Geochemistry at DSDP Hole 69-504B

Cores from Deep Sea Drilling Project Holes 501, 504B and 505B have an unusual near-vein zonation in basalts. Megascopically, zonation occurs as differently colored strips and zones whose typical thickness does not exceed 6 to 7 cm. Microscopically, the color of zones depends on variably colored clay minerals which are the products of low-temperature hydrothermal alteration in basalt. These differently colored zones form the so called "oxidative" type of alteration of basalts. Another "background," or, less precisely termed, "non-oxidative," type of alteration in basalts is characterized by large-scale, homogeneous replacement of olivine, and filling of vesicles and cracks by an olive-brown or olive-green clay mineral. The compositions of clay minerals of the "background" type of alteration, as well as the composition of co-existing titanomagnetites, were determined with an electron microprobe. There are sharp maxima in potassium and iron content, and minima in alumina, silica, and magnesia in clay minerals in the colored zones near veins. Coloring of clay and rock-forming minerals by iron hydroxides and a decrease of the amount of titanomagnetite, which apparently was the source of redeposited iron, occur frequently in colored zones. We assume that the large-scale "background" alteration in the basalts occurred under the effect of pore waters slowly penetrating through bottom sediments. Faulting can facilitate access of fresh sea water to basalts; thus above the general homogeneous background arise zones of "oxidative" alteration along fractures in basalts. The main factors controlling these processes are time (age of basalt), grain size, temperature, thickness of sedimentary cover, and heat flow.

(Table 1) Geochemical composition of surface waters obtained aboard the R/V Rift along the Volga-Caspian canal

The Volga River discharge consists of the waters transferred by fast currents through channels and the waters which are passing through the shallow areas of the delta overgrown by cane. Using the hydrochemical data, it is possible to track distribution of the waters modified by 'biofilters' of macrophytes in the delta shallows starting from the external edge of the delta. The main distinctive features of these waters are the high content of dissolved oxygen, the abnormally high values of the pH, and the low content of dissolved inorganic carbon (both total and as CO2). These waters extend in the shape of 1 to 3-km-wide strips at a distance of 20-40 km from the outer border of the delta. The analysis of the data obtained during the expeditions run by the Institute of Oceanology of the Russian Academy of Sciences in 2003-2009, along with archived and published data, show that such 'modified' waters occur almost constantly along the outer edge of the Volga River delta.