Concentration of organic compounds in slush, under-ice water, and the snow-ice fast-ice cover of the southeast sector of the Antarctic in April 2008

Data are presented on concentration of hydrocarbons (HC) relative to concentrations of suspended matter, lipids, organic carbon, and chlorophyll a in surface waters and snow-ice cover of the East Antarctic coastal areas. It was shown that growth of concentrations of aliphatic HC (AHC) to 30 µg/l in surface waters takes place in frontal zones and under young ice formation. AHC concentration in snow increases with growth of aerosol concentration in the atmosphere. In the lower part of ice, at the boundary with seawater, despite low temperatures, autochthonous processes may provide high AHC concentrations (up to 289 µg/l). Within the snow-ice cover on fast ice, concentration co-variations of all the compounds considered take place.

Alkenone and boron based Oligocene pCO2 records

The Pliocene period is the most recent time when the Earth was globally significantly (~3°C) warmer than today. However, the existing pCO2 data for the Pliocene are sparse and there is little agreement between the various techniques used to reconstruct palaeo-pCO2. Moreover, the temporal resolution of the published records does not allow a robust assessment of the role of declining pCO2 in the intensification of the Northern Hemisphere Glaciation (INHG) and a direct comparison to other proxy records are lacking. For the first time, we use a combination of foraminiferal (delta11B) and organic biomarker (alkenone-derived carbon isotopes) proxies to determine the concentration of atmospheric CO2 over the past 5 Ma. Both proxy records show that during the warm Pliocene pCO2 was between 330 and 400 ppm, i.e. similar to today. The decrease to values similar to pre-industrial times (275-285 ppm) occurred between 3.2 Ma and 2.8 Ma - coincident with the INHG and affirming the link between global climate, the cryosphere and pCO2.

Continuous measurements at Schwingbachtal Studienlandschaft in the growing seasons 2013-2014

The recent development of in-situ monitoring devices, such as UV-spectrometers, makes the study of short-term stream chemistry variation relevant, especially the study of diurnal cycles, which are not yet fully understood. Our study is based on high-frequency data from an agricultural catchment (Studienlandschaft Schwingbachtal, Germany). We propose a novel approach, i.e. the combination of cluster analysis and Linear Discriminant Analysis, to mine from these data nitrate behavior patterns. As a result, we observe a seasonality of nitrate diurnal cycles, that differs from the most common cycle seasonality described in the literature, i.e. pre-dawn peaks in spring. Our cycles appear in summer and the maximum and minimum shift to a later time in late summer/autumn. This is observed both for water- and energy-limited years, thus potentially stressing the role of evapotranspiration. This concluding hypothesis on the role of evapotranspiration on nitrate stream concentration, which was obtained through data mining, broadens the perspective on the diurnal cycling of stream nitrate concentrations.