyses of sediments are presented from a total of 317 samples from all three sites.

Cretaceous-Paleogene biomagnetostratigraphy of ODP Leg 121 sites

Broken Ridge, in the eastern Indian Ocean, is a shallow-water volcanic platform which formed during the Early to middle Cretaceous at which time it comprised the northern portion of the Kerguelen-Heard Plateau. Rifting during the middle Eocene and subsequent seafloor spreading has moved Broken Ridge about 20?N to its present location. The sedimentary section of Broken Ridge includes Turonian-lower Eocene limestone and chalk with volcanic ash, an interval of detrital sands and gravels associated with middle Eocene rifting and uplift, and a middle-late Oligocene unconformity overlain by a thin section of Neogene-Holocene pelagic calcareous ooze. This paper summarizes the available post-cruise biostratigraphic and magnetostratigraphic data for the Cretaceous-Paleogene section on Broken Ridge. The synthesis of this information permits a more precise interpretation of the timing of events in the history of Broken Ridge, in particular the timing and duration of the middle Eocene rifting event. Paleontologic data support rapid flexural uplift of Broken Ridge in response to mechanical rather than thermal forces. Other highlights of the section include a complete Cretaceous/Tertiary boundary and an opportunity for first-order correlation of Paleogene diatom stratigraphy with that of the calcareous groups.

Late Eocene larger foraminifera and other fossils of ODP Leg 115 holes

Shallow-water larger foraminifers have been recovered at two drill sites on the eastern Maldive Ridge. Despite the poor recovery in Hole 715A, a rather diversified larger benthic foraminifer assemblage allowed us to date the initiation of a carbonate platform, resting on volcanic basement, as late early Eocene. Several age-diagnostic species belonging to the genera Alveolina, Nummulites, Orbitolites, and Discocyclina have been identified. The assemblages may be attributable to the upper part of the Nummulites burdigalensis cantabricus Zone and/or to the lower part of the Nummulites campesinus Zone and to the Alveolina dainellii (upper part) and/or to the A. violae (lower part) zones. The carbonate platform had a very short life (a few hundred thousand years) and rapidly sank below the euphotic zone, as testified by the occurrence of several species of planktonic foraminifers associated with redeposited reef-derived skeletal debris, especially discocyclinids, in the upper part of the sequence. Among the planktonic foraminifers, the presence of Planorotalites palmeri, which has a range confined to the lower portion of the late early Eocene Zone P9, implies that the platform was drowned before the end of the early Eocene. At Hole 714A, the occurrence of several shallow-water foraminifer genera, such as Nummulites (N. fabianii gr.), Discocyclina, Fabiania, Heterostegina, and Operculina (O. gomezi), in pebbles derived from turbidite beds interbedded within late Oligocene pelagic sediments, allows us to suggest that a carbonate platform, possibly reduced in size, was still growing in the Maldive Ridge area after the late early Eocene time. The erosional event, responsible for the redeposition of middle to late Eocene reef-derived skeletal debris, is apparently coeval with the global sea-level fall recorded in late Oligocene Zone P22.

Primary mineralogy of ODP Leg 115 basalts

Basement rocks were recovered at four sites on Leg 115 along the Reunion hotspot track in the western Indian Ocean. Plate tectonic reconstructions indicate that the drilled structures formed in three different volcanic environments. Sites 706 and 713 from the eastern side of the Saya de Malha Bank and the northern end of the Chagos Bank, respectively, are on a large volcanic platform analogous to Iceland on the Mid-Atlantic Ridge. Lavas at Site 707 on the northwestern side of the Saya de Malha Bank erupted during the early stages of rifting of the Seychelles from India. Basalts from Site 715 were erupted onto an isolated oceanic island that was distant from ocean ridges and continents much as Reunion Island is today. Many of the rocks were examined in thin section and found to be primarily augite-plagioclase basalts with minor olivine and rare opaque oxides. Site 715 is unusual in that it contains a variety of basalts including olivine-rich and aphyric Fe-Ti basalts. At each of the four sites the rocks were grouped into chemical types (units) on the basis of ship- board bulk-rock analyses and at least one thin section from each chemical unit was analyzed by electron microprobe. The plagioclase and augite chemistry reflects the bulk-rock chemistry and, in general, these minerals were in equilibrium with their host magmas at the time the basalts were quenched. Olivine was rarely preserved, but where it is still present it also appears to have crystallized in equilibrium with the host magma. At three of the drill sites plagioclase phenocrysts or megacrysts that crystallized from a primitive magma are also present. The one site (715) that does not contain these primitive plagioclase phenocrysts is also the site that appears to have been influenced the least by ocean- ridge or Deccan-type magmas. Site 715, furthermore, has a mineralogy that is dominated by olivine as compared with the plagioclase-rich lavas of the other sites.

Interstitial water d13C and sediment geochemistry of ODP Leg 166 sites

A review of interstitial water samples collected from Sites 1003-1007 of the Bahamas Transect along with a shore-based analysis of oxygen and carbon isotopes, minor and trace elements, and sediment chemistry are presented. Results indicate that the pore-fluid profiles in the upper 100 meters below seafloor (mbsf) are marked by shifts between 20 and 40 mbsf that are thought to be caused by changes in sediment reactivity, sedimentation rates, and the influence of strong bottom currents that have been active since the late Pliocene. Pore-fluid profiles in the lower Pliocene-Miocene sequences are dominated by diffusion and do not show significant evidence of subsurface advective flow. Deeper interstitial waters are believed to be the in situ fluids that have evolved through interaction with sediments and diffusion. Pore-fluid chemistry is strongly influenced by carbonate recrystallization processes. Increases in pore-fluid Cl- and Na+ with depth are interpreted to result mainly from carbonate remineralization reactions that are most active near the platform margin. A lateral gradient in detrital clay content observed along the transect, leads to an overall lower carbonate reactivity, and enhances preservation of metastable aragonite further away from the platform margin. Later stage burial diagenesis occurs at slow rates and is limited by the supply of reactive elements through diffusion.

Miozene larger foraminifera in ODP Leg 133 holes

The Marion Plateau is a large carbonate platform off northeastern Queensland. Three sites (815, 816, and 826) were drilled on this platform and form the basis for this study. Larger benthic foraminifers, together with rare planktonic forms from the shallow-water carbonates that form the main part of the platform sequence, were studied to establish a biostratigraphy. The presence of Lepidocyclina (Nephrolepidiná) howchini sensu lato and Ladoronia vermicularis, together with Globorotalia (Globorotalia) praemenardii and Orbulina, indicate an early middle Miocene (N9-N12) age (i.e., lower Tf stage) for these carbonates. Dolomitization has destroyed much of the original fabric of these carbonates, making study of the larger foraminifers difficult. Sites 815 (forereef location) and 826 (backreef, lagoonal setting) provide the best faunas. However, at all sites nodular coralline algae and Halimeda are the major bioclasts; coral fragments form a major component at Sites 816 and 826. The middle Miocene neritic sequence is separated from the overlying hemipelagic sequence by an unconformity that spans much of the middle and late Miocene. At Site 815, which is in a forereef situation, the overlying hemipelagic sequence contains a Zone N17A fauna, but at Site 816, higher on the platform, a similar sequence contains a Zone N19 fauna. The faunas indicate that the platform was built up during the early middle Miocene and remained at fairly constant water depths and temperatures during this period. It was then exposed prior to subsiding rapidly during the late Miocene and Pliocene to depths similar to those of the present day.

Paleogene and Neogene larger foraminifera of ODP Leg 133 holes

At several sites drilled during Ocean Drilling Program (ODP) Leg 133 on the Queensland Plateau, larger shallow-water benthic foraminifers have been recovered from neritic carbonates and from turbidites that consist of shallow-water-derived material. Within neritic sediments, the occurrence of different faunal associations provides a tool for biostratigraphic subdivision. Three main phases of neritic deposition occurred on the Queensland Plateau. An Eocene episode is characterized by subtropical to temperate associations (Operculina-Nummulites Facies). It is unconformably followed by a late Oligocene to middle Miocene episode that contains tropical to subtropical associations (Spiroclypeus Facies, Larger Foraminifer-Coral Facies, Austrotrillina Facies, Flosculinella-Amphistegina Facies, Marginopora Facies, and Miogypsina Facies). After the middle Miocene, most of the Queensland Plateau carbonate platform was drowned. The post-middle Miocene to Holocene reefs, which are characterized by a geographically more restricted distribution, shed neritic material including larger benthic foraminifers into adjacent basinal areas. This process is associated with a partial reworking of middle Miocene deposits containing Lepidocyclina (Nephrolepidina).

Stable oxygen isotope ratios of pore waters from ODP Leg 166 sites

This study investigates the d18O of pore waters from Sites 1003 through 1007, drilled along the western margin of the Great Bahama Bank during Leg 166 of the Ocean Drilling Program. These pore waters generally show a positive correlation between d18O and the concentration of chloride. The exception to this trend is Site 1006, where the pore waters exhibit nonlinear behavior with respect to chloride. The correlation between the concentration of Cl- and d18O at most of the sites appears to be a coincidence because although the increase in Cl- is a result of diffusion from an underlying source, the increases in d18O result from the recrystallization of metastable carbonates in the presence of a geothermal gradient. The difference in behavior in the d18O of the pore water at Site 1006 is probably a result of the relative reduced rate of carbonate recrystallization at this site. The d18O of the pore waters in the upper portion of the cores shows a pattern similar to the concentration of chloride in that there is an interval of 30-50 m in which neither the d18O nor the concentration of Cl- changes. This interval is consistent with either an interval of very rapid deposition of sediment or the advection of fluid through the platform. Both the d18O and the concentration of Cl- increase toward the platform, suggesting an input of saline and isotopically heavy water from the platform surface.

Miocene to Pleistocene planktonic foraminifer biostratigraphy of ODP Leg 135 sites

Diverse and well-preserved planktonic foraminifers were recovered from six sites (834-839) drilled in the Lau Basin. Planktonic faunas from the Tongan Platform sites varied from those of the Lau Basin sites by being less well preserved (Site 840) to being very poorly preserved and very sparse (Site 841); at Site 841 most samples were barren. All sites penetrated a volcaniclastic sequence in which thick ash beds were encountered; foraminifer populations within the ash beds were often very small, making it difficult to obtain biostratigraphic data. No hiatuses were encountered in the upper Miocene to Pleistocene sections of the Lau Basin, but a possible break occurs at Site 840 on the Tongan Platform. Site 834 penetrated through a Quaternary-Pliocene sequence overlying basaltic basement, and topmost Miocene (Zone N17B) sediments interbedded within the volcanic sequence. Site 835 penetrated into the lower Pliocene (Zones N19 to N19-20). Site 836 penetrated the shortest section, with Zone N22 {Globorotalia (Truncorotalia) crassaformis hessi Subzone) directly overlying basalts. Site 837 penetrated into the basal part of Zone N22 (Globigerinoides quadrilobatus fistulosus Subzone) overlying basalt. Site 838 failed to encounter basalts, with the oldest sediment being from Zone N22 (Globigerinoides quadrilobatus fistulosus Subzone). Site 839, within the same basin as Site 838, located Zone N22 (Globigerinoides quadrilobatus fistulosus Subzone) sediments directly overlying igneous basement. Site 840 penetrated into the upper Miocene Zone N17A without encountering any major unconformity. Site 841, studied mainly from core-catcher samples, penetrated a Quaternary to questionable upper Miocene sequence that was in fault contact with middle Miocene (Zones N8 to N9) sediments. For the Lau Basin sites, reworking was encountered only in Sites 834 and 835. Site 834 was drilled adjacent to the Lau Ridge, on which are developed numerous reef al and shallow-water environments, where erosional conditions could have been expected during sea-level lowstands. Site 835 was drilled in a narrow basin that has been remote from these erosional influences; slumping and erosion of material from the adjacent basin slopes appears to have been the source of the reworking. For the Tongan Platform sites, reworking was observed only in the lower part of the upper Miocene section at Site 841, where late Eocene larger foraminifers are present in conglomerates and grits. The presence of Globorotalia (Globorotalia) multicamerata and small specimens of Sphaeroidinellopsis spp. in the Pleistocene of Site 840 may indicate reworking, but this is not clear. Unit I, which marks a reduction in volcanic activity in the Lau Basin, ranges in age from the lower part of Zone N22 (Globigerinoides quadrilobatus fistulosus Subzone) at Sites 834 and 835, to within Zone N22 (Globorotalia crassaformis hessi Subzone) at Sites 836 to 838, and within the upper part of Zone N22 (Bolliella praeadamsi Subzone) at Site 839. Units II and III are generally represented by thick to very thick ash beds, which generally contain low-diversity and often poorly preserved assemblages. Igneous sources seem to have remained important contributors of sediment up to the present day.

Geochemistry at DSDP Leg 82 Holes

The nine holes (556-564) drilled during DSDP Leg 82 in a region west and southwest of the Azores Platform (Fig. 1) exhibit a wide variety of chemical compositions that indicate a complex petrogenetic history involving crystal fractionation, magma mixing, complex melting, and mantle heterogeneity. The major element chemistry of each hole except Hole 557 is typical of mid-ocean ridge basalts (MORBs), whereas the trace element and rare earth element (REE) abundances and ratios are more variable, and show that both depleted Type I and enriched Type II basalts have been erupted in the region. Hole 556 (30-34 Ma), located near a flow line through the Azores Triple Junction, contains typically depleted basalts, whereas Hole 557 (18 Ma), located near the same flow line but closer to the Azores Platform, is a highly enriched FeTi basalt, indicating that the Azores hot-spot anomaly has existed in its present configuration for at least 18 Ma, but less than 30-34 Ma. Hole 558 (34-37 Ma), located near a flow line through the FAMOUS and Leg 37 sites, includes both Type I and II basalts. Although the differences in Zr/Nb and light REE/heavy REE ratios imply different mantle sources, the (La/Ce)ch (>1) and Nd isotopic ratios are almost the same, suggesting that the complex melting and pervasive, small-scale mantle heterogeneity may account for the variations in trace element and REE ratios observed in Hole 558 (and FAMOUS sites). Farther south, Hole 559 (34-37 Ma), contains enriched Type II basalts, whereas Hole 561 (14-17 Ma), located further east near the same flow line, contains Type I and II basalts. In this case, the (La/Ce)ch and Nd isotopic ratios are different, indicating two distinct mantle sources. Again, the existence along the same flow line of two holes exhibiting such different chemistry suggests that mantle heterogeneity may exist on a more pervasive and transient smaller scale. (Hole 560 was not sampled for this study because the single basalt clast recovered was used for shipboard analysis.) All of the remaining three holes (562, 563, 564), located along a flow line about 100 km south of the Hayes Fracture Zone (33°N), contain only depleted Type I basalts. The contrast in chemical compositions suggests that the Hayes Fracture Zone may act as a "domain" boundary between an area of fairly homogeneous, depleted Type I basalts to the south (Holes 562-564) and a region of complex, highly variable basalts to the north near the Azores hot-spot anomaly (Holes 556-561).

Depths and ages of seismic sequence boundaries in ODP Leg 166 holes

High-resolution, multichannel seismic data collected across the Great Bahama Bank margin and the adjacent Straits of Florida indicate that the deposition of Neogene-Quaternary strata in this transect are controlled by two sedimentation mechanisms: (1) west-dipping layers of the platform margin, which are a product of sea-level-controlled, platform-derived downslope sedimentation; and (2) east- or north-dipping drift deposits in the basinal areas, which are deposited by ocean currents. These two sediment systems are active simultaneously and interfinger at the toe-of-slope. The prograding system consists of sigmoidal clinoforms that advanced the margin some 25 km into the Straits of Florida. The foresets of the clinoforms are approximately 600 m high with variable slope angles that steepen significantly in the Pleistocene section. The seismic facies of the prograding clinoforms on the slope is characterized by dominant, partly chaotic, cut-and-fill geometries caused by submarine canyons that are oriented downslope. In the basin axis, seismic geometries and facies document deposition from and by currents. Most impressive is an 800-m-thick drift deposit at the confluence of the Santaren Channel and the Straits of Florida. This "Santaren Drift" is slightly asymmetric, thinning to the north. The drift displays a highly coherent seismic facies characterized by a continuous succession of reflections, indicating very regular sedimentation. Leg 166 of the Ocean Drilling Program (ODP) drilled a transect of five deep holes between 2 and 30 km from the modern platform margin and retrieved the sediments from both the slope and basin systems. The Neogene slope sediments consist of peri-platform oozes intercalated with turbidites, whereas the basinal drift deposits consist of more homogeneous, fine-grained carbonates that were deposited without major hiatuses by the Florida Current starting at approximately 12.4 Ma. Sea-level fluctuations, which controlled the carbonate production on Great Bahama Bank by repeated exposure of the platform top, controlled lithologic alternations and hiatuses in sedimentation across the transect. Both sedimentary systems are contained in 17 seismic sequences that were identified in the Neogene-Quaternary section. Seismic sequence boundaries were identified based on geometric unconformities beneath the Great Bahama Bank. All the sequence boundaries could be traced across the entire transect into the Straits of Florida. Biostratigraphic age determinations of seismic reflections indicate that the seismic reflections of sequence boundaries have chronostratigraphic significance across both depositional environments.

Sediment composition and sedimentation rates of four Holes in ODP Leg 166

To date, work on the Great Bahama Bank's western, leeward margin has centred chiefly on seismic-scale expressions of carbonate sequences and systems tracts. However, periplatform, slope sediments also exhibit very well developed cyclicity on scales of decimetres to several metres. It is these small-scale, high-frequency cycles within the larger-scale facies successions of the Quaternary which form the main topic of this paper. Previous studies have shown that the small-scale cycles correlate to the orbitally forced, high-frequency sea-level changes. Therefore these cycles should indicate how sea level has affected the slope development and thus platform-margin evolution during this period. Through detailed, high-resolution sequence stratigraphy of the Great Bahama Bank's leeward margin, obtained via delta18O isotope and mineralogical (XRD) analyses, confined by U/Th dating and nannofossil bioevents, a greater understanding of the bedding geometries within the Pleistocene-Holocene seismic sequences and clues as to the nature of the slope development has been achieved. The high-resolution seismic profiles indicate that since the Plio-Pleistocene change in geometry, in which the Great Bahama Bank developed into a rimmed platform, continued steepening and subsequent progradation of the leeward margin has typified slope development during the Quaternary, which is described as an accretionary slope. However, on the basis of our observations we conclude that only the early to lower middle Pleistocene section (isotope stages 45-20) and the Holocene (isotope stage 1) of the leeward margin is accretionary. This indicates that a degree of erosion and/or by-passing has occurred on the leeward margin since the lower middle Pleistocene (isotope stage 19). During the first part of this period (isotope stages 19-12) erosion and/or by-passing occurred in the middle to lower slope regions and toe-of-slope. By the end of the upper middle to late Pleistocene phase (isotope stages 11-2) erosion also occurred on the upper slope. This erosion by currents at the toe-of-slope and oversteepening of the upper and middle slopes have led to back-cutting upslope and resulted in the progressive retreat of the toe-of-slope towards the platform to the east. However, the rise in sea level since the Last Glacial Maximum to its present-day level has allowed high productivity on the platform top during the Holocene and the deposition of a thick sediment wedge on the slope and sedimentation across the entire leeward flanks. This has led to the redevelopment of an accretionary slope and continued westward progradation of the Great Bahama Bank's western, leeward margin.

Carbonate minerals, uranium and thorium concentration and U-Th ages of sediments from ODP Leg 166 sites

We have performed U-Th isotope analyses on pure aragonite samples from the upper sections of Leg 166 cores to assign each aragonite-rich sediment package to the correct sea-level highstand. The uppermost sediment package from each of the four sites investigated (Sites 1003, 1005, 1006, and 1007) yielded a Holocene U-Th age. Sediment packages from deeper in the cores have suffered diagenesis. This diagenesis consists of significant U loss (up to 40%) in the site nearest the platform (Site 1005), slight U gain in sites further from the platform, and continuous loss of pure 234U caused by alpha recoil at all sites. The difference in diagenesis between the sites can be explained by the different fluid-flow histories they have experienced. Site 1005 is sufficiently close to the platform to have probably experienced a change in flow direction whenever the banks have flooded or become exposed. Other sites have probably experienced continuous flow into the sediment. Although diagenesis prevents assignment of accurate ages, it is sufficiently systematic that it can be corrected for and each aragonite-rich package assigned to a unique highstand interval. Site 1005 has sediment packages from highstands associated with marine isotope Stages 1, 5, 7, 9, and 11. Site 1006 is similar, except that the Stage 7 highstand is missing, at least in Hole 1006A. Site 1003 has sediment only from Stage 1 and 11 highstands within the U-Th age range. And Site 1007 has sediment only from the stage 1 highstand. This information will allow the construction of better age models for these sites. No high-aragonite sediments are seen for Stage 3 or Substages 5a and 5c. Unless rather unusual erosion has occurred, this indicates that the banks did not flood during these periods. If true, this would require the sea level for Substages 5a and 5c to have remained at least ~10 m lower than today.

Calcareous nannofossils of ODP Leg 101 holes

Leg 101 of the Ocean Drilling Program drilled 19 holes at 11 sites to investigate the geology of the Straits of Florida and the northern Bahamas. Drilling at Site 626 indicated that the Gulf Stream has had significant flow through the Straits of Florida for at least the last 24 million years. Winnowed, foraminiferal grainstones and packstones with sparse nannofossil assemblages and the reworking of older nannofossils suggest strong bottom-current activity throughout this interval. Drilling north of Little Bahama Bank and in Exuma Sound documents the growth of platform slopes during the late Cenozoic. Nannofossil biostratigraphy of the upper Cenozoic sediments from the Little Bahama Bank and Exuma Sound slope transects indicates relatively continuous deposition, with only short breaks in the periplatform ooze and/or calciturbidite accumulation during the late Pliocene. These unconformities may be linked to sea-level lowstands. Nannofossil assemblages are generally poorly preserved owing to accelerated diagenesis caused by high aragonite and high magnesium calcite contents of bank-derived material. High rates of influx of bank-derived materials appear to coincide with highstands of sea level. Periplatform sediments are largely limited to the upper Cenozoic at Little Bahama Bank. Pelagic and/or hemipelagic conditions existed during the Late Cretaceous and Paleogene. A relatively complete, continuous section of Oligocene is present in the Little Bahama Bank area, although the rest of the Paleogene is thin. Paleogene material is also present in Northeast Providence Channel, although its thickness is uncertain. A thick upper Campanian chalk sequence with abundant, moderately to well-preserved nannofossils occurs in the Little Bahama Bank area. Hemipelagic nannofossil marls and marly chalks at Little Bahama Bank contain an excellent nannofossil record, which indicates a continuous lowermost to middle Cenomanian sequence overlying the upper Albian drowned platform. These hemipelagic sediments are significantly younger than the organic-rich, middle Albian limestones in Northeast Providence Channel. The latter indicate that a deep-water channel was already well established by the middle Albian.