(Table 1) Upper Carboniferous spores abundances from ODP Holes 172-1062B, 172-1063A and 172-1063B

Color variations were interpreted in paleoceanographic terms for the late Pliocene-Pleistocene sediments recovered by ODP Leg 172 on deep-sea drifts at Blake-Bahama Outer Ridge and northeastern Bermuda Rise. The color-derived parameters used in interpretation included predicted carbonate content, terrigenous fluxes, and hematite content. Abundance of Upper Carboniferous spores indicates that the hematite is probably derived from the Permo-Carboniferous red beds of the Canadian Maritimes. In the last 800 kyr sedimentation pattern changes on the Blake-Bahama Outer Ridge were determined by the sediment delivery to the deep basin as well as circulation changes. Sediment delivery increased during glacials (especially during the last 500 kyr and particularly since Stage 6). A fundamental change in the thermohaline circulation occurred at about 500 ka corresponding to the end of the Mid-Pleistocene Transition period at the onset of the predominant 100-kyr climate cyclicity. Sedimentation related to WBUC had intensified at that time and had become more focused at depths below 3000 m. Changes in hematite content and sedimentation rate show a pulse of sediment via the St. Lawrence outlet at the Pliocene-Pleistocene boundary suggesting that a likely change in the hydrography/physiography of the Laurentide Ice Sheet could have been involved in the climatic and ocean circulation changes at that time.

Selected Devonian/Carboniferous boundary profiles in the Sauerland area (Rhenish massif)

Selected sections, containing Devonian/Carboniferous boundary beds, are described from the northern and northeastern margin of the Rhenish massif, especially from the Seiler region near Iserlohn and the Warstein area. These sections are from prospecting trenches, quarries and road cuts. The dominantly carbonate sequences were investigated in regard to the development of conodonts. The Devonian/Carboniferous boundary could be placed precisely in both areas by means of the phylogenetic transition from Siphonodella praesulcata to S. sulcata. Compared investigations lead to the following conclusions: - The basal part of the Hangenberg limestone is heterochronous. - The Devonian/Carboniferous boundary lies distinctly below the Hangenberg limestone, i. e. at the same stratigraphical level as the Stockum limestone. - The Imitoceras limestone lens of Stockum and the Stockum limestone represent a special facies within the Hangenberg schists. 80th belong either to the praesulcata- and sulcata-zone or are restricted only to the sulcata-zone. - Protognathodus kuehni appears together with Siphonodella sulcata. Where S. sulcata is lacking, P. kuehni may be considered as a valid index conodont indicating the beginning of the Carboniferous. - The upper part of the Wocklum beds, following above the Wocklum limestone, usually consists up to the lower Carbonilerous boundary in a more or less consistent facies, that of the Hangenberg schists. Only in the section 01 the northeastern wall of the eastern Provincial Quarry at Drewer and in the road profile Rüthen - Nuttlar, the Devonian/Carboniferous boundary is to be placed in a continuous carbonate sequence. - The eastern Provincial Quarry at Drewer is therefore proposed as a new candidate section for the Devonian/Carboniferous boundary stratotype. - In many places the carbonates at the Devonian / Carboniferous boundary and the Hangenberg limestone are characterized by an impoverished conodont fauna. - Using platform conodonts, biofacies models are developed, permitting to conclude on the position of the respective setting 01 sedimentation area, either close to a rise or a basin.

Brachiopods in Early Carboniferous

Changes in Mississippian global paleogeography derived from the reconfiguration of the continents, a reversal in ocean currents and global cooling. Although the tectonic and climatic changes are well-documented, their effects on the distribution of brachiopod fauna are poorly documented. Here we present systematic quantitative analyses on global paleobiogeography based on a global brachiopod database from the Mississippian (i.e., Tournaisian, Visean, and Serpukhovian). The dataset consists of 2123 species of 344 brachiopod genera from 1156 localities. Our results reveal that global provincialism was not evident during the Tournaisian and Visean Stages. Two realms, i.e., the Gondwanan and Paleoequatorial Realms, are recognized during the Tournaisian. The Paleoequatorial Realm dominates during the Visean Stage, whereas the Gondwanan Realm is not documented due to the absence of data points. In contrast to the early and middle Mississippian stages, faunal provincialism is greatly enhanced in the Serpukhovian Stage with Paleotethyan and North American realms easily distinguished. This indicates that the Rheic Ocean was closed before the Serpukhovian due to the collision between Gondwana and Laurussia, that disrupted faunal interchange between the Paleotethys and North America. In addition, the paleolatitude-related thermal gradient was enhanced and the Boreal Realm was distinguished from the Paleotethyan Realm during the onset of the Late Palaeozoic Ice Age (LPIA) in the Serpukhovian. The paleolatitude diversity gradient pattern further shows a distinct shift of diversity center from the southern tropic zone in the Tournaisian and Visean to the northern tropic zone in the Serpukhovian.

Geological and geochemical characteristics of the Tersang gold deposit, Malaysia: implications for genesis and gold exploration

The Central gold belt of peninsular Malaysia comprises a number of gold deposits located in the east of the N-S striking Bentong-Raub Suture Zone. The Tersang gold deposit is one of the gold deposits in the gold belt and hosted in sandstone, rhyolite and breccia units. The deposit has an inferred resource of 528,000 ounces of gold. The geochronology of the Tersang deposit has been newly constrained by LA ICP-MS U-Pb zircon dating. The maximum depositional age of the host sedimentary rocks ranges from Early Carboniferous to Early Permian (261.5 ± 4.9 Ma to 333.5 ± 2.5 Ma) for the host sandstone and Late Triassic for the rhyolite intrusion (218.8 ± 1.7 Ma). Textural characteristics of pyrite have revealed five types including (1) Euhedral to subhedral pyrite with internal fracturing and porous cores located in the sandstone layers (pyrite 1); (2) Anhedral pyrite overgrowths on pyrite 1 and disseminated in stage 1 vein (pyrite 2); (3) Fracture-filled or vein pyrite located in stages 1 and 2 vein (pyrite 3); (4) Euhedral pyrite with internal fractures also located in stage 2 vein (pyrite 4); and (5) Subhedral clean pyrite located in the rhyolite intrusion (pyrite 5). Based on pyrite mapping and spot analyses, two main stages of gold enrichment are documented from the Tersang gold deposit. Gold in sandstone-hosted pyrite 1 (mean 4.3 ppm) shows best correlation with Bi and Pb (as evidenced on pyrite maps). In addition, gold in pyrite 3 (mean 8 ppm) located in stage 2 vein shows a good correlation with As, Ag, Sb, Cu, Tl, and Pb. In terms of gold exploration, we suggest that elements such as As, Ag, Sb, Cu, Tl, Bi, and Pb associated with Au may serve as vectoring tools in gold exploration. Our new geological, structural, geochemical and isotopic data together with mineral paragenesis, pyrite chemistry and ore fluid characteristics indicate that the Tersang gold deposit is comparable to a sediment-hosted gold deposit. Our new genetic model suggests deposition of the Permo-Carboniferous sediments followed by intrusion of rhyolitic magma in the Late Triassic. At a later stage, gold mineralisation overprinted the rhyolite intrusion and the sandstone.

Geochemistry on the Kekesai composite intrusion

The late Carboniferous to Permian is a critical period for final amalgamation of the Central Asian Orogenic Belt (CAOB), which is characterized by voluminous igneous rocks, particularly granitoids. The Kekesai composite granitoid porphyry intrusion, situated in the Chinese western Tianshan (southwest part of CAOB) includes two intrusive phases, a monzogranite phase, intruded by a granodiorite phase. LA-ICPMS U-Pb zircon analyses suggest that the monzogranitic rocks formed at 305.5±1.1 Ma, with a wide age range of inherited zircons (358-488 Ma and 1208-1391 Ma), whereas the granodioritic rocks formed at 288.7±1.5 Ma. The monzogranitic and granodioritic phases have similar geochemical features and Sr-Nd-Hf isotopic compositions. They exhibit high and variable SiO2 (66-71 wt.%) and MgO (0.41-2.14 wt.%) contents with some arc-like geochemical characteristics (e.g., enrichment of large ion lithophile elements and negative anomalies of Nb, Ta and Ti) and relatively high initial 87Sr/86Sr ratios (ISr=0.7055-0.7059), low positive eNd(t) (+0.84 to +1.03) as well as a large variation in Hf isotopic compositions with eHf(t) between +3.43 to +14.8, implying both of them were derived from similar source materials. These geochemical characteristics suggest that they might be mainly derived from the partial melting of arc-derived Mesoproterozoic mafic lower crust with involvement of a mantle-derived component in variable proportions by mantle-derived magma underplating. The presence of late-Ordovician to earliest early Carboniferous inherited zircons and the Hf isotopic compositions in the monzogranitic sample, similar to that of the widespread juvenile arc rocks, indicates some crust contamination during magma emplacement. Our new data, combined with previous studies, imply that extensive post-collisional magmatism due to underplating of mantle-derived magma, could plausibly be explained by slab break-off regime.