Elements and isotopic measurements of magmatic rock samples from ODP Hole 104-642E

Trace element and isotopic signatures of magmatic rock samples from ODP Hole 642E at the Vøring Plateau provide insight into the interaction processes of mantle melt with crust during the initial magma extrusion phases at the onset of the continental breakup. The intermediate (basaltic-andesitic) to felsic (dacitic and rhyolitic) Lower Series magmas at ODP Hole 642E appear to be produced by large amounts of melting of upper crustal material. This study not only makes use of the traditional geochemical tools to investigate crust-mantle interaction, but also explores the value of Cs geochemistry as an additional tool. The element Cs forms the largest lithophile cation, and shows the largest contrast in concentration between (depleted) mantle and continental crust. As such it is a very sensitive indicator of involvement of crustal material. The Cs data reinforce the conclusion drawn from isotopic signatures that the felsic magmas are largely anatectic crustal melts. The down-hole geochemical variation within ODP Hole 642E defines a decreasing continental crustal influence from the Lower Series into the Upper Series. This is essential information to distinguish intrinsic geochemical properties of the mantle melts from signatures imposed by crustal contamination. A comparison with data from the SE Greenland margin highlights the compositional asymmetry of the crust-mantle interactions at both sides of the paleo-Iapetus suture. While Lower Series and Middle Series rocks from the SE Greenland margin have isotopic signatures reflecting interactions with lower and middle crust, such signatures have not been observed at the mid-Norwegian margin. The geochemical data either point to a dissimilar Caledonian crustal composition and/or to different geodynamic pre-breakup rifting history at the two NE Atlantic margin segments.

Permeability, overburden stress and friction coefficients of ODP Hole 190-1173A and 190-1174B

Permeability measured on three samples in a triaxial cell under effective confining pressure from 0.2 to 2.5 MPa ranges from 10**-18 to 10**-19 m**2. Overall, results indicate that permeability decreases with effective confining pressure up to 1.5 MPa; however, measurements at low effective pressure are too dispersed to yield a precise general relationship between permeability and pressure. When the effective pressure is increased from 1.5 to 2.5 MPa, permeability is roughly constant (~1-4 x 10**-19 m**2). Samples deformed in the triaxial cell developed slickenlined fractures, and permeability measurements were performed before and after failure. A permeability increase is observed when the sample fails under low effective confining pressure (0.2 MPa), but not under effective pressure corresponding to the overburden stress. Under isotropic stress conditions, permeability decrease related to fracture closure occurs at a relatively high effective pressure of ~1.5 MPa. Coefficients of friction on the fractures formed in the triaxial cell are ~0.4.

Strontium and neodymium concentrations and isotope compositions in fossil fish teeth and pore waters at ODP Sites 130-807 and 125-786

We analyzed Nd and Sr isotopic compositions of Neogene fossil fish teeth from two sites in the Pacific in order to determine the effect of cleaning protocols and burial diagenesis on the preservation of seawater isotopic values. Sr is incorporated into the teeth at the time of growth; thus Sr isotopes are potentially valuable for chemostratigraphy. Nd isotopes are potential conservative tracers of paleocirculation; however, Nd is incorporated post-mortem, and may record diagenetic pore waters rather than seawater. We evaluated samples from two sites (Site 807A, Ontong Java Plateau and Site 786A, Izu-Bonin Arc) that were exposed to similar bottom waters, but have distinct lithologies and pore water chemistries. The Sr isotopic values of the fish teeth appear to accurately reflect contemporaneous seawater at both sites. The excellent correlation between the Nd isotopic values of teeth from the two sites suggests that the Nd is incorporated while the teeth are in chemical equilibrium with seawater, and that the signal is preserved over geologic timescales and subsequent burial. These data also corroborate paleoseawater Nd isotopic compositions derived from Pacific ferromanganese crusts that were recovered from similar water depths (Ling et al., 1997; doi:10.1016/S0012-821X(96)00224-5). This corroboration strongly suggests that both materials preserve seawater Nd isotope values. Variations in Pacific deepwater e-Nd values are consistent with predictions for the shoaling of the Isthmus of Panama and the subsequent initiation of nonradiogenic North Atlantic Deep Water that entered the Pacific via the Antarctic Circumpolar Current.

Chemical and isotopic compositions of rocks and minerals from the Franz Josef Land Archipelago

Rb, Sr, Sm, Nd, U, and Pb contents and Sr, Nd, and Pb isotopic composition were determined in tholeiite and subalkaline basalts (in both whole-rock samples and individual minerals) from the Franz Josef Land Archipelago. Isotopic data obtained for the Arctic basin are similar to those for islands from the Pacific, Atlantic, and Indian oceans. The assimilation of crustal (sedimentary) rocks by primary depleted material makes isochron determination of basalt age difficult or impossible. The subalkaline basalts (basaltic andesites) were presumably formed by the metasomatic introduction of incompatible elements in tholeiitie basalts and, only partially, through crustal contamination and fractional crystallization.

Nd, Sm and carbon isotopic data for samples from ODP Legs 115, 145, 171, and 207

Late Cretaceous fish debris from Demerara Rise exhibits a dramatic positive excursion of 8 e-Nd units during ocean anoxic event 2 (OAE2) that is superimposed on extremely low e-Nd(t) values (-14 to -16.5) observed throughout the rest of the studied interval. The OAE2 e-Nd excursion is the largest yet documented in marine sediments, and the majority of the shift is estimated to have occurred over <20 k.y. Low background e-Nd values on Demerara Rise are explained as the Nd isotopic signature of the South American craton, whereas eruptions of the Caribbean large igneous province or enhanced mixing of intermediate waters in the North Atlantic could have caused the excursion.