Accumulation rates of volcanic glass and ice-rafted debris in sediments of the North Pacific Ocean

Mass accumulation rates (MAR) of different components of North Pacific deep-sea sediment provide detailed information about the timing of the onset of major Northern Hemisphere glaciation that occurred at 2.65 Ma. An increase in explosive volcanism in the Kamchatka-Kurile and Aleutian arcs occured at this same time, suggesting a link between volcanism and glaciation. Sediments recovered by piston-coring techniques during ODP Leg 145 provide a unique opportunity to undertake a detailed test of this possibility. Here we use volcanic glass as a proxy for explosive volcanism and ice-rafted debris (IRD) as a proxy for glaciation. The MAR of both glass and IRD increase markedly at 2.65 Ma. Further, the flux of the volcanic glass increased just prior the flix of ice-radted material, suggesting that the cooling resulting from explosive volcanic eruptions may have been the ultimate trigger for the mid-Pliocene glacial intensification.

n-Alkane analyses from an transect of marine surface sediments off southwest Africa

An isobathic transect of marine surface sediments from 1°N to 28°S off southwest Africa was used to further evaluate the potential of the chain length distribution and carbon stable isotope composition of higher plant n-alkanes as proxies for continental vegetation and climate conditions. We found a strong increase in the n-C29-33 weighted mean average d13C values from -33 per mil near the equator to around -26 per mil further south. Additionally, C25-35n-alkanes reveal a southward trend of increasing average chain length from 30.0 to 30.5. The data reflect the changing contribution of plants employing different photosynthetic pathways (C3 and C4) and/or being differently influenced by the environmental conditions of their habitat. The C4 plant proportions calculated from the data (ca. 20% for rivers draining the rainforest, to ca. 70% at higher latitude) correspond to the C4 plant abundance in continental catchment areas postulated by considering prevailing wind systems and river outflows. Furthermore, the C4 plant contribution to the sediments correlates with the mean annual precipitation and aridity at selected continental locations in the postulated catchment areas, suggesting that the C4 plant fraction in marine sediments can be used to assess these environmental parameters.

Clay mineral and heavy metal composition of sea-bed surface sediments and pre-Holocene sediment samples taken during POLARSTERN cruise ANT-XXIII/9

Surface mineralogical compositions and their association to modern processes are well known from the east Atlantic and south-west Indian sectors of the Southern Ocean, but data from the interface of these areas - the Prydz Bay-Kerguelen region - is still missing. The objective of our study was to provide mineralogical data of reference samples from this region and to relate these mineralogical assemblages to hinterland geology, weathering, transport and depositional processes. Clay mineral assemblages were analysed by means of X-ray diffraction technique. Heavy mineral assemblages were determined by counting of gravity-separated grains under a polarizing microscope. Results show that by use of clay mineral assemblages four mineralogical provinces can be subdivided: i) continental shelf, ii) continental slope, iii) deep sea, iv) Kerguelen Plateau. Heavy mineral assemblages in the fine sand fraction are relatively uniform except for samples taken from the East Antarctic shelf. Our findings show that mineralogical studies on sediment cores from the study area have the potential to provide insights into past shifts in ice-supported transport and activity and provenance of different water masses (e.g. Antarctic slope current and deep western boundary current) in the Prydz Bay-Kerguelen region.

Planktonic foraminiferal biostratigraphy and stable carbon isotope ratios of late middle Eocene sediments from Blake Plateau, West Atlantic Ocean

The muricate planktonic foraminiferal genera Morozovella and Acarinina were abundant and diverse during the upper Palaeocene to middle Eocene and dominated the tropical and subtropical assemblages. A significant biotic turnover in planktonic foraminifera occurred in the latest middle Eocene with a notable reduction in the acarininid lineage and the extinction of the morozovellids. These genera are extensively employed as palaeoclimatic and biostratigraphic markers and, therefore, this turnover episode is an important event in the record of the Cenozoic planktonic foraminifera. Sediments from the western North Atlantic (Ocean Drilling Program Site 1052) were examined in order to investigate these extinction events, in terms of both timing and mechanisms. Biostratigraphic events of the middle and late Eocene have been examined with a sampling resoluti on of approximately 3 kyr. These have been calibrated to the magneto- and astrochronology to accurately define the timing of key biostratigraphic events, particularly the extinction of Morozovella spinulosa which is a distinct biomarker for late middle Eocene sediments. High-resolution biostratigraphy reveals that the extinctions in the muricate group occurred in a stepwise form. The large acarininids (Acarinina praetopilensis) terminate 10 kyr prior to the extinction of M. spinulosa and small acarininids (Acarinina medizzai and Acarinina echinata) continue into the upper Eocene. High-resolution stable isotope analyses have been conducted on planktonic and benthic foraminifera from the western North Atlantic to reconstruct sea surface temperatures (SSTs) and deep water temperatures and the structure of the water column around this major biotic turnover. Whilst the extinctions of M. spinulosa and A. praetopilensis occur during a long-term cooling trend, the biotic turnover in the muricate group does not appear to be related to significant climatic change. Sea surface temperatures decrease slowly prior to the extinction events, and there is no evidence for a large-temperature shift associated with the faunal changes. The turnover event was therefore probably related to the increased surface water productivity and the deterioration of photosymbiotic partnerships with algae.