AMS radiocarbon dates and pollen analysis of ODP Hole 175-1078C

ODP Site 1078 situated under the coast of Angola provides the first record of the vegetation history for Angola. The upper 11 m of the core covers the past 30 thousand years, which has been analysed palynologically in decadal to centennial resolution. Alkenone sea surface temperature estimates were analysed in centennial resolution. We studied sea surface temperatures and vegetation development during full glacial, deglacial, and interglacial conditions. During the glacial the vegetation in Angola was very open consisting of grass and heath lands, deserts and semi-deserts, which suggests a cool and dry climate. A change to warmer and more humid conditions is indicated by forest expansion starting in step with the earliest temperature rise in Antarctica, 22 thousand years ago. We infer that around the period of Heinrich Event 1, a northward excursion of the Angola Benguela Front and the Congo Air Boundary resulted in cool sea surface temperatures but rain forest remained present in the northern lowlands of Angola. Rain forest and dry forest area increase 15 thousand years ago. During the Holocene, dry forests and Miombo woodlands expanded. Also in Angola globally recognised climate changes at 8 thousand and 4 thousand years ago had an impact on the vegetation. During the past 2 thousand years, savannah vegetation became dominant.

AMS radiocarbon dates and pollen analysis from Zugspitzplatt

On the strongly karstified and almost unvegetated surface of the Zugspitzplatt, at an altitude of about 2290 m in the Wettersteingebirge, there is a doline within which over a period of several thousand years a bed of fine loess-like sediment, almost 1m thick, has accumulated. Notwithstanding the situation of this locality far above the present tree-line, this infill contains quantities of pollen and spores sufficient for pollen analysis without use of any enrichment techniques. Despite poor pollen preservation, it was possible to date the basal layers of this profile on the basis of their pollen assemblages. AMS dating (7415 ± 30 BP) has confirmed that the oldest sediments were laid down during the early Atlantic period, the time of the thermal optimum of the Holocene. At least since that time this site has never been overridden by a glacier. The moraine associated with the Löbben Oscillation between 3400 and 3100 BP - here represented by the so-called Platt Stillstand (Plattstand) - did not quite reach the doline. A diagram shows known Holocene glacial limits. The composition of the pollen assemblages from the two oldest levels with high pollen concentrations strongly suggests that the distance between the doline and the forest was much less during the Atlantic than at present.

AMS 14C ages and isotopic compositions of samples from the Derugin Basin, Sea of Okhotsk

An area of massive barite precipitations was studied at a tectonic horst in 1500 m water depth in the Derugin Basin, Sea of Okhotsk. Seafloor observations and dredge samples showed irregular, block- to column-shaped barite build-ups up to 10 m high which were scattered over the seafloor along an observation track 3.5 km long. High methane concentrations in the water column show that methane expulsion and probably carbonate precipitation is a recently active process. Small fields of chemoautotrophic clams (Calyptogena sp., Acharax sp.) at the seafloor provide additional evidence for active fluid venting. The white to yellow barites show a very porous and often layered internal fabric, and are typically covered by dark-brown Mn-rich sediment; electron microprobe spectroscopy measurements of barite sub-samples show a Ba substitution of up to 10.5 mol% of Sr. Rare idiomorphic pyrite crystals (~1%) in the barite fabric imply the presence of H2S. This was confirmed by clusters of living chemoautotrophic tube worms (1 mm in diameter) found in pores and channels within the barite. Microscopic examination showed that micritic aragonite and Mg-calcite aggregates or crusts are common authigenic precipitations within the barite fabric. Equivalent micritic carbonates and barite carbonate cemented worm tubes were recovered from sediment cores taken in the vicinity of the barite build-up area. Negative d13C values of these carbonates (>-43.5 per mill PDB) indicate methane as major carbon source; d18O values between 4.04 and 5.88 per mill PDB correspond to formation temperatures, which are certainly below 5°C. One core also contained shells of Calyptogena sp. at different core depths with 14C-ages ranging from 20 680 to >49 080 yr. Pore water analyses revealed that fluids also contain high amounts of Ba; they also show decreasing SO4**2- concentrations and a parallel increase of H2S with depth. Additionally, S and O isotope data of barite sulfate (d34S: 21.0-38.6 per mill CDT; d18O: 9.0-17.6 per mill SMOW) strongly point to biological sulfate reduction processes. The isotope ranges of both S and O can be exclusively explained as the result of a mixture of residual sulfate after a biological sulfate reduction and isotopic fractionation with 'normal' seawater sulfate. While massive barite deposits are commonly assumed to be of hydrothermal origin, the assemblage of cheomautotrophic clams, methane-derived carbonates, and non-thermally equilibrated barite sulfate strongly implies that these barites have formed at ambient bottom water temperatures and form the features of a Giant Cold Seep setting that has been active for at least 49 000 yr.

Sedimentary history and chemical characteristics of clay minerals from the Bengal Fan

The purpose of this study is to clarify the sedimentary history and chemical characteristics of clay minerals found in sediments deposited in the distal part of the Bengal Fan since the Himalayas were uplifted 17 m.y. ago. A total of seventy-eight samples were collected from three drilled cores which were to be used for the clay mineral analyses by means of XRD and ATEM. The results obtained from the analyses show that individual clay mineral species in the sediment samples at each site have similar features when the samples are of the same age, whereas these species have different features in samples of differing geological ages. Detrital clay minerals such as illite and chlorite were deposited in greater amounts than kaolinite and smectite during the Early to Middle Miocene. This means that the Himalayan uplift was vigorous at least until the Middle Miocene. In the Pliocene chemical weathering was more prevalent so that instead, in the distal part of the Bengal Fan, kaolinite shows the highest concentrations. This would accord with weaker uplift in the Himalayas. In the Pleistocene period, vigorous Himalayan uplift is characterized by illite-rich sediment in place of kaolinite. In the Holocene, smectite shows the highest concentration in place of the illite and kaolinite which were the predominant clay minerals of the earlier periods. Increasing smectite concentration suggests the Himalayan uplift to have been stable after the Pleistocene period. The smectite analyzed here is found to be dioctahedral Fe-beidellite, and it originated largely from the augite-basalt on the Indian Deccan Traps. The tri-octahedral chlorite is subdivided into three sub-species, an Fe-type, a Mg-type and an intermediate type. The mica clay mineral can be identified as di-octahedral illite which is rich in potassium. The chemical composition and morphology of each clay mineral appears to exhibit no change with burial depth in the sedimentary columns. This implies that there was no systematic transformation of clay minerals with time.

The effects of trans-generational exposure to ocean warming and acidification on life history and physiological traits in a marine polychaete

Human-assisted, trans-generational exposure to ocean warming and acidification has been proposed as a conservation and/or restoration tool to produce resilient offspring. To improve our understanding of the need for and the efficacy of this approach, we characterised life history and physiological responses in offspring of the marine polychaete Ophryotrocha labronica exposed to predicted ocean warming (OW: + 3 °C), ocean acidification (OA: pH -0.5) and their combination (OWA: + 3 °C, pH -0.5), following the exposure of their parents to either control conditions (within-generational exposure) or the same conditions (trans-generational exposure). Trans-generational exposure to OW fully alleviated the negative effects of within-generational exposure to OW on fecundity and egg volume and was accompanied by increased metabolic activity. While within-generational exposure to OA reduced juvenile growth rates and egg volume, trans-generational exposure alleviated the former but could not restore the latter. Surprisingly, exposure to OWA had no negative impacts within- or trans-generationally. Our results highlight the potential for trans-generational laboratory experiments in producing offspring that are resilient to OW and OA. However, trans-generational exposure does not always appear to improve traits, and therefore may not be a universally useful tool for all species in the face of global change.