(Table 1) Cation exchange capacity and other characteristics of soils common in Lower Saxony, Germany

The chemical and biochemical processes associated with the filtration of rainwater through soils, a step in groundwater recharge, were investigated. Under simulated climatic conditions in the laboratory, undisturbed soil columns of partly loamy sands, sandy soils and loess were run as lysimeters. A series of extraction procedures was carried out to determine solid matter in unaltered rock materials and in soil horizons. Drainage water and moisture movement in the columns were analysed and traced respectively. The behaviour of soluble humic substance was investigated by percolation and suspension experiments. The development of seepage-water in the unsaturated zone is closely associated with the soil genetic processes. Determining autonomous chemical and physical parameters are mineral composition and grain size distribution in the original unconsolidated host rock and prevailing climatic conditions. They influence biological activity and transport of solids, dissolved matter and gases in the unsaturated zone. Humic substances, either as amorphous solid matter or as soluble humic acids play a part in diverse sorption, solution and precipitation processes.

Heavy metal concentrations in soils, vegetation, earthworms and wood mice from Heteren and Plateaux, The Netherlands

Effects of soil properties on the accumulation of metals to wood mice (Apodemus sylvaticus) were evaluated at two sites with different pH and organic matter content of the soil. pH and organic matter content significantly affected accumulation of Cd, Cu, Pb and Zn in earthworms and vegetation. For Cd, Cu and Zn these effects propagated through the food web to the wood mouse. Soil-to-kidney ratios differed between sites: Cd: 0.15 versus 3.52, Cu: 0.37 versus 1.30 and Zn: 0.33-0.83. This was confirmed in model calculations for Cd and Zn. Results indicate that total soil concentrations may be unsuitable indicators for risks that metals pose to wildlife. Furthermore, environmental managers may, unintentionally, change soil properties while taking specific environmental measures. In this way they may affect risks of metals to wildlife, even without changes in total soil concentrations.

Organic carbon and total nitrogen stocks in soils of the Lena River Delta

The Lena River Delta, which is the largest delta in the Arctic, extends over an area of 32 000 km**2 and likely holds more than half of the entire soil organic carbon (SOC) mass stored in the seven major deltas in the northern permafrost regions. The geomorphic units of the Lena River Delta which were formed by true deltaic sedimentation processes are a Holocene river terrace and the active floodplains. Their mean SOC stocks for the upper 1 m of soils were estimated at 29 kg/m**2 ± 10 kg/m**2 and at 14 kg/m**2 ± 7 kg/m**2, respectively. For the depth of 1 m, the total SOC pool of the Holocene river terrace was estimated at 121 Tg ± 43 Tg, and the SOC pool of the active floodplains was estimated at 120 Tg ± 66 Tg. The mass of SOC stored within the observed seasonally thawed active layer was estimated at about 127 Tg assuming an average maximum active layer depth of 50 cm. The SOC mass which is stored in the perennially frozen ground at the increment 50-100 cm soil depth, which is currently excluded from intense biogeochemical exchange with the atmosphere, was estimated at 113 Tg. The mean nitrogen (N) stocks for the upper 1 m of soils were estimated at 1.2 kg/m**2 ± 0.4 kg/m**2 for the Holocene river terrace and at 0.9 kg/m**2 ± 0.4 kg/m**2 for the active floodplain levels, respectively. For the depth of 1 m, the total N pool of the river terrace was estimated at 4.8 Tg ± 1.5 Tg, and the total N pool of the floodplains was estimated at 7.7 Tg ± 3.6 Tg. Considering the projections for deepening of the seasonally thawed active layer up to 120 cm in the Lena River Delta region within the 21st century, these large carbon and nitrogen stocks could become increasingly available for decomposition and mineralization processes.

Analysis of soils from King George Island and Casey station, Antarctica

A comparative study was carried out on soils of the maritime (Arctowski, King George Island) and the continental (Casey, Wilkes Land) Antarctic. Soil sampIes are described for surface layers (0-10 cm) by their in situ temperature profiles as well as by field and laboratory analyses of grain sizes, pH and nutrient contents. Active cryoturbation is a main factor of mixing processes in surfaces with high silt and clay content. In both regions processes of podzolisation were recognized. Microclimatic conditions show the importance of small scale processes which are of special importance for freeze-thaw cycles. The distribution of nutrients and other inorganic components is rather homogeneous in regosols and leptosols. But in soils with organic top layers by lichen and moss cushions (crusts) accumulation occurs as well as displacement of metal ions into deeper layers (>10 cm). Histosols show patterns of brown soils. Special attention is given to the origin of nitrogen compounts and the different ways of import of other components (e.g. chloride) into the Antarctic system are discussed.

Specific microbial biomarker signatures from Congo fan sediments of ODP site 175-1075, Congo soils, wetland and estuary sediments

Methane (CH4) is a strong greenhouse gas known to have perturbed global climate in the past, especially when released in large quantities over short time periods from continental or marine sources. It is therefore crucial to understand and, if possible, quantify the individual and combined response of these variable methane sources to natural climate variability. However, past changes in the stability of greenhouse gas reservoirs remain uncertain and poorly constrained by geological evidence. Here, we present a record from the Congo fan of a highly specific bacteriohopanepolyol (BHP) biomarker for aerobic methane oxidation (AMO), 35-aminobacteriohopane-30,31,32,33,34-pentol (aminopentol), that identifies discrete periods of increased AMO as far back as 1.2 Ma. Fluctuations in the concentration of aminopentol, and other 35-aminoBHPs, follow a pattern that correlates with late Quaternary glacial-interglacial climate cycles, with highest concentrations during warm periods. We discuss possible sources of aminopentol, and the methane consumed by the precursor methanotrophs, within the context of the Congo River setting, including supply of methane oxidation markers from terrestrial watersheds and/or marine sources (gas hydrate and/or deep subsurface gas reservoir). Compound-specific carbon isotope values of -30 per mil to -40 per mil for BHPs in ODP 1075 and strong similarities between the BHP signature of the core and surface sediments from the Congo estuary and floodplain wetlands from the interior of the Congo River Basin, support a methanotrophic and likely terrigenous origin of the 35-aminoBHPs found in the fan sediments. This new evidence supports a causal connection between marine sediment BHP records of tropical deep sea fans and wetland settings in the feeding river catchments, and thus tropical continental hydrology. Further research is needed to better constrain the different sources and pathways of methane emission. However, this study identifies the large potential of aminoBHPs, in particular aminopentol, to trace and, once better calibrated and understood, quantify past methane sources and fluxes from terrestrial and potentially also marine sources.

Morphological, chemical and physical characteristics of cryosolic soils from Arctic Canada

Cryosols are permafrost-affected soils whose genesis is dominated by cryogenic processes, resulting in unique macromorphologies, micromorphologies, thermal characteristics, and physical and chemical properties. In addition, these soils are carbon sinks, storing high amounts of organic carbon collected for thousands of years. In the Canadian soil classification, the Cryosolic Order includes mineral and organic soils that have both cryogenic properties and permafrost within 1 or 2 m of the soil surface. This soil order is divided into Turbic, Static and Organic great groups on the basis of the soil materials (mineral or organic), cryogenic properties and depth to permafrost. The great groups are subdivided into subgroups on the basis of soil development and the resulting diagnostic soil horizons. Cryosols are commonly associated with the presence of ground ice in the subsoil. This causes serious problems when areas containing these soils are used for agriculture and construction projects (such as roads, town sites and airstrips). Therefore, where Cryosols have high ice content, it is especially important either to avoid these activities or to use farming and construction methods that maintain the negative thermal balance.

Characteristics of soils from the Quartermain Mountain area, Antarctica

Soil-forming processes and soil development rates are compared and contrasted on glacial deposits in two adjacent and coeval valleys of the Quartermain Mountains, which are important because they display Miocene glacial stratigraphy and some of the oldest landforms in the McMurdo Dry Valleys. More than 100 soil profiles were examined on seven drift sheets ranging from 115 000 to greater than 11.3 million years in age in Beacon Valley and Arena Valley. Although the two valleys contain drifts of similar age, they differ markedly in ice content of the substrate. Whereas Arena Valley generally has 'dry-frozen' permafrost in the upper 1 m and minimal patterned ground, Beacon Valley contains massive ice buried by glacial drift and ice-cored rock glaciers and has ice-cemented permafrost in the upper 1 m and considerable associated patterned ground. Arena Valley soils have twice the rate of profile salt accumulation than Beacon Valley soils, because of lower available soil water and minimal cryoturbation. The following soil properties increase with age in both valleys: weathering stage, morphogenetic salt stage, thickness of the salt pan, the quantity of profile salts, electrical conductivity of the horizon of maximum salt enrichment, and depth of staining. Whereas soils less than 200 000 years and older soils derived from sandstone-rich ground moraine are Typic Anhyorthels and Anhyturbels, soils of early Quaternary and older age, particularly on dolerite-rich drifts, are Petronitric Anhyorthels. Arena Valley has the highest pedodiversity recorded in the McMurdo Dry Valleys. The soils of the Quartermain Mountains are the only soils in the McMurdo Dry Valleys known to contain abundant nitrates.

Soil chemistry and particle size distribution of mountainous tundra soils in the Rai-Iz Massif

Gravelly clay loamy and clayey soils developed from the derivatives of ultramafic rocks of the dunite-harzburgite complex of the Rai-Iz massif in the Polar Urals have been studied. They are represented by raw-humus pelozems (weakly developed clayey soils) under conditions of perfect drainage on steep slopes and by the gleyzems (Gleysols) with vivid gley color patterns in the eluvial positions on leveled elements of the relief. The magnesium released from the silicates with the high content of this element (mainly from olivine) specifies the neutral-alkaline reaction in these soils. Cryoturbation, the accumulation of raw humus, the impregnation of the soil mass with humic substances, gleyzation, and the ferrugination of the gleyed horizons are also clearly pronounced in the studied soils. Despite the high pH values, the destruction of supergene smectites in the upper horizons and ferrugination (the accumulation of iron hydroxides) in the microfissures dissecting the grains of olivine, pyroxene, and serpentine, and in decomposing plant tissues take place. The development of these processes may be related to the local acidification (neutralization) of the soil medium under the impact of biota and carbonic acids. The specificity of gleyzation in the soils developing from ultra-mafic rocks is shown in the absence of iron depletion from the fine earth material against the background of the greenish blue gley color pattern.

Chemical composition of soils and rocks from King George Island

Both the olivine-hearing tholeiite basalts of the island and the brown soils which have developed on the basalts contain 2-20% of a swelling clay mineral. It emerges from chemical, optical, X-ray diffraction and differential thermal analytical studies that this clay mineral is a Mg-rich, Fe2+ and AI-bearing tri-octahedral smectite, e. g. Mg-saponite. Due to petrographic and crystal chemical properties the saponite should have been formed by hydrothermal alteration of the primary Mg-Fe-minerals olivine and clinopyroxene. The soils consist of plagioclase, saponite and goethite which has been formed by chemical weathering within the soils. In the uppermost layer some of the soils contain humic substances and phosphatic material, the latter may be related to the recent production of guano.