(Table 2) Contents of U, P2O5, CO2, and TOC in phosphorites from Pacific seamounts

Uranium content of in phosphorites from Pacific seamounts does not exceed 10ppm; it is significantly lower than in phosphorites from submarine continental margins and deposits on land. Phosphate is not the main carrier of uranium, which is inhomogeneously distributed in ferromanganese hydroxide-, phosphate-, silicate- and carbonate materials. Uranium associated with phosphate is not isomorphic admixture. Uranium occurs in rocks in fine particles of unknown composition. Ultramicroscopic inclusions of U(IV) oxides have been also found.

Age and chemical composition of apatites from five DSDP and ODP Sites in the Pacific, Atlantic and Indian Oceans

Since studies on deep-sea cores were carried out in the early 1990s it has been known that ambient temperature may have a marked affect on apatite fission track annealing. Due to sluggish annealing kinetics, this effect cannot be quantified by laboratory annealing experiments. The unknown amount of low-temperature annealing remains one of the main uncertainties for extracting thermal histories from fission track data, particularly for samples which experienced slow cooling in shallow crustal levels. To further elucidate these uncertainties, we studied volcanogenic sediments from five deep-sea drill cores, that were exposed to maximum temperatures between ~10° and 70°C over geological time scales of ~15-120 Ma. Mean track lengths (MTL) and etch pit diameters (Dpar) of all samples were measured, and the chemical composition of each grain analyzed for age and track length measurements was determined by electron microprobe analysis. Thermal histories of the sampled sites were independently reconstructed, based on vitrinite reflectance measurements and/or 1D numerical modelling. These reconstructions were used to test the most widely used annealing models for their ability to predict low-temperature annealing. Our results show that long-term exposure to temperatures below the temperature range of the nominal apatite fission track partial annealing zone results in track shortening ranging between 4 and 11%. Both chlorine content and Dpar values explain the downhole annealing patterns equally well. Low chlorine apatite from one drill core revealed a systematic relation between Si-content and Dpar value. The question whether Si-substitution in apatite has direct and systematic effects on annealing properties however, cannot be addressed by our data. For samples, which remained at temperatures <30°C, and which are low in chlorine, the Laslett et al. [Laslett G., Green P., Duddy I. and Gleadow A. (1987) Thermal annealing of fission tracks in apatite. Chem. Geol. 65, 1-13] annealing model predicts MTL up to 0.6 µm longer than those actually measured, whereas for apatites with intermediate to high chlorine content, which experienced temperatures >30°C, the predictions of the Laslett et al. (1987) model agree with the measured MTL data within error levels. With few exceptions, predictions by the Ketcham et al. [Ketcham R., Donelick R. and Carlson W. (1999) Variability of apatite fission-track annealing kinetics. III: Extrapolation to geological time scales. Am. Mineral. 84/9, 1235-1255] annealing model are consistent with the measured data for samples which remained at temperatures below ~30°C. For samples which experienced maximum temperatures between ~30 and 70°C, and which are rich in chlorine, the Ketcham et al. (1999) model overestimates track annealing.

Chemical composition and sulfur-isotope ratios in DSDP Legs 69-and 70

As part of the geochemical-petrological study of basalts recovered from DSDP Hole 504B (Leg 70) on the southern flank of the Costa Rica Rift, we investigated specially the relationships between the distribution and isotopic composition of sulfur of scattered and vein sulfides on the one hand, and the observed pattern and processes of secondary alterations on the other. The following groups of observations are essential: (1) variations in the contents and isotopic composition of sulfur of different forms of sulfides are clearly interrelated and are observed solely in porous horizons established on the basis of detailed geophysical experiments; (2) the enrichment of sulfides in the light sulfur isotope decreases from the upper to the lower horizons, and within horizons in the direction of the less-altered rock; (3) the increase of d34S values of scattered sulfides in individual permeable zones parallels a decrease in the degree of iron oxidation in the contents of crystallization water, and in the concentrations of Mg, K, and Li in the rock.

Contents of P2O5 and REE in phosphorites from shelves and Pacific seamounts

Recent phosphorites from the Namibian shelf are characterized by low REE contents, depletion in REE compared to host sediments and sharp deficiency of lanthanum and europium. In Late Quaternary and Pre-Quaternary phosphorites from ocean shelves REE contents and patterns in general are the same as in host sediments. Phosphorites from seamounts are enriched in REE compared to shelf phosphorites and their patterns are close to one of seawater. Behavior of REE in shelf phosphorites is determined by the fact that in early stages of phosphorite formation REE are associated not primarily with phosphate, but with organic matter and terrigenous impurities. Only in the later stages of diagenesis phosphate begins to play a leading role in concentration of REE. In metasomatic phosphorites on seamounts concentration of REE depends on age and depth of these rocks, i.e. it is determined by duration and conditions of contact with sea water.

Middle Miocene to Quaternary diatoms in the Nankai Trough and Japan Trench

During Leg 87 of the Deep Sea Drilling Project, eleven holes were drilled at Sites 582 and 583 in the Nankai Trough, off Shikoku, southwestern Honshu, and three holes at Site 584 in the Japan Trench, off northeastern Honshu, Japan. In the former area, a low-latitude diatom zone called the Pseudoeunotia doliolus Zone is recognized in thick upper Quaternary sediments, which yield rare but characteristic admixtures of marine planktonic, marine tychopelagic-tobenthic, and nonmarine diatoms. In the latter area, all the sediments recovered contain abundant to common diatoms, allowing recognition of 12 continuous diatom zones from upper Quaternary through lower middle Miocene. Three hiatuses occur in this area around the Pleistocene/Pliocene boundary and in the upper and middle Miocene. In addition, 19 modified diatom zones for a lower Miocene through upper Quaternary interval are proposed. These middle-to-highlatitude zones are numerically coded (NPD1-NPD12) and represent the entire North Pacific. The establishment of these zones is based primarily on Leg 87 data and other DSDP materials and partially on several Japanese subaerial sequences. Correlation of the new zonal framework with previously established frameworks is attempted by the evaluation of operational usefulness of previously used datums. Resting spores of Chaetoceros and its related forms are recorded with specific intent for the first time, and possible ramifications of its frequency variation are presented. Nine new species are proposed: Delphineis sheshukovae Akiba n. sp., Denticulopsis praelauta Akiba and Koizumi n. sp., Kisseleviella ezoensis Akiba n. sp., Nitzschia umaoiensis Akiba n. sp., Thalassiosira jouseae Akiba n. sp., T. praenidulus Akiba n. sp., T. sancettae Akiba n. sp., T. umaoiensis Akiba n. sp., and T. urahoroensis Akiba n. sp. Transfers of systematic positions of the following four taxa are also proposed: Delphineis simonsenii (Mertz) Akiba n. comb., Ikebea tenuis (Brun) Akiba n. comb., Thalassiosira delicata (Barron) Akiba n. stat., and Thalassiothrixrobusta (Schrader) Akiba n. comb.