Sedimentology, mineral magnetism, andoxygen isotope stratigraphy of ODP Hole 133-819A

To investigate late Quaternary paleoclimatic and paleoceanographic change in the sedimentary record, preserved on the Australian Continental Margin during the late Quaternary, core material was collected from Ocean Drilling Program, Leg 133, Site 819. An expanded sequence of late Quaternary, rhythmically bedded, predominantly hemipelagic sediments were recovered from Hole 819A. The foraminiferal d18O record preserved at Hole 819A suggests that the late Quaternary section is incomplete. Both benthic and planktonic d18O stratigraphies can be traced tentatively downcore to stage 6 at about 32.5 mbsf, where a major hiatus occurs. At this level, a slump detachment surface has been identified (Shipboard Scientific Party, 1991). This slump has removed marine oxygen isotope stages 7 to 13. Below 32.5 mbsf, continuous correlation can be achieved in the planktonic d18O curve, with existing deep-sea foraminiferal oxygen isotope stratigraphies from stage 14 through stage 28. The major hiatus at 32.5 mbsf marks the position of a significant change in the character of the sedimentation at Site 819. Sediments below 32.5 mbsf, relative to those above 32.5 mbsf, are characterized by less variation in mean particle size; lower percentages of carbonate content in the coarse fraction (>63 µm); a stronger relationship between the percentage of fine fraction and magnetic mineral concentration, and lower foraminiferal abundances. Above the hiatus, large fluctuations in mean particle size occurred, which have been interpreted to be the result of high foraminiferal abundances. Early highstands show high terrigenous influx in the fine fraction above the hiatus. This is the opposite of the general idea of high terrigenous influx during lowstands of sea level on siliciclastic dominated continental margins. We are far from understanding the origin of this material and further investigation will be required (see also Glenn et al., this volume). All our records, except the planktonic foraminiferal oxygen isotope record, indicate that the major hiatus marks the position of a significant change in the environment at Site 819. The planktonic foraminiferal d18O record suggests that environmental change occurred prior to the formation of the hiatus (i.e., near the Brunhes/Matuyama [B/M] boundary). The interval between the B/M boundary and the hiatus represents a transitional period between two different patterns of ocean circulation. Throughout most of the lower part of the sequence, Site 819 was at a shallow-water depth and local oceanographic conditions were dominated by sluggish Subtropical Central Water (SCW) flow. However, near the B/M boundary, ocean circulation patterns intensified, reflecting a worldwide change in paleoenvironment. Enhanced ocean circulation patterns were possibly aided by tectonic subsidence. During this period Site 819 became progressively more under the influence of Antarctic Intermediate Water (AAIW), than SCW. In the upper part of the sequence at Hole 819 A, we see a continuation of the pattern of oceanographic reorganization suggested during stages 21 through 14. Intensification of the subsurface oceanographic circulation was also accompanied by the progressive wedging southward of surface waters associated with the East Australian Current (EAC). The change in the nature of the records in the lower and upper parts of the sequence at Site 819 are thought to reflect perturbations by the orbital eccentricity cycle.

Environmental magnetism, geochemical measurements and colour reflectance of two sediment cores: GeoB4905-4 off Cameroon and GeoB4906-3 off Gabon

We combine environmental magnetism, geochemical measurements and colour reflectance to study two late Quaternary sediment cores: GeoB 4905-4 at 2° 30 N off Cameroon and GeoB 4906-3 at 0° 44 N off Gabon. This area is suitable for investigating precipitation changes over Central and West Africa because of its potential to record input of aeolian and fluvial sediments. Three magnetozones representing low and high degree of alteration of the primary rock magnetic signals were identified. The magnetic signature is dominated by fine-grained magnetite, while residual haematite prevails in the reduced intervals, showing increase in concentration and fine grain size at wet intervals. Our records also show millennial-scale changes in climate during the last glacial and interglacial cycles. At the northern location, the past 5.5 ka are marked by high-frequency oscillations of Ti and colour reflectance, which suggests aeolian input and hence aridity. The southern location remains under the influence of the Intertropical Convergence Zone and thus did not register aeolian signals. The millennial-scale climatic signals indicate that drier and/or colder conditions persisted during the late Holocene and are synchronous with the 900 a climatic cycles observed in Northern Hemisphere ice core records.

Rock magnetism and paleomagnetism of basalts at DSDP Leg 65 Holes

We investigated the magnetic and paleomagnetic properties of 77 basalt samples from Holes 482, 482C, 482D, 483, 483B, 485, and 485A in order to study the structure and development of the ocean's crust. During the course of this study, we measured the natural remanent magnetization, Jn, and its stability in an alternating magnetic field; the magnetic susceptibility, x; the saturation magnetization, Js; the saturation remanent magnetization, Jrs; the coercivity of maximum remanence, HCR; and the median destructive fields MDFn (for Jn) and MDFs for Jrs. A thermomagnetic analysis for Js and Jrs was also performed; these latter measurements were made on the same samples.

Rock magnetism of pelagic sediments from DSDP Leg 85 sites

A detailed rock magnetic investigation has been carried out on Deep Sea Drilling Project (DSDP) pelagic sediments from the Central Equatorial Pacific. This comprises hysteresis and thermomagnetic measurements, Lowrie-Fuller test and, for the first time, ferromagnetic resonance (FMR). Nearly stochiometric magnetite in two grain size fractions, single domain (SD) and multi domain (MD), has been deduced to be the carrier of magnetic remanence. Comparatively strong paramagnetic contributions are carried by pyrite, being identified by X-ray analysis. The statistical analysis of paleomagnetic parameters (NRM, MDF, initial susceptibility, Königsberger ratio Q) from a large number (> 1000) of samples, supported by hysteresis measurements, indicates a latitude and sedimentation rate dependent ratio of SD/MD grains. Possible sources for the magnetic constituents are discussed in terms of bacterial, volcanic, meteoritic and authigenic origin.

(Table T1) Magnetic properties of MORB from ODP Leg 187 sites

The core samples of mid-ocean-ridge basalts (including Indian and Pacific type) recovered from the Southeast Indian Ridge (SEIR) area near the Australian Antarctic Discordance during Ocean Drilling Program Leg 187 were studied using rock magnetism, mineralogy, and petrography methods. On the basis of thermomagnetic analyses and low-temperature magnetometry, the dominant magnetic carrier in most of the basalt samples (pillow basalts) is characterized as titanomaghemite, which presumably formed by low-temperature oxidation of primary titanomagnetite. Some samples from unaltered massive basalts contain nearly unoxidized titanomagnetite as the main magnetic mineral. A metadiabase sample showing greenschist facies metamorphism contains magnetic minerals dominated by magnetite. The pillow basalts contain titanomaghemite ranging from stable single-domain to pseudosingle-domain (PSD) grains, and the majority are characterized by a single stable component of remanence. The massive basalts show hysteresis features of larger PSD grains and contain a very low coercivity remanence. The values of natural remanent magnetization (NRM) of the samples in this SEIR area are on the same order as those of other oceanic ridge basalts. They show a general decreasing trend of NRM with increasing crust age. However, the values of NRM show no correlation either with the tectonic zonations (Zone A vs. Zone B) or with the mantle provinces (Pacific vs. Indian types).

A time-slice study in Heinrich Stadial 1 and Mid Holocene sediment cores off northern Senegal

Sediment dynamics in limnic, fluvial and marine environments can be assessed by granulometric and rock-magnetic methodologies. While classical grain-size analysis by sieving or settling mainly bears information on composition and transport, the magnetic mineral assemblages reflect to a larger extent the petrology and weathering conditions in the sediment source areas. Here, we combine both methods to investigate Late Quaternary marine sediments from five cores along a transect across the continental slope off Senegal. This region near the modern summer Intertropical Convergence Zone is particularly sensitive to climate change and receives sediments from several aeolian, fluvial and marine sources. From each of the investigated five GeoB sediment cores (494-2956 m water depth) two time slices were processed which represent contrasting climatic conditions: the arid Heinrich Stadial 1 (~ 15 kyr BP) and the humid Mid Holocene (~ 6 kyr BP). Each sediment sample was split into 16 grain-size fractions ranging from 1.6 to 500 µm. Concentration and grain-size indicative magnetic parameters (susceptibility, SIRM, HIRM, ARM and ARM/IRM) were determined at room temperature for each of these fractions. The joint consideration of whole sediment and magnetic mineral grain-size distributions allows to address several important issues: (i) distinction of two aeolian sediment fractions, one carried by the north-easterly trade winds (40-63 µm) and the other by the overlying easterly Harmattan wind (10-20 µm) as well as a fluvial fraction assigned to the Senegal River (< 10 µm); (ii) identification of three terrigenous sediment source areas: southern Sahara and Sahel dust (low fine-grained magnetite amounts and a comparatively high haematite content), dust from Senegalese coastal dunes (intermediate fine-grained magnetite and haematite contents) and soils from the upper reaches of the Senegal River (high fine-grained magnetite content); (iii) detection of partial diagenetic dissolution of fine magnetite particles as a function of organic input and shore distance; (iv) analysis of magnetic properties of marine carbonates dominating the grain-size fractions 63-500 µm.

Chemistry of upper Eocene microtektites

Late Eocene microtektites and crystal-bearing microkrystites extracted from DSDP and ODP cores from the Atlantic, Pacific, and Indian oceans have been analyzed to address their provenance. A new analysis of Nd and Sr isotopic compositions confirms previous work and the assignment of the uppermost microtektite layer to the North American tektites, which are associated with the 35.5 Ma, 85 km diameter Chesapeake impact structure of Virginia, USA. Extensive major element and Nd and Sr isotopic analyses of the microkrystites from the lowermost layer were obtained. The melanocratic microkrystites from Sites 216 and 462 in the Indian and Pacific oceans possess major element chemistries, Sr and Nd isotopic signatures and Sm-Nd, T CHUR, model ages similar to those of tagamite melt rocks in the Popigai impact structure. They also possess Rb-Sr, T UR, model ages that are younger than the tagamite TCHUR ages by up to ~1 Ga, which require a process, as yet undefined, of Rb/Sr enrichment. These melanocratic microkrystites are consistent with a provenance from the 35.7 Ma, 100 km diameter Popigai impact structure of Siberia, Russia, while ruling out other contemporaneous structures as a source. Melanocratic microkrystites from other sites and leucocratic microkrystites from all sites possess a wide range of isotopic compositions (epsilon (143Nd) values of -16 to -27.7 and epsilon (87Sr) values of 4.1-354.0), making the association with Popigai tagamites less clear. These microkrystites may have been derived by the melting of target rocks of mixed composition, which were ejected without homogenization. Dark glass and felsic inclusions extracted from Popigai tagamites possess epsilon (143Nd) and epsilon (87Sr) values of -26.7 to -27.8 and 374.7 and 432.4, respectively, and T CHUR and T UR model ages of 1640-1870 Ma and 240-1830 Ma, respectively, which require the preservation of initially present heterogeneity in the source materials. The leucocratic microkrystites possess diverse isotopic compositions that may reflect the melting of supra-basement sedimentary rocks from Popigai, or early basement melts that were ejected prior to homogenization of the Popigai tagamites. The ejection of melt rocks with chemistries consistent with a basement provenance, rather than the surface ~1 km of sedimentary cover rocks, atypically indicates a non-surficial source to some of the ejecta. Microkrystites from two adjacent biozones possess statistically indistinguishable major element compositions, suggesting they have a single source. The occurrence of microkrystites derived from a single impact event, but in different biozones, can be explained by: (1) diachronous biozone boundaries; (2) post-accumulation sedimentary reworking; or (3) erroneous biozonation.

Paleomagnetism of DSDP Leg 80 holes

Paleomagnetic results from sediments acquired from the continental margin at DSDP Sites 548, 549, 550, and 551 are described. Where possible, the results were used to construct a polarity reversal stratigraphy for the sections sampled, thus enabling the biostratigraphic dating of the sediments to be refined. Several sections in this study were found to be suitable for magnetostratigraphic work, in particular the upper Paleocene to middle Eocene sediments from Site 549, which contained rich faunal assemblages. These sediments are underlain by a thick sequence of Cretaceous sediments that formed during the Long Cretaceous normal polarity interval. Sediments that formed during the later part of this magnetically quiet interval were also recovered at Site 550. Three short reverse polarity intervals were also recovered at this site; they lie directly over basement and are thought to represent a mixed-polarity interval of late Albian age. They may therefore provide important evidence concerning the age of the earliest sediments at this site. In addition, measurements of the magnetic susceptibility and intensity of remanent magnetism proved to be of interest. A significant decrease in the susceptibility and intensity values close to the early/middle Eocene boundary was noted at Sites 548 and 549. This decrease may be correlated with the results from Holes 400A and 401, which were drilled on DSDP Leg 48 in the northeast Bay of Biscay. The decrease may represent an abrupt reduction in the supply of terrigenous material at the end of the early Eocene, reflecting, perhaps, a change in sediment transport processes at that time

Magnetic properties of ODP Hole 116-717C

Dark gray and black mud turbidites cored on ODP Leg 116 commonly yielded large magnetic susceptibility peaks. What is more, these peaks displayed different shapes suggesting variations in sedimentological processes. Consequently, a detailed study of the magnetic properties of two of these turbidites was undertaken to better understand the source of their unusual magnetism. Physical properties were measured as was the demagnetization behavior of sample natural remanent magnetizations (NRMs). Subsequently, an anhysteretic remanent magnetization (ARM) and saturation isothermal remanent magnetization (SIRM) were imparted to the samples, demagnetized, and various grain size tests based on the behavior of these remanences were applied. Finally, magnetic concentrates from two samples were examined with a scanning electron microscope with the capability to do energy dispersive X-ray (EDX) analysis. The turbidites stand out from surrounding layers because of their high susceptibilities, NRMs, ARMs, SIRMs, and ratios of ARM and SIRM to susceptibility. Their alternating field and thermal demagnetization properties and IRM acquisition curves are consistent with titanomagnetite grains as the primary magnetic mineral with some amount of hematite present. These properties are very similar to those published for samples from the Deccan flood basalts and suggest this formation as a possible source of the magnetic grains. Magnetic granulometry tests implied that the magnetic particles behave dominantly as single-domain and pseudo-single-domain grains. Moreover, they also implied that the large variation in susceptibility observed in the black mud turbidites results from a tenfold increase in the concentration of titanomagnetite grains. Electron microscope, EDX, and SIRM analyses revealed detrital titanomagnetites with typical sizes around 8-10 µm, but as large as 20-25 µm. These are probably the dominant magnetic grains in the black mud turbidites; however, ARM and susceptibility frequency-dependence suggested that there may also be a submicrometer fraction present. Most of the observed titanomagnetite grains are tabular and some display exsolution lamellae, accounting for the pseudo-single-domain behavior despite their moderate sizes. We hypothesize that the magnetic mineral concentration variations are brought about by sedimentological factors. The heavier magnetic minerals may tend to sink to the bottom of a turbidite; however, sometimes turbidite turbulence may act to keep these tabular, medium-size grains in suspension longer than some other larger or more equidimensional grains. Consequently, the susceptibility peak shape may reflect the turbidite current velocities as well as other sedimentological factors.

Magnetic measurements performed on sediments from the Bay of Seine seafloor (France) from 2011 to 2013

Impact and monitoring of dredge spoils are an important environmental issue. This investigation aims to map two dredge-spoil dispersals in the Bay of Seine by using an innovative application of well-established environmental magnetic proxies. Low-field magnetic susceptibility measurements were performed on discrete samples from dredge sediments and from the Bay of Seine seafloor before & after dumping. The fingerprinting of the dispersion of dredge-dumped sediments is efficient due to the higher susceptibility of the dredge sediments with respect to the background. Besides, terrestrial input is also monitored in our susceptibility maps. Dilution of the susceptibility signal allows an estimation of the resilience of the sedimentary environment on a six-month survey. This susceptibility signal is controlled by the ferromagnetic fraction of the sediment. A constant magnetic mineralogy carried by magnetite is observed in the study area, thus a qualitative parameter for magnetic grain size was selected that shows an in-progress resilience pattern over the survey.