Transverse drainages of the Susquehanna River basin, Pennsylvania, USA

While large-scale transverse drainages (TDs) such as those of the Susquehanna River above Harrisburg, PA, have been recognized since the 19th century, there have been no systematic surveys done of TDs since that of Ver Steeg's in 1930. Here, the results are presented of a topographic and statistical analysis of TDs in the Susquehanna River basin using Google Earth and associated overlays. 653 TDs were identified in the study area, 95% of which contain streams with discharges of less than 10 m3/s. TD depths ranged from a 23 m deep water gap near Blain, PA, to the 539 m deep gorge of the Juniata River through Jacks Mountain. Although TD depth tended to increase with stream size, many small streams were located in deep gaps, and eight streams with discharges of 10 m3/s or less were found in gorges whose depths matched or exceeded the deepest TD of the Susquehanna, the largest stream in the basin. Streams of less than 10 m3/s made up the majority of TDs regardless of the rock type capping the breached structure. Overall, TDs through sandstone-capped ridges were deeper than those topped by shales, and TDs in both sandstones and shales displayed a lognormal distribution of depths, which may be indicative of a preferred value. Stream flow direction was primarily perpendicular to local structural strike, with 47% of streams flowing NW and 53% flowing SE. 19% of the TDs were found to be in alignment with at least one other TD, with aligned segment lengths ranging from .5 to 14.8 km. The majority of TDs were in rocks of Paleozoic age. The techniques described here allow the frequency and distribution of TDs to be quantified so that they can be integrated into models of basin evolution.

d15N of lipids in marine animals of the Dutch Wadden Sea

Lipid extraction of biomass prior to stable isotope analysis is known to cause variable changes in the stable nitrogen isotopic composition (d15N) of residual biomass. However, the underlying factors causing these changes are not yet clear. Here we address this issue by comparing the d15N of bulk and residual biomass of several marine animal tissues (fish, crab, cockle, oyster, and polychaete), as well as the d15N of the extracted lipids. As observed previously, lipid extraction led to a variable offset in d15N of biomass (differences ranging from -2.3 to +1.8 per mil). Importantly, the total lipid extract (TLE) was highly depleted in 15N compared to bulk biomass, and also highly variable (differences ranging from -14 to +0.7 per mil). The TLE consisted mainly of phosphatidylcholines, a group of lipids with one nitrogen atom in the headgroup. To elucidate the cause for the 15N-depletion in the TLE, the d15N of amino acids was determined, including serine because it is one of the main sources of nitrogen to N-containing lipids. Serine d15N values differed by -7 to +2 per mil from bulk biomass d15N, and correlated well with the 15N depletion in TLEs. On average, serine was less depleted (-3 per mil) than the TLE (-7 per mil), possibly due to fractionation during biosynthesis of N-containing headgroups, or that other nitrogen-containing compounds, such as urea and choline, or recycled nitrogen contribute to the nitrogen isotopic composition of the TLE. The depletion in 15N of the TLE relative to biomass increased with the trophic level of the organisms.