(Table 1) Color, Fe-C-S chemistry and carbonate content from ODP Sites 172-1062 and 172-1063

Reflectance spectra collected during ODP Leg 172 were used in concert with solid phase iron chemistry, carbonate content, and organic carbon content measurements to evaluate the agents responsible for setting the color in sediments. Factor analysis has proved a valuable and rapid technique to detect the local and regional primary factors that influence sediment color. On the western North Atlantic drifts, sediment color is the result of primary mineralogy as well as diagenetic changes. Sediment lightness is controlled by the carbonate content while the hue is primarily due to the presence of hematite and Fe2+/Fe3+ changes in clay minerals. Hematite, most likely derived from the Permo-Carboniferous red beds of the Canadian Maritimes, is differentially preserved at various sites due to differences in reductive diagenesis and dilution by other sedimentary components. Various intensities for diagenesis result from changes in organic carbon content, sedimentation rates, and H2S production via anaerobic methane oxidation. Iron monosulfides occur extensively at all high sedimentation sites especially in glacial periods suggesting increased high terrigenous flux and/or increased reactive iron flux in glacials.

Planktic foraminiferal abundance and faunal-derived sea surface temperature of eastern equatorial Pacific ODP Site 202-1240

Glacial cooling (~1-5°C) in the eastern equatorial Pacific (EEP) cold tongue is often attributed to increased equatorial upwelling, stronger advection from the Peru-Chile Current (PCC), and to the more remote subpolar southeastern Pacific water mass. However, evidence is scarce for identifying unambiguously which process plays a more important role in driving the large glacial cooling in the EEP. To address this question, here we adopt a faunal calibration approach using planktic foraminifers with a new compilation of coretop data from the eastern Pacific, and present new downcore variation data of fauna assemblage and estimated sea surface temperatures (SSTs) for the past 160 ka (Marine Isotope Stage (MIS) 6) from ODP Site 1240 in the EEP. With significant improvement achieved by adding more coretop data from the eastern boundary current, our downcore calibration results indicate that most of the glacial cooling episodes over the past 160 ka in the EEP are attributable to increased influence from the subpolar water mass from high latitudes of the southern Pacific. By applying this new calibration of the fauna SST transfer function to a latitudinal transect of eastern Pacific (EP) cores, we find that the subpolar water mass has been a major dynamic contributor to EEP cold tongue cooling since MIS 6.

Coccolithophore taxa and PCA factor analysis of ODP Site 1233

We provide high-resolution sea surface temperature (SST) and paleoproductivity data focusing on Termination 1. We describe a new method for estimating SSTs based on multivariate statistical analyses performed on modern coccolithophore census data, and we present the first downcore reconstructions derived from coccolithophore assemblages at Ocean Drilling Project (ODP) Site 1233 located offshore Chile. We compare our coccolithophore SST record to alkenone-based SSTs as well as SST reconstructions based on dinoflagellates and radiolaria. All reconstructions generally show a remarkable concordance. As in the alkenone SST record, the Last Glacial Maximum (LGM, 19-23 kyr B.P.) is not clearly defined in our SST reconstruction. After the onset of deglaciation, three major warming steps are recorded: from 18.6 to 18 kyr B.P. (~2.6°C), from 15.7 to 15.3 kyr B.P. (~2.5°C), and from 13 to 11.4 kyr B.P. (~3.4°C). Consistent with the other records from Site 1233 and Antarctic ice core records, we observed a clear Holocene Climatic Optimum (HCO) from ~8-12 kyr B.P. Combining the SST reconstruction with coccolith absolute abundances and accumulation rates, we show that colder temperatures during the LGM are linked to higher coccolithophore productivity offshore Chile and warmer SSTs during the HCO to lower coccolithophore productivity, with indications of weak coastal upwelling. We interpret our data in terms of latitudinal displacements of the Southern Westerlies and the northern margin of the Antarctic Circumpolar Current system over the deglaciation and the Holocene.