Chemical composition of siderites and clay minerals from DSDP Holes 70-506G and 70-507B

As soon as they are emplaced on the sea floor, oceanic basalts go through a low-temperature alteration process which produces black halos concentrical with exposed surfaces and cracks, whereas the grey internal parts of the basaltic pieces apparently remain unaltered. This paper reports for the first time the occurrence of authigenic siderite and ankerite in oceanic basalts and more particularly in the grey internal parts of the latter. Small (8-50 µm) crystals of zoned siderite and ankerite have been observed in ten vesicles of two samples recovered from DSDP Holes 506G and 507B drilled south of the Galápagos Spreading Center (GSC). These Fe-carbonates show a large range of chemical composition (FeCO3 = 47-88%; CaCO3 = 5-40%; MgCO3 = 1-20%; MnCO3 = 0-11%). Most of them are Ca-richer than siderite reported in the literature. The chemical composition of the carbonate clearly reflects the fluctuation of the fluid chemical composition during crystallization. Mn and at least part of the Fe are thought to be hydrothermal in origin, whereas Mg and probably Ca were provided by seawater. It is proposed that siderite and ankerite formed at relatively low temperature (<85°C) and is metastable. The alteration of the GSC basalts seems to have proceeded in two stages: during the first, reducing stage, pyrite precipitated from hydrothermal fluids. A little further in the rock, siderite precipitated from the fluid which had already been modified by the formation of pyrite, and thus in a microenvironment where particular conditions prevailed (high P_CO2, increasing p_S**2- or increasing pH or increasing or decreasing pe). During the second, oxidizing, stage of alteration, a seawater-dominated fluid allowed crystallization of mixtures of Fe-rich smectites and micas, and Fe-hydroxides forming the black halos in the external portion of the basalt pieces and locally oxidizing pyrite and siderite in their innermost part. It is shown in this paper that, even at its earliest stage, and at low temperature, alteration of the upper oceanic crust (lavas) involves fluids enriched in Fe and Mn, interpreted to be of hydrothermal origin.

(Table 4) Mean diameter of Orbulina universa d'Orbigny at DSDP Leg 54 Holes

On Deep Sea Drilling Project Leg 54, we recovered upper Pliocene (Globigerinoides obliquus: PL6 zone) to Pleistocene sediments from the equatorial East Pacific Rise (EPR) and Galapagos spreading center (GSC). Progressively older sediments were drilled at increasing distances from the crest, with the exception of the sediment drilled in the deepest trough known in the Siqueiros fracture zone. The anomalous age obtained at the latter site suggests that the basalt which was drilled may represent fracture zone volcanism. Paleoenvironmental analysis using the planktonic foraminifers at the EPR sites indicated the presence of environmental cycles of shorter wave length during the interval from 0 to 0.24 Ma, whereas cycles of longer wave length occurred from 0.43 to 2.17 Ma. The planktonic foraminiferal taphocoenoses at the EPR sites were strongly affected by selective dissolution which indicated that these EPR sites have been near either the lysocline or carbonate compensation surface since the upper Pliocene. The planktonic foraminiferal thanatocoenoses at the GSC sites were preserved better than those at the EPR sites. The number of planktonic foraminiferal species generally was greatly reduced in the green mud associated with the GSC hydrothermal mounds. More species were found in older than in younger green mud; this suggests that there probably was an increase in the rate of production of green mud sometime after the initiation of the hydrothermal system.