Composition of melt inclusions and age of zircons of plagiogneisses from the Kola Superdeep Borehole

A comprehensive study of melt inclusions and SHRIMP dating of zircons from trondhjemite gneisses of the sequence VIII from the Kola Superdeep Borehole has revealed presence of old primary magmatic crystals with age up to 2887+/-15 Ma. This is not consistent with the previous view, according to which the oldest zircons from the Archean Complex in SG-3 are products of granulite metamorphism. Primary magmatic zircons of early generation (from 2887 to 2842 Ma) formed in deep-seated magma chambers during partial crystallization of CO2-saturated trondhjemite estimates on duration of generation of tonalite-trondhjemite-granite melts through partial melting of mafic rocks.

Isotope composition of sulfur, oxygen and carbon in Black Sea sediments

Inversion of isotopic composition in the SO4(2-)-H2S system is shown to be universal in Neoeuxine sediments and an explanation of its occurrence is proposed. Change in isotopic composition of sulfate sulfur in Black Sea waters over last 10-15 thousand years is reconstructed. Periods of alteration between aerobic and anaerobic situations are identified, the beginning of entry of Mediterranean waters into the basin is dated, presence of authigenic carbonates in sediments of the sea is established and amounts are determined. Methane generation from carbon dioxide is shown to have been replaced by its generation from acetate in the paleo-Black Sea period.

n-Alkanes and lignin in bottom sediments of the Norwegian Sea

Investigations of bottom sediments from the central and northern parts of the Norwegian Sea including study regions at the Storegga landslide, the Haakon Mosby mud volcano, and Knipovich Ridge were carried out. Concentration of n-alkanes in bottom sediments from these regions ranges from 0.53 to 22.1 µg/g of dry sediments that corresponds to 0.02-1.97% of Corg. Molecular composition of hydrocarbons indicates mixed allochtonous-authochtonous genesis of total organic matter (TOC) formed by hydrobiota and residuals of terrestrial plants. Terrigenous organic mater dominates in bottom sediments. Active redox, microbial and thermolytic processes of organic matter transformation take place in the sedimentary mass. Special character of chromatographic spectra of n-alkane distribution in both low and high-molecular ranges, as well as increased naphtene contents can be interpreted as a sign of oil hydrocarbon generation from maternal organic matter as a result of thermocatalytic reactions within sedimentary mass and their displacement into the upper sedimentary layers. Molecular compositions and concentrations of phenols and lignin were determined in core samples from the Norwegian Sea. Total concentration of phenols in the cores ranges from 8.1 to 101.8 (µg/g of dry sediments that corresponds to 0.15-1.15% of TOC. Lignin concentration was estimated at 21.0-459.0 µg/g of dry sediments (0.59-7.9% of ?org. Phenol compounds of p-hydroxybenzoic, vanillin, syringyl and cinnamyl families as basic components of lignin macromolecules were identified. It was found that sea currents and aerosols are the main contributors of lignin into the abyssal part of the Norwegian Sea.

(Table 1) Chemical composition of interstitial waters from the area of gas hydrate generation, Sea of Okhotsk

Distributions of halogens (Cl, Br and I) in interstitial waters from sediments containing methane hydrate and in water of the hydrate itself are presented. High concentrations of halogens do not occur in interstitial waters from sediments that contain gas hydrates. The main reason for their low concentrations is the poverty of organic matter in sediments.