Concentrations of As and other chemical elements in bottom sediments of the Baltic Sea

As is less toxic than Hg, Cd, Pb, Se, Zn, and Cu. The As clarke for clays and shales is 10 ppm. Our samples of bottom sediments from Kurshskii Bay were determined to contain from 15 to 26 ppm As and up to 34 ppm As in the vicinity of the Neman River mouth. Elevated As concentrations (50-114 ppm) were detected in four columns of subsurface bottom sediments (at depths of 10-65 cm) from the Vistula Lagoon. Elevated As concentrations (50-180 ppm) were also found in a few surface samples of sand from the Gdansk Deep near oil platform D-6. These sediments are either partly contaminated with anthropogenic As or contain Fe sulfides and glauconite, which can concentrate As and contain its elevated concentrations. The As concentration in columns of bottom sediments from the Gulf of Finland were at the natural background level (throughout the columns) typical of the area (9-34 ppm). We repeatedly detected very high As concentrations (up to 227 ppm As) in politic ooze from Bornholm Deep, in the vicinity of the sunken vessel with chemical weapons. The sources of elevated As concentrations in the Baltic Sea are the following: (1) chemical weapon (CW) material buried in the floor of the Baltic Sea; (2) As-bearing pesticides, agricultural mineral fertilizers, and burned coal and other fuels; (3) kerogen-bearing Ordovician rocks exposed on the bottom; and (4) As-rich Fe sulfides brought to the area together with construction sand and gravel. This mixture was used in paper production and for the construction of hydraulic engineering facilities in the Vistula Lagoon in the early 20th century and later caused the so-called lagoon disease.

Drought risk assessment as changes in the potential stand yield classes and potential forest production for Sitka spruce, Scots pine, and pedunculate oak over the next 80 years in the Great Britain

Probabilistic climate data have become available for the first time through the UK Climate Projections 2009, so that the risk of tree growth change can be quantified. We assess the drought risk spatially and temporally using drought probabilities and tree species vulnerabilities across Britain. We assessed the drought impact on the potential yield class of three major tree species (Picea sitchensis, Pinus sylvestris, and Quercus robur) which presently cover around 59% (400,700 ha) of state-managed forests, across lowland and upland sites. Here we show that drought impacts result mostly in reduced tree growth over the next 80 years when using b1, a1b and a1fi IPCC emissions scenarios. We found a maximum reduction of 94% but also a maximum increase of 56% in potential stand yield class in the 2080s from the baseline climate (1961-1990). Furthermore, potential production over the national forest estate for all three species in the 2080s may decrease due to drought by 42% in the lowlands and 32% in the uplands in comparison to the baseline climate. Our results reveal that potential tree growth and forest production on the national forest estate in Britain is likely to reduce, and indicate where and when adaptation measures are required. Moreover, this paper demonstrates the value of probabilistic climate projections for an important economic and environmental sector.

Beryllium-10 and aluminium-26 concentration and production rates in glacial deposits from the Quartermain Mountains

Many glacial deposits in the Quartermain Mountains, Antarctica present two apparent contradictions regarding the degradation of unconsolidated deposits. The glacial deposits are up to millions of years old, yet they have maintained their meter-scale morphology despite the fact that bedrock and regolith erosion rates in the Quartermain Mountains have been measured at 0.1-4.0 m/Ma. Additionally, ground ice persists in some Miocene-aged soils in the Quartermain Mountains even though modeled and measured sublimation rates of ice in Antarctic soils suggest that without any recharge mechanisms ground ice should sublimate in the upper few meters of soil on the order of 10**3 to 10**5 years. This paper presents results from using the concentration of cosmogenic nuclides beryllium-10 (10Be) and aluminum-26 (26Al) in bulk sediment samples from depth profiles of three glacial deposits in the Quartermain Mountains. The measured nuclide concentrations are lower than expected for the known ages of the deposits, erosion alone does not always explain these concentrations, and deflation of the tills by the sublimation of ice coupled with erosion of the overlying till can explain some of the nuclide concentration profiles. The degradation rates that best match the data range 0.7-12 m/Ma for sublimation of ice with initial debris concentrations ranging 12-45% and erosion of the overlying till at rates of 0.4-1.2 m/Ma. Overturning of the tills by cryoturbation, vertical mixing, or soil creep is not indicated by the cosmogenic nuclide profiles, and degradation appears to be limited to within a few centimeters of the surface. Erosion of these tills without vertical mixing may partially explain how some glacial deposits in the Quartermain Mountains maintain their morphology and contain ground ice close to the surface for millions of years.