Long-term eddy-covariance measurements from FINO2 platform above the Baltic Sea

The estimation of the carbon dioxide (CO2) fluxes above the open ocean plays an important role for the determination of the global carbon cycle. A frequently used method therefore is the eddy-covariance technique, which is based on the theory of the Prandl-layer with height-constant fluxes in the atmospheric boundary layer. To test the assumption of the constant flux layer, in 2008 measurements of turbulent heat and CO2 fluxes were started within the project Surface Ocean Processes in the Anthropocene (SOPRAN) at the research platform FINO2. The FINO2 platform is situated in the South-west of the Baltic Sea, in the tri-border region between Germany, Denmark, and Sweden. In the frame of the Research project SOPRAN, the platform was equipped with additional sensors in June 2008. A combination of 3-component sonic anemometers (USA-1) and open-path infrared gas analyzers for absolute humidity (H2O) and CO2 (LICOR 7500) were installed at a 9m long boom directed southward of the platform in two heights, at 6.8 and 13.8m above sea surface. Additionally slow temperature and humidity sensors were installed at each height. The gas analyzer systems were calibrated before the installation and worked permanently without any calibration during the first measurement period of one and a half years. The comparison with the measurements of the slow sensors showed for both instruments no significant long-term drift in H2O and CO2. Drifts on smaller time scales (in the order of days) due to the contamination with sea salt, were cleaned naturally by rain. The drift of both quantities had no influence on the fluctuation, which, in contrast to the mean values, are important for the flux estimation. All data were filtered due to spikes, rain, and the influence of the mast. The data set includes the measurements of all sensors as average over 30 minutes each for one and a half years, June 2008 to December 2009, and 10 month from November 2011 to August 2012. Additionally derived quantities for 30 minutes intervals each, like the variances for the fast-sensor variables, as well as the momentum, sensible and latent heat, and CO2 flux are presented.

TEX86H proxy and BIT index of sediment core GeoB9528-3 and reconstructed temperature data from NW Africa surface sediments

Changes in the strength of Atlantic meridional overturning circulation (AMOC) are known to have profound impacts on global climate. Coupled modelling studies have suggested that, on annual to multi-decadal time scales, a slowdown of AMOC causes a deepening of the thermocline in the tropical Atlantic. However, this process has been poorly constrained by sedimentary geochemical records. Here, we reconstruct surface (UK'37 Index) and thermocline (TEX86H) water temperatures from the Guinea Plateau Margin (Eastern tropical Atlantic) over the last two glacial-interglacial cycles (~ 192 kyr). These paleotemperature records show that periods of reduced AMOC, as indicated by the d13 C benthic foraminiferal record from the same core, coincide with a reduction in the near-surface vertical temperature gradient, demonstrating for the first time that AMOC-induced tropical Atlantic thermocline adjustment exists on longer, millennial time scales. Modelling results support the interpretation of the geochemical records and show that thermocline adjustment is particularly pronounced in the eastern tropical Atlantic. Thus, variations in AMOC strength appear to be an important driver of the thermocline structure in the tropical Atlantic from annual to multi-millennial time scales.

Radiolarian-based paleotemperatures of ODP Site 177-1089 in the Atlantic Sector of the Southern Ocean

Two cores, Site 1089 (ODP Leg 177) and PS2821-1, recovered from the same location (40°56'S; 9°54'E) at the Subtropical Front (STF) in the Atlantic Sector of the Southern Ocean, provide a high-resolution climatic record, with an average temporal resolution of less than 600 yr. A multi-proxy approach was used to produce an age model for Core PS2821-1, and to correlate the two cores. Both cores document the last climatic cycle, from Marine Isotopic Stage 6 (MIS 6, ca. 160 kyr BP, ka) to present. Summer sea-surface temperatures (SSSTs) have been estimated, with a standard error of ca. +/-1.16°C, for the down core record by using Q-mode factor analysis (Imbrie and Kipp method). The paleotemperatures show a 7°C warming at Termination II (last interglacial, transition from MIS 6 to MIS 5). This transition from glacial to interglacial paleotemperatures (with maximum temperatures ca. 3°C warmer than present at the core location) occurs earlier than the corresponding shift in delta18O values for benthic foraminifera from the same core; this suggests a lead of Southern Ocean paleotemperature changes compared to the global ice-volume changes, as indicated by the benthic isotopic record. The climatic evolution of the record continues with a progressive temperature deterioration towards MIS 2. High-frequency, millennial-scale climatic instability has been documented for MIS 3 and part of MIS 4, with sudden temperature variations of almost the same magnitude as those observed at the transitions between glacial and interglacial times. These changes occur during the same time interval as the Dansgaard-Oeschger cycles recognized in the delta18Oice record of the GRIP and GISP ice cores from Greenland, and seem to be connected to rapid changes in the STF position in relation to the core location. Sudden cooling episodes ('Younger Dryas (YD)-type' and 'Antarctic Cold Reversal (ACR)-type' of events) have been recognized for both Termination I (ACR-I and YD-I events) and II (ACR-II and YD-II events), and imply that our core is located in an optimal position in order to record events triggered by phenomena occurring in both hemispheres. Spectral analysis of our SSST record displays strong analogies, particularly for high, sub-orbital frequencies, to equivalent records from Vostok (Antarctica) and from the Subtropical North Atlantic ocean. This implies that the climatic variability of widely separated areas (the Antarctic continent, the Subtropical North Atlantic, and the Subantarctic South Atlantic) can be strongly coupled and co-varying at millennial time scales (a few to 10-ka periods), and eventually induced by the same triggering mechanisms. Climatic variability has also been documented for supposedly warm and stable interglacial intervals (MIS 1 and 5), with several cold events which can be correlated to other Southern Ocean and North Atlantic sediment records.

Neogene radiolarian datum levels in the equatorial Indian and Pacific Oceans

Fifty radiolarian events of early Pleistocene and Neogene age were identified in an E-W transect of equatorial DSDP sites, extending from the Gulf of Panama to the western Pacific and eastern Indian Oceans. Our objective was to document the degree of synchroneity or time-transgressiveness of stratigraphically-useful datum levels from this geologic time interval. We restricted our study to low latitudes within which morphological variations of individual taxa are minimal, the total assemblage diversity remains high, and stratigraphic continuity is well-documented by an independent set of criteria. Each of the five sites chosen (503, 573, 289/586, 214) was calibrated to an "absolute" time scale, using a multiple of planktonic foraminiferal, nannofossil, and diatom datum levels which have been independently correlated to the paleomagnetic polarity time scale in piston core material. With these correlations we have assigned "absolute" ages to each radiolarian event, with a precision of 0.1-0.2 m.y. and an accuracy of 0.2-0.4 m.y. On this basis we have classified each of the events as either: (a) synchronous (range of ages <0.4 m.y.); (b) time-transgressive (i.e., range of ages >1.0 m.y.); and (c) not resolvable (range of ages 0.4-1.0 m.y.). Our results show that, among the synchronous datum levels, a large majority (15 out of 19) are last occurrences. Among those events which are clearly time-transgressive, most are first appearances (10 out of 13). In many instances taxa appear to evolve first in the Indian Ocean, and subsequently in the western and eastern Pacific Ocean. This pattern is particularly unexpected in view of the strong east-to-west zonal flow in equatorial latitudes. Three of the time-transgressive events have been used to define zonal boundaries: the first appearances of Spongaster pentas, Diartus hughesi, and D. petterssoni. Our results suggest that biostratigraphic non-synchroneity may be substantial (i.e., greater than 1 m.y.) within a given latitudinal zone; one would expect this effect to be even more pronounced across oceanographic and climatic gradients. We anticipate that the extent of diachroneity may be comparable for diatom, foraminiferal, and nannofossil datum levels as well. If this proves true, global "time scales" may need to be re-formulated on the basis of a smaller number of demonstrably synchronous events.

(Table T1) Ice rafted debris characteristics of ODP Site 177-1092

We have carried out a multiphase analysis of samples from ODP Site 177-1092, Meteor Rise, subantarctic South Atlantic. Samples were analyzed for ice-rafted debris (IRD [see Table T1]) and stable isotopes from benthic foraminifera [see Murphy et al., 2002, doi:10.1016/S0031-0182(01)00495-3]. Both analyses were performed on the same samples. Additional work was performed to identify the paleomagnetic stratigraphy. The analyzed samples range in age from about 2.6(?) Ma to 4.6 Ma, a time span that saw considerable global warmth, but witnessed overall global refrigeration and the transition to truly bipolar glaciations. IRD arrived frequently during the Early and early Late Pliocene, but only as 'background rafting' (occasional grains per sample). The first identifiable IRD above background rafting is associated with marine isotope stage (MIS) KM4 (~3.18 Ma). Successive IRD peaks become larger, the same pattern as noted at nearby Site 114-704. A very large peak near the top of the record, approximately 2.8 Ma, is considered to represent a hiatus. Peaks below 51.3 meters composite depth (mcd) coincide with positive excursions of the oxygen isotopic record, and with negative excursions of the carbon isotopic curve, a pattern also noted at Site 114-704. However, the reasonably large IRD peak at 51 mcd (tentatively identified with MIS G11) coincides with a positive excursion on the carbon isotopic curve and negative excursion on the oxygen isotopic curve. This relationship suggests a northern hemisphere interglacial, rising sea level, destabilization of the Antarctic margin, and delivery of Antarctic icebergs to the Southern Ocean. Such a mechanism has recently been suggested by Kanfoush et al. (2000, doi:10.1126/science.288.5472.1815) for latest Pleistocene stadial/interstadial oscillations. Here we suggest that such a mechanism may have been in place on glacial/interglacial time scales as early as the Late Pliocene.

(Tables 1,2) Viability of Poa trivialis seeds transported to Antarctica from different locations

Antarctic ecosystems are at risk from the introduction of invasive species. The first step in the process of invasion is the transportation of alien species to Antarctic in a viable state. However, the effect of long-distance human-mediated dispersal, over different time-scales, on propagule viability is not well known. We assessed the viability of Poa trivialis seeds transported to Antarctica from the UK, South Africa and Australia by ship or by ship and aircraft. Following transportation to the Antarctic Treaty area, no reduction in seed viability was found, despite journey times lasting up to 284 days and seeds experiencing temperatures as low as -1.5°C. This work confirms that human-mediated transport may overcome the dispersal barrier for some propagules, and highlights the need for effective pre-departure biosecurity measures.

(Appendix) Relative abundance of planktonic foraminifera in ODP Site 138-846 late Quaternary sediments

High-resolution records of d18O and relative abundances of planktonic foraminifers were generated for ODP Leg 138 Site 846 for the past 800 k.y., with an average sampling interval of 3.6 k.y. The time scale was constructed by correlating the benthic d18O record to the SPECMAP and ODP Site 677 d18O time scales using the mapping function technique of Martinson et al. (1981). Our observations show that variations in the foraminiferal assemblages, although influenced by dissolution, are interpretable in terms of changing characteristics of upper ocean waters. Carbonate dissolution as indicated by fragmentation of planktonic foraminifers shows concentrated variance that is coherent with d18O at the 100 and 41 k.y. orbital periods. At these periods, maximum dissolution occurs during interglacial extremes. This finding differs from previous studies that have indicated that in this region percent carbonate minimum lags global ice volume minimum. N. dutertrei and dextral N. pachyderma dominate the assemblages, but do not show consistent relationships relative to glacial-interglacial cycles. However, less abundant species G. ruber, G. menardii, G. glutinata and G. sacculifer show positive and G. bulloides negative correlation with the d18O record. Q-mode factor analysis of the Site 846 assemblages and comparison with modern assemblages suggest the following. Prior to and during interglacials, the area was considerably warmer and more subtropical than at present; during glacials, the area was colder than at present with greater upwelling and advection off the eastern boundary, and possibly a stronger Peru Current; the equatorial ôcool tongueö was also possibly stronger.