Concentrations of labile dissolved forms of Cu, Zn, Pb, and Cu in waters of the Kara Sea and Ob and Yenisey estuaries

Concentrations of labile dissolved forms of Cu, Zn, Pb, and Cu in waters of the Kara Sea and Ob and Yenisey estuaries measured on board during Cruise 49 of R/V Dmitry Mendeleev.

Biomarkers in surface sediments from the Ob and Yenisei estuaries and the southern Kara Sea

Organic-geochemical bulk parameter (Total organic carbon contents, C/N ratios and d13Corg values), biogenic opal and biomarkers (n-alkanes, fatty acids, sterols and amino acids) were determined in surface sediments from the Ob and Yenisei estuaries and the adjacent southern Kara Sea. Maximum TOC contents were determined in both estuaries, reaching up to 3 %. Relatively high C/N ratios around 10, light d13Corg values of -26.5 per mil (Yenisei) and -28 to -28.7 per mil (Ob), and maximum concentrations of long-chain n-alkanes of up to about 10 µg/g Sed clearly show the predominance of terrigenous organic matter in the sediments from the estuaries. Towards the open Kara Sea, all p arameters indicate a decrease in terrigenous organic carbon. Brassicasterol as well as the short-chain n-alkanes parallel this trend, suggesting that these biomarkers are probably also related to a terrigenous (fresh-water phytoplankton) source. Amino acid spectra show characteristic trends from the Yenisei Estuary to the open Kara Sea revealing increasing state of degradation. Sedimentary organic matter in the Yenisei Estuary is relatively less degraded compared to the Ob Estuary and the open Kara Sea.

(Table 1) Vertical fluxes of sediment matter and organic carbon in the Kara Sea and in the Yenisey and Ob estuaries

Sedimentary particle fluxes in the Kara Sea and in the Ob and Yenisey estuaries were first estimated and particulate matter composition was studied in September 1993 during Cruise 49 of R/V Dmitry Mendeleev. Twenty three bottom stations with sediment traps were deployed, and samples were collected from 13 stations. Particle fluxes ranged from 9.0 to 62.6 mg/m**2/day to the north of the Ob and Yenisey estuaries and were 18.7 to 62.0 mg/m**2/day in the southwestern part of the Kara Sea. Fluxes were up to 1321 mg/m**2/day in the Ob estuary and up to 22156 mg/m**2/day in the Yenisey estuary. Organic matter fluxes were estimated as 0.71-3.29, 4.28-9.04, 26.7, and 368 mg/m**2/day, respectively. Particulate matter is largely represented by pellets of planktic Crustacea and by "sea snow" flakes mainly composed of diatoms. Rapidly settling particles are extensively inhabited by bacterial flora.

The number of plastic particles found in estuarine sediment and water samples of five estuaries, Durban, KwaZulu-Natal, South Africa

Widespread disposal of plastics negatively affects biotic and abiotic components of marine systems. Monitoring plastics transitioning through estuaries is vital in assessing terrestrial inputs to oceanic environments. Data on microplastics (particles <= 5mm) in estuaries are scant. This study determined microplastic levels within five estuaries along the Durban coastline and on intervening beaches. Plastics were isolated from estuarine sediment, beach sediment and the surface water of each estuary and characterised. Sediment at the Bayhead area of Durban Harbour was found to contain the highest average plastic concentrations (745.40 ± 129.72 particles per 500ml). Overall an attenuating concentration trend away from the city center was found. Fragments composed the largest percent of plastics (59 %) found in Bayhead, whereas fibers dominated other estuaries (Mdloti - 66 %, uMgeni - 38 %, Isipingo - 45 % and iLovu - 53 %). Plastic particle concentration in estuarine sediment generally increased from larger to smaller size classes. If high input and high retention in the harbour is coupled with high organic and metal pollutant loads, this area can become (if not already) a major environmental hazard.

Total organic carbon in surface sediments of the Ob and Yenisei estuaries and adjacent coastal areas, appendix 1

Two main mechanisms are controlling the accumulation of organic matter in the sediments of the Kara Sea. The large rivers Ob and Yenisei supply significant quantities of freshwater onto the shelf (Lisitsyn and Vinogradov, 1995; Bobrovitskaya et al., 1996; Johnson et al., 1997) and deliver terrigenous organie matter and aquatic algae. Additionally, marine organic matter is produced in the water column. In order to distinguish between the different sources of the organic material maceral analysis, organic-geochemical bulk Parameters and biomarkers (short- and long-chain D-alkanes, fatty acids and pigments) were used to determine the quality (marine vs. terrigenous) and quantity of the organic carbon fraction in the surface sediments taken during the 28th cruise of RV Akademik Boris Petrov (Matthiessen and Stepanets, 1998) (Fig. 1). Previous organic-geochemical investigations (i.e., total organic-carbon content (TOC), hydrogen indices (Hl), CIN-ratios) indicate the importance of terrigenous input of organic matter (Galimov et al., 1996; Stein, 1996). Studies of lipid biomarkers in surface sediments in the Ob estuary show also a predominance of terrestrial constituents and an increase in planktonogenic and bacterial lipids further offshore (Belyaeva and Eglinton, 1997). In complex systems such as the Eurasian continental margin characterized by high input of terrestriallaquatic organic matter and strong seasonal variation in sea-ice Cover and primary productivity, the Interpretation of the organic geochemical data is much more complicated and restricted in comparison to similar data Sets from low-latitude open-ocean environments (Fahl and Stein, 1998). Microscopical studies (maceral analysisl palynology), however, allow a direct visual inspection of the particulate organic matter and allow to differentiate particles of different biological sources. Thus, a combination of both methods as shown in this study, yields a more precise identification of organic-carbon sources.