Mineral resources in Lower Brule Indian Reservation

On the Lower Brule Indian Reservation in South Dakota, about 3 million tons of metallic manganese are in low-grade deposits in the DeGrey Member of the Pierre Shale on the reservation. The geology and methods of mining and processing this sub-economic mineral resource have been studied extensively; technologically, extraction of manganese is possible. However, an efficient, economical method to separate manganese-bearing nodules from the shale host rocks has yet to be found. The manganiferous nodules occur in the Oacoma zone of the Sully shale member (De-Grey Member) which is a subdivision of the South Dakota Pierre Shale formation. These nodular deposits have an interesting similarity in stratigraphical position, lithology and manganese content to those of the Porcupine Mountain area in Manitoba.

Inorganic carbon and geochemistry measurements from landfast sea ice in Resolute Passage, Nunavut, Canada, as part of the Arctic-ICE project, May - June 2010

We conducted a six-week investigation of the sea ice inorganic carbon system during the winter-spring transition in the Canadian Arctic Archipelago. Samples for the determination of sea ice geochemistry were collected in conjunction with physical and biological parameters as part of the 2010 Arctic-ICE (Arctic - Ice-Covered Ecosystem in a Rapidly Changing Environment) program, a sea ice-based process study in Resolute Passage, Nunavut. The goal of Arctic-ICE was to determine the physical-biological processes controlling the timing of primary production in Arctic landfast sea ice and to better understand the influence of these processes on the drawdown and release of climatically active gases. The field study was conducted from 1 May to 21 June, 2010.

(Table 1) White ice and melt pond characteristics in Darnley and Franklin Bay, Canada

Melt pond covered sea ice is a ubiquitous feature of the summertime Arctic Ocean when meltwater collects in lower-lying areas of ice surfaces. Horizontal transects were conducted during June 2008 above and below landfast sea ice with melt ponds to characterize surface and bottom topography together with variations in transmitted spectral irradiance. We captured a rapid progression from a highly flooded sea ice surface with lateral drainage toward flaws and seal breathing holes to the formation of distinct melt ponds with steep edges. As the mass of the ice cover decreased due to meltwater drainage and rose upward with respect to the seawater level, the high-scattering properties of ice above the water level (i.e., white ice) were continuously regenerated, while pond waters remained transparent compared to underlying ice. The relatively stable albedos observed throughout the study, even as ice thickness decreased, were directly related to these surface processes. Transmission through the ice cover of incident irradiance in the 400-700 nm wave band ranged from 38% to 67% and from 5% to 16% beneath ponded and white ice, respectively. Our results show that this transmission varied not only as a function of surface type (melt ponds or white ice) areal coverage but also in relation to ice thickness and proximity to other surface types through the influence of horizontal spreading of light. Thus, in contrast to albedo, this implies that regional transmittance estimates need to consider melt pond size and shape distributions and variations in optical properties and thickness of the ice cover.

Sedimentaology, pollen profile, and climate reconstruction on a sediment core from Trou Lake, Yukon, Canada

Beringian climate and environmental history are poorly characterized at its easternmost edge. Lake sediments from the northern Yukon Territory have recorded sedimentation, vegetation, summer temperature and precipitation changes since ~16 cal ka BP. Herb-dominated tundra persisted until ~14.7 cal ka BP with mean July air temperatures less than or equal to 5 °C colder and annual precipitation 50 to 120 mm lower than today. Temperatures rapidly increased during the Bølling/Allerød interstadial towards modern conditions, favoring establishment of Betula-Salix shrub tundra. Pollen-inferred temperature reconstructions recorded a pronounced Younger Dryas stadial in east Beringia with a temperature drop of ~1.5 °C (~2.5 to 3.0 °C below modern conditions) and low net precipitation (90 to 170 mm) but show little evidence of an early Holocene thermal maximum in the pollen record. Sustained low net precipitation and increased evaporation during early Holocene warming suggest a moisture-limited spread of vegetation and an obscured summer temperature maximum. Northern Yukon Holocene moisture availability increased in response to a retreating Laurentide Ice Sheet, postglacial sea level rise, and decreasing summer insolation that in turn led to establishment of Alnus-Betula shrub tundra from ~5 cal ka BP until present, and conversion of a continental climate into a coastal-maritime climate near the Beaufort Sea.

Re-OS and Pb isotope ratios of sediments from Saanich Inlet, Western Canada

Re-Os and Pb-Pb isotopic analysis of reduced varved sediments cored in the deeper basin of Saanich Inlet (B.C.) are presented. From core top to 61 cm down-core, spanning approximately the last 100 yrs of sedimentation, 187Os/188Os ratio and Os concentration respectively increase from ~0.8 to ~0.9 and from 55 to 60 ppt, whereas Re concentration decreases from 3600 to 2600 ppt. Re correlates with Corg (R2=0.6) throughout the entire section, whereas Os follows Re and Corg trends deeper down-core, suggesting a decoupling of a Re- and Os-geochemistry during burial and/or very early diagenesis. No systematic compositional differences are observed between seasonal laminae. 204Pb-normalized lead isotope ratios increase from sediment surface down to 7 cm down-core, then decrease steadily to pre-industrial levels at ~50 cm down-core. This pattern illustrates the contamination from leaded gasoline until the recent past. The measured Pb isotopic ratios point primarily toward gasoline related atmospheric lead from the USA. The osmium isotopic values measured are significantly lower than those of modern seawater-Os. In comparison with other anoxic environments, the osmium content of Saanich Inlet sediments is low, and its Os isotopic composition suggests significant inputs from unradiogenic sources (detrital and/or dissolved). Ultramafic lithologies in the watershed of the Fraser River are suspected to contribute to sedimentary inputs as well as to the input of dissolved unradiogenic osmium in the water of Saanich Inlet. The presence of some unradiogenic Os from anthropogenic contamination cannot be discounted near the core top, but since deeper, pre-anthropogenic levels also yielded unradiogenic Os results, one is led to conclude that the overall low 187Os/188Os ratios result from natural geochemical processes. Thus, the bulk sediment of Saanich Inlet does not appear to record 187Os/188Os composition of the marine end-member of the only slightly below normal salinity, fjord water. The low seawater-derived Os content of the sediment, coupled with unradiogenic Os inputs from local sources, explains the overall low isotopic values observed. As a consequence, such near-shore anoxic sediments are unlikely to record changes in the past ocean Os isotopic composition.

The petrology of the lower series volcanics of ODP Hole 104-642E

Between 1086.6 and 1229.4 m below seafloor at Site 642 on the Outer Vøring Plateau, a series of intermediate volcanic extrusive flow units and volcaniclastic sediments was sampled. A mixed sequence of dacitic subaerial flows, andesitic basalts, intermediate volcaniclastics, subordinate mid-ocean ridge basalt, (MORB) lithologies, and intrusives was recovered, in sharp contrast to the more uniform tholeiitic T-type MORB units of the overlying upper series. This lower series of volcanics is composed of three chemically distinct groups, (B, A2, A1), rather than the two previously identified. Flows of the dacitic group (B) have trace-element and initial Sr isotope signatures which indicate that their source magma derived from the partial melting of a component of continental material in a magma chamber at a relatively high level in the crust. The relative proportions of crustal components in this complex melt are not known precisely. The most basic group (A2) probably represents a mixture of this material with MORB-type tholeiitic melt. A third group (A1), of which there was only one representative flow recovered, is chemically intermediate between the two groups above, and may suggest a repetition of, or a transition phase in, the mixing processes.

Barnacle recurit density, biomass, and reproductive output measured in rocky intertidal habitats in Glasgow Head, on the Atlantic coast of Nova Scotia, Canada

Through a field experiment, we show that a predator has negative nonconsumptive effects (NCEs) on different life-history stages of the same prey species. Shortly before the recruitment season of the barnacle Semibalanus balanoides (May-June), we established experimental cages in rocky intertidal habitats in Nova Scotia, Canada. The cages were used to manipulate the presence and absence of dogwhelks, Nucella lapillus, the main predators of barnacles. At the centre of each cage, we installed a tile where barnacle pelagic larvae could settle and the resulting recruits grow. Mesh prevented caged dogwhelks from accessing the tiles, but allowed waterborne dogwhelk cues to reach the tiles. Results in May indicated that barnacle larvae settled preferentially on tiles from cages without dogwhelks. In November, at the end of the dogwhelk activity period and once the barnacle recruits had grown to adult size, barnacle body mass was lower in the presence of dogwhelks. This limitation may have resulted from a lower barnacle feeding activity with nearby dogwhelks, as found by a previous study. The observed larval and adult responses in barnacles are consistent with attempts to decrease predation risk. November data also indicated that dogwhelk cues limited barnacle reproductive output, a possible consequence of the limited growth of barnacles. Overall, this study suggests that a predator species might influence trait evolution in a prey species through NCEs on different life-history stages.

Description and geochemical composition of manganese nodules retrieved from Lake Ontario, Canada

A large deposit of ferromanganese oxide coated sands and scattered manganese nodules occurs in the northern portion of Lake Ontario. The Mn and Fe contents of the concretions are similar to those in concretions from other environments, while their Ni, Cu, and Co contents are lower than in deep-sea nodules, but higher than in most previously described lacustrine concretions. Pb and Zn are high in the coatings and exceed the concentrations found in many previously analyzed Mn deposits. Within the deposit, Mn, Ni, Co, and Zn contents are correlated, and they vary inversely with Fe. Mn, Fe, Ni, Cu, and Pb are present in the interstitial waters of the sediments underlying the deposit in higher concentrations than in the overlying lake waters, thus providing a potential source of metals for concretion formation.The origin and compositional variations in the deposit possibly can be explained in terms of the fractionation and precipitation of Fe and Mn as a result of redox variations in the lake sediments. Eh increases from south to north across the deposit in such a way that iron may be selectively oxidized and precipitated in the south and manganese, in the north. The upward diffusion of Mn, Fe, and associated elements from the underlying sediments probably provides the principal source of the metals in the south of the deposit, while metal-enriched bottom waters are probably the principal source in the north.

Petrology of mafic and ultramafic intrusions from the Portneuf-Mauricie Domain, Grenville Province, Canada

The Portneuf-Mauricie Domain (PMD), located in the south-central part of the Grenville Province, comprises several mafic and ultramafic intrusions hosting Ni-Cu ± platinum-group element (PGE) prospects and a former small mining operation (Lac Édouard mine). These meter- to kilometer-scale, sulfide-bearing intrusions display diverse forms, such as layered and tabular bodies with no particular internal structure, and zoned plutons. They were injected ~ 1.40 Ga into a mature oceanic arc, before and during accretion of the arc to the Laurentian margin. The pressure-temperature conditions of the magmas at the beginning of their emplacement were 3 kbar and 1319-1200 °C (according to the petrologic modeling results from this study). The PMD mineralized intrusions are interpreted to represent former magma chambers or magma conduits in the roots of the oceanic arc. The parent magmas of the mineralized intrusions resulted mainly from the partial melting of a mantle source composed of spinel-bearing lherzolite. Petrologic modeling and the occurrence of primary amphibole in the plutonic rocks indicate that these parent melts were basaltic and hydrous. In addition, fractional crystallization modeling and Mg/Fe ratios suggest that most of the intrusions may have formed from evolved magmas, with Mg# = 60, resulting from the fractionation of more primitive magmas (primary magmas, with Mg# = 68). Petrologic modeling demonstrates that 30% fractional crystallization resulted in the primitive to evolved characteristics of the studied intrusive rocks (as indicated by the crystallization sequences and mineral chemistry). Exceptions are the Réservoir Blanc, Boivin, and Rochette West parent magmas, which may have undergone more extensive fractional crystallization, since these intrusions contain pyroxenes that are more iron rich and have lower Mg numbers than pyroxenes in the other PMD intrusions. The PMD mafic and ultramafic intrusions were intruded into an island arc located offshore from the Laurentian continent. Thus, their presence confirms the existence of a well-developed magmatic network (responsible of the fractionation processes) beneath the Proterozoic arc, which resulted in the wide range of compositions observed in the various plutons.

Characteristics and changes of thermokarst lakes in Canada, Russia and Sweden

Peat plateaus are widespread at high northern latitudes and are important soil organic carbon reservoirs. A warming climate can cause either increased ground subsidence (thermokarst) resulting in lake formation or increased drainage as the permafrost thaws. A better understanding of spatiotemporal variations in these landforms in relation to climate change is important for predicting the future thawing permafrost carbon feedback. In this study, dynamics in thermokarst lake extent during the last 35-50 years has been quantified through time series analysis of aerial photographs and high-resolution satellite images (IKONOS/QuickBird) in three peat plateau complexes, spread out across the northern circumpolar region along a climatic and permafrost gradient. From the mid-1970s until the mid-2000s there has been an increase in mean annual air temperature, winter precipitation, and ground temperature in all three study areas. The two peat plateaus located in the continuous and discontinuous permafrost zones, respectively, where mean annual air temperatures are below -5°C and ground temperatures are -2°C or colder, have experienced small changes in thermokarst lake extent. In the peat plateau located in the sporadic permafrost zone where the mean annual air temperature is around -3°C, and the ground temperature is close to 0°C, lake drainage and infilling with fen vegetation has been extensive and many new thermokarst lakes have formed. In a future progressively warmer and wetter climate permafrost degradation can cause significant impacts on landscape composition and greenhouse gas exchange also in areas with extensive peat plateaus, which presently still experience stable permafrost conditions.

(Table 1) Annual mean concentrations of atmospheric a- and g-Hexachlorocyclohexane at stations Alert, Canada and Zeppelin, Norway

Twelve year datasets of weekly atmospheric concentrations of alpha- and gamma-HCH were compared between the two Arctic monitoring stations of Alert, Nunavut, Canada, and Zeppelin Mountain, Svalbard, Norway. Time-series analysis was conducted with the use of dynamic harmonic regression (DHR), which provided a very good model fit, to examine both the seasonal behaviour in these isomers and the longer-term, underlying trends. Strong spatial differences were not apparent between the two sites, although subtle differences in seasonal behaviour and composition were identified. For example, the composition of gamma-HCH to total HCH (alpha + gamma) was greater at Zeppelin compared to Alert, probably reflecting this site's proximity to major use regions of lindane. Pronounced seasonality in air concentrations for gamma-HCH was marked by a 'spring maximum event' (SME), confirming earlier studies. For alpha-HCH, the SME was much weaker and only evident at Alert, whereas at Zeppelin, seasonal fluctuations for alpha-HCH were marked by elevated concentrations in summer and lower concentrations during winter, with this pattern most apparent for the years after 2000. We attribute this difference in spatial and temporal patterns to the Arctic oscillation. A similar climatic pattern was not evident at either site in the gamma-HCH data. Seasonally adjusted, long-term trends revealed declining concentrations at both sites for alpha- and gamma-HCH over the entire time-series. Recent legislation affecting lindane use appear to account for this decline in gamma-HCH, with little evidence of a delay or 'lag' between the banning of lindane in Europe (a main source region) or Canada, and a decline in air concentrations observed at both Arctic sites.