(Table, page 95) Chemistry of bog manganese concretions and wad from the Columbia County, New York

Bog manganese was long ago reported from various places in Columbia county (1:54) and it seemed well to reexamine these occurrences. According to W. W. Mather in his report of the First District Survey, 1836-42, " in the counties of Columbia and Dutchess 50,000 tons of manganese could be procured without any great expense, if carefully prepared." He also stated that some of the bog manganese showed on analysis as high as 68.5 per cent manganese oxide and less than 5 per cent silica. At the direction of the State Geologist the writer has devoted most of the summer of 191 7 to this work. The results of this investigation, though not in any way confirming the quantitative results of Mr Mather, are herewith published as a matter of record and as an account of the manner of the occurrence and the genesis of postglacial bog manganese.

Biogenic sedimentation of DSDP Site 85-574

The equatorial Pacific is an important part of the global carbon cycle and has been affected by climate change through the Cenozoic (65 Ma to present). We present a Miocene (12-24 Ma) biogenic sediment record from Deep Sea Drilling Project (DSDP) Site 574 and show that a CaCO3 minimum at 17 Ma was caused by elevated CaCO3 dissolution. When Pacific Plate motion carried Site 574 under the equator at about 16.2 Ma, there is a minor increase in biogenic deposition associated with passing under the equatorial upwelling zone. The burial rates of the primary productivity proxies biogenic silica (bio-SiO2) and biogenic barium (bio-Ba) increase, but biogenic CaCO3 decreases. The carbonate minimum is at ~17 Ma coincident with the beginning of the Miocene climate optimum; the transient lasts from 18 to 15 Ma. Bio-SiO2 and bio-Ba are positively correlated and increase as the equator was approached. Corg is poorly preserved, and is strongly affected by changing carbonate burial. Terrestrial 232Th deposition, a proxy for aeolian dust, increases only after the Site 574 equator crossing. Since surface production of bio-SiO2, bio-Ba, and CaCO3 correlate in the modern equatorial Pacific, the decreased CaCO3 burial rate during the Site 574 equator crossing is driven by elevated CaCO3 dissolution, representing elevated ocean carbon storage and elevated atmospheric CO2. The length of the 17 Ma CaCO3 dissolution transient requires interaction with a 'slow' part of the carbon cycle, perhaps elevated mantle degassing associated with the early stages of Columbia River Basalt emplacement.