Carbonate preservation reconstructed from ODP Sites 154-927 and 154-929 at Ceará Rise

Enhanced Atlantic overturning during the Pliocene was first proposed almost 10 yrs ago. Evidence for this Pliocene super conveyor scenario has been collected using a number of proxies (e.g., benthic d13C, Nd isotopic composition of manganese crusts). The present study contributes to the existing evidences by using carbonate dissolution and current vigour history of early Pliocene sediments from the Ceará Rise (ODP Sites 927 and 929). In order to reveal carbonate dissolution history, a number of commonly used and newly established proxies were applied, i.e., sand and carbonate contents, foraminifer fragmentation index, Bulloides Dissolution Index and carbonate silt grain-size distributions. Terrigenous silt grain-size distributions were used to unravel variations in relative current strength and sediment input to the two sites. Overall good carbonate preservation at the shallow Site 927 (3314 m water depth) shows that this level was bathed in North Atlantic Deep Water throughout the early Pliocene. The contrastingly poor carbonate preservation record of the deeper Site 929 (4358 m water depth, at present exposed to Antarctic Bottom Water) is frequently interrupted by phases of good carbonate preservation. These results indicate that the depth of the calcite lysocline was mainly tied to present level (ab. 4200 m water depth), and sometimes even dropped to water depths greater than 4360 m due to even more enhanced circulation. Surprisingly the expansion of NADW is not clearly reflected by an increase in current speed as shown by continuously fine terrigenous grain size.

Magnetic extracts of three gravity cores located at the Ceará Rise, the Mid-Atlantic Ridge and the Sierra Leone Rise

The magnetic microparticle and nanoparticle inventories of marine sediments from equatorial Atlantic sites were investigated by scanning and transmission electron microscopy to classify all present detrital and authigenic magnetic mineral species and to investigate their regional distribution, origin, transport, and preservation. This information is used to establish source-to-sink relations and to constrain environmental magnetic proxy interpretations for this area. Magnetic extracts were prepared from sediments of three supralysoclinal open ocean gravity cores located at the Ceará Rise (GeoB 1523-1; 3°49.9'N/41°37.3'W), the Mid-Atlantic Ridge (GeoB 4313-2; 4°02.8'N/33°26.3'W), and the Sierra Leone Rise (GeoB 2910-1; 4°50.7'N/21°03.2'W). Sediments from two depths corresponding to marine isotope stages 4 and 5.5 were processed. This selection represents glacial and interglacial conditions of sedimentation for the western, central, and eastern equatorial Atlantic and avoids interferences from subsurface and anoxic processes. Crystallographic, elemental, morphological, and granulometric data of more than 2000 magnetic particles were collected by scanning and transmission electron microscopy. On basis of these properties, nine particle classes could be defined: detrital magnetite, titanomagnetite (fragmental and euhedral), titanomagnetite-hemoilmentite intergrowths, silicates with magnetic inclusions, microcrystalline hematite, magnetite spherules, bacterial magnetite, goethite needles, and nanoparticle clusters. Each class can be associated with fluvial, eolian, subaeric, and submarine volcanic, biogenic, or chemogenic sources. Large-scale sedimentation patterns are delineated as well: detrital magnetite is typical of Amazon discharge, fragmental titanomagnetite is a submarine weathering product of mid-ocean ridge basalts, and titanomagnetite-hemoilmenite intergrowths are common magnetic particles in West African dust. This clear regionalization underlines that magnetic petrology is an excellent indicator of source-to-sink relations. Hematite encrustations, magnetic spherules, and nanoparticle clusters were found at all investigated sites, while bacterial magnetite and authigenic hematite were only detected at the more oxic western site. At the eastern site, surface pits and crevices were seen on the crystal faces indicating subtle early diagenetic reductive dissolution. It was observed that paleoclimatic signatures of magnetogranulometric parameters such as the ratio of anhysteretic and isothermal remanent magnetizations can be formed either by mixing of multiple sources with separate, relatively narrow grain size ranges (western site) or by variable sorting of a single source with a broad grain size distribution (eastern site). Hematite, goethite, and possibly ferrihydrite nanoparticles occur in all sediment cores studied and have either high-coercive or superparamagnetic properties depending on their partly ultrafine grain sizes. These two magnetic fractions are generally discussed as separate fractions, but we suggest that they could actually be genetically linked.

Stable isotopes of foraminifers, mineralogy and ages of sediment core GeoB1523-1

Today the western tropical Atlantic is the most important passage for cross-equatorial transfer of heat in the form of warm surface water flowing from the South into the North Atlantic. Circulation changes north of South America may thus have influenced the global thermohaline circulation system and high northern latitude climate. Here we reconstruct late Quaternary variations of western equatorial Atlantic surface circulation and Amazon lowland climate obtained from a multiproxy sediment record from Ceará Rise. Variations in the illite/smectite ratio suggest drier climatic conditions in the Amazon Basin during glacials relative to interglacials. The 230Thex-normalized fluxes and the 13C/12C record of organic carbon indicate that sea level fluctuations, shelf topography, and changes of the surface circulation pattern controlled variations and amplitude of terrigenous sediment supply to the Ceará Rise. We attribute variations in thermocline depth, reconstructed from vertical planktic foraminiferal oxygen isotope gradients and abundances of the phytoplankton species Florisphaera profunda, to changes in southeast trade wind intensity. Strong trade winds during ice volume maxima are associated with a deep western tropical Atlantic thermocline, strengthening of the North Brazil Current retroflection, and more vigorous eastward flow of surface waters.

X-ray fluorescence (XRF) measurements of two sediment cores from the Ceara Rise

Die XRF-Daten wurden an Archivhälften der Schwerelotkerne GeoB4402-2 und GeoB4407-3 erhoben, die am Nordwest-Hang des Ceará-Rückens gezogen wurden. Der Ceará-Rücken liegt im westlichen, äquatorialen Atlantik im Ablagerungsgebiet des Amazonas. Die Messdaten wurden mit dem XRF-Kern-Scanner "CORETEX (Corescanner Texel)" im Marum in Bremen erhoben, der auf dem Prinzip der Röntgenfluoreszenzanalyse beruht (gemessene Auflösung: 1 cm). Der Sedimenteintrag, speziell der Eintrag von terrigenem Material (durch Verwitterung entstandenes Material auf den Kontinenten), in die Ozeane ist ein immer noch schlecht verstandener Prozess, der aber für eine Vielzahl von geologischen Fragestellungen von entscheidender Bedeutung ist. Der terrigene Sedimenteintrag am Ceará-Rücken ist nahezu ausschließlich vom Amazonas geprägt. Die abgelagerten Sedimente auf dem Ceará-Rücken können als Zwei-Komponentensystem beschrieben werden. Eine Quelle ist der terrigene Eintrag aus dem Amazonas. Die zweite Quelle ist biogenes Kalziumkarbonat, dass vom kalkigen Plankton (vor allem Coccolithophoriden und zum Teil Foraminiferen) aus der oberen Wassersäule stammt. Heutzutage ist der westliche, tropische Atlantik die Hauptpassage des Transfers von warmem Oberflächenwasser vom Süd- in den Nordatlantik. Die Abgabe von Wärme und Feuchtigkeit aus den Tropen könnte im Zusammenhang mit kurzfristigen Klimawechseln stehen. Untersuchungen an Hand von Aufzeichnungen aus der nördlichen Hemisphäre weisen darauf hin, dass kurzfristige Klimaschwankungen der Nordhemisphäre zu Veränderungen der atmosphärischen Zirkulation in niedrigen Breiten auf einer Zeitskala von nur wenigen Tausenden Jahren führen können. Eine wichtige Frage dabei ist, wie der spätpleistozäne Eintrag von Terrigen-Material durch den Amazonas gesteuert ist durch Klimaschwankungen in den Tropen in Wechselwirkung mit den Vereisungs- und Abschmelzphasen der Nordhemisphäre. Hierbei sind sowohl die Glazial-Interglazial Zyklen als auch kurzfristige Klimaschwankungen wie die Dansgaard-Oeschger-Zyklen und die mit ihnen verbundenen Heinrich-Ereignisse von Bedeutung.

Radionuclides and accumulation rates of sediments from the equatorial Atlantic

Variations in carbonate flux and dissolution, which occurred in the equatorial Atlantic during the last 24,000 years, have been estimated by a new approach that allows the point-by-point determination of paleofluxes to the seafloor. An unprecedented time resolution can thus be obtained which allows sequencing of the relatively rapid events occurring during deglaciation. The method is based on observations that the flux of unsupported 230Th into deep-sea sediments is nearly independent of the total mass flux and is close to the production rate. Thus excess 230Th activity in sediments can be used as a reference against which fluxes of other sedimentary components can be estimated. The study was conducted at two sites (Ceará Rise; western equatorial Atlantic, and Sierra Leone Rise; eastern equatorial Atlantic) in cores raised from three different depths at each site. From measurements of 230Th and CaCO3, changes in carbonate flux with time and depth were obtained. A rapid increase in carbonate production, starting at the onset of deglaciation, was found in both areas. This event may have important implications for the postglacial increase in atmospheric CO2 by increasing the global carbonate carbon to organic carbon rain ratio and decreasing the alkalinity of surface waters (and possibly the North Atlantic Deep Water). Increased carbonate dissolution occurred in the two regions during deglaciation, followed by a minimum during mid-Holocene and renewed intensification of dissolution in late Holocene. During the last 16,000 years, carbonate dissolution was consistently more pronounced in the western than in the eastern basin, reflecting the influence of Antarctic Bottom Water in the west. This trend was reversed during stage 2, possibly due to the accumulation of metabolic CO2 below the level of the Romanche Fracture Zone in the eastern basin.

Silt grain-size analysis of ODP holes from the western equatorial Atlantic

Grain-size records of the terrigenous and calcareous silt fraction, preservation of planktic foraminifera, and benthic foraminiferal stable-isotope data (delta13C, delta18O values of C. wuellerstorfi) at ODP Site 927 on the Ceará Rise (5°27.7'N, 44°28.8'W), are used to reconstruct variations in the history of bottom current strength, ventilation, and carbonate corrosiveness of deep waters during the time interval from 0.8 to 0.3 Ma. Glacial periods are characterized by generally smaller mean sizes of the terrigenous sortable silt fraction (mean(SS)), lower delta13C values, and poorer preservation of planktic foraminifera compared to interglacials. This indicates lower bottom current speeds, larger nutrient contents and more corrosive deep water. By contrast, larger mean(SS) sizes, higher delta13C values, and well preserved planktic foraminifera indicate strong circulation and a well ventilated deep-water mass during interglacials. The observed changes are most likely related to the weakening and strengthening of circulation of Lower North Atlantic Deep Water (LNADW). Cross-spectral analysis between the mean(SS) and benthic delta18O records reveals that minima in mean(SS) occur about 7.6 k.y. after the maximum in ice volume. This indicates a considerable lag time between ice-shield induced changes in LNADW production and subsequent changes in the velocity of LNADW flow in the western equatorial Atlantic. Striking changes in bottom current speed occur regularly during glacial to interglacial transitions. Extremely fine mean(SS) minima point to an almost complete shutdown of bottom current vigor in response to a cessation of LNADW production caused by an enhanced melt water release during the initial phases of deglaciation. However, each of the fine minima extremes is followed by a rapid shift to very high mean(SS) values that indicate strong bottom currents, and hence, vigorous LNADW flow during the early interglacials. After the onset of glacial Stage 12, generally poorer carbonate preservation and higher variability is registered. This coincides with a global decrease in carbonate preservation during the mid-Brunhes (mid-Brunhes dissolution event). Detailed grain-size analysis of the calcareous fine fraction (<63 µm) revealed a considerable reduction of particles in the fraction from 7 to 63 µm during periods of enhanced dissolution. This indicates a preferential dissolution of larger planktic foraminiferal fragments which leads to an enrichment of coccoliths in the calcareous fine fraction.

Discarge compilation from The Global River Discharge (RivDIS) Project

The Global River Discharge (RivDIS) data set contains monthly discharge measurements for 1018 stations located throughout the world. The period of record varies widely from station to station, with a mean of 21.5 years. These data were digitized from published UNESCO archives by Charles Voromarty, Balaze Fekete, and B.A. Tucker of the Complex Systems Research Center (CSRC) at the University of New Hampshire. River discharge is typically measured through the use of a rating curve that relates local water level height to discharge. This rating curve is used to estimate discharge from the observed water level. The rating curves are periodically rechecked and recalibrated through on-site measurement of discharge and river stage.

Planktonic foraminiferal preservation in Plio/Pleistocene sediments from the western equatorial Atlantic and Caribbean

Records of mean sortable silt and planktonic foraminiferal preservation from the Ceará Rise (western equatorial Atlantic) and from the Caribbean are presented to analyze the Pliocene (3.5-2.2 Ma) to Pleistocene (1.6-0.3 Ma) evolution of near-bottom current strength and the carbonate corrosiveness of deep water. During the mid-Pleistocene climate transition (~1 Ma) a drastic decrease in glacial bottom current strength and an increase in carbonate corrosiveness is registered, demonstrating a substantial decrease in the glacial contribution of the Lower North Atlantic Deep Water (LNADW) to the Atlantic Ocean. Also, an increased sensitivity to eccentricity orbital forcing is registered after the MPT. By contrast, carbonate preservation increases considerably in the deep Caribbean in response to a strong and persistent stable contribution of Upper North Atlantic Deep Water (UNADW). We found evidence for the strongest and most stable circulation within the LNADW cell during the Northern Hemisphere cooling period between ~3.2 and 2.75 Ma. This is in agreement with the 'superconveyor model' which postulates that the highest NADW production took place prior to ~2.7 Ma. A considerable decrease in bottom current strength and planktonic foraminiferal preservation is observed synchronous with the first occurrence of large-scale continental ice sheets in the Northern Hemisphere. This documents the final termination of the 'superconveyor' at ca. 2.75 Ma. However, our data do not support a 'superconveyor' in the interval between 3.5 and 3.2 Ma when high-amplitude fluctuations in bottom current flow and preservation in planktonic foraminifera are observed. Because of the great sensitivity of NADW production to changes in surface water salinity, we assume that the high-amplitude fluctuations of LNADW circulation prior to ~3.2 Ma are linked to changes in the Atlantic salinity budget. After 2.75 Ma they are primarily controlled by ice-sheet forcing. In contrast to the stepwise deterioration of planktonic foraminiferal preservation in the western deep Atlantic, a trend toward better preservation from the Pliocene to Pleistocene is observed in the deep Caribbean. This indicates a long-term increase in the contribution of UNADW to the Atlantic Ocean.

Dinoflagellates of sediment core GeoB1523-1

Large numbers of calcareous dinoflagellate cysts and the vegetative calcareous coccoid species Thoracosphaera heimii are generally found in sediments underlying oligotrophic and/or stratified (sub)surface water environments. It is difficult to distinguish between the relative importance of these two environmental parameters on calcareous cyst and T. heimii distribution as they usually covary, but this information is essential if we want to apply cysts properly in the reconstruction of palaeoenvironments and past surface water hydrography. In the multi-proxy core GeoB 1523-1 from the Ceará Rise region in the western equatorial Atlantic Ocean (covering the past 155 ka), periods of greatest oligotrophy are not synchronous with periods of greatest stratification (Rühlemann et al., 1996, doi:10.1016/S0025-3227(96)00048-5; Mulitza et al., 1997, doi:10.1130/0091-7613(1997)025<0335:PFAROP>2.3.CO;2; 335-338; Mulitza et al., 1998, doi:10.1016/S0012-821X(98)00012-0), giving us the unique opportunity to differentiate between the effects of both parameters on cyst accumulation. The calcareous cyst record of the core reflects prominent increases in accumulation rate of nearly all observed species only during the nutrient-enriched but more stratified isotopic (sub)stages 5.5, 5.3, 5.1 and 1. In this respect, the distribution trends in the core are more similar to those of the eastern equatorial upwelling region (GeoB 1105-4) than they are to those of the oligotrophic north-eastern Brazilian continental slope (GeoB 2204-2), even though temporal changes in bioproductivity are principally in antiphase between the eastern and western equatorial regions. We conclude that stratification of the upper water column and the presence of a well-developed thermocline are probably the more important factors controlling cyst distribution in the equatorial Atlantic, whereas the state of oligotrophy secondarily influences cyst production within a well-stratified environment.