Interstitial-water chemistry of ODP Leg 113 sites

Variations in the distribution of major elements and stable oxygen isotopes in ODP Leg 113 pore water are not related to lithology and thus appear to be controlled by minor constituents. Petrographic observations and geochemical considerations indicate that alteration of calc-alkalic volcanic material dispersed in the sediment is an important process. A diagenetic reaction is constructed that involves transformation of volcanic glass into smectite, zeolite (represented by phillipsite), chert, and iron sulfide. Mass balance calculations reveal that alteration of less than 10% (volume) of volcanogenic material may account for the observed depletion of magnesium, potassium, and 18O and enrichment of calcium. Alteration of this amount of volcanic glass produces less than 4% (volume) of smectite and zeolite. Hence, mass balance is obtained without having to invoke unreasonable large amounts of volcanic matter or interactions between seawater and basement.

Lower Cretaceous nannofossils of ODP Holes 113-682B and 113-693A

Organic-rich, moderately to sparsely nannofossiliferous Lower Cretaceous claystones ("black shales") were cored at two Ocean Drilling Program Leg 113 sites on the continental slope of East Antarctica off Dronning Maud Land. A 39 m section at Site 692 yielded a Neocomian assemblage of limited diversity with rare Cyclagelosphaera deflandrei, Diadorhombus rectus, and Cruciellipsis cuvillieri, and is probably Valanginian in age. A 70-m section at Site 693 is assigned to the Rhagodiscus angustus Zone (late Aptian-early Albian in age). The latter zone is represented at DSDP sites on the Falkland Plateau, but equivalents to the Neocomian section are absent there, probably due to a disconformity. Watznaueria barnesae is the dominant species at both ODP sites, but it shares dominance with Repagulum parvidentatum at Site 693, where they total 70%-90% of the assemblage; their dominance is attributed to a paleogeographic setting within a restricted basin rather than to postdepositional dissolution of other species. The evolutionary development of this restricted basin and its eventual ventilation in early Albian times is discussed in terms of the regional stratigraphy and the breakup and dispersal of southwestern Gondwanaland. One new species, Corollithion covingtonii, is described.

Sporomorphs and dinoflagellate cysts of ODP Leg 113 holes

Palynological studies were carried out on Paleogene sections from Sites 693 and 696 of Ocean Drilling Project Leg 113 in the Weddell Sea region. Dinoflagellate cysts and sporomorphs were recovered at Site 696 (61°S, 42°W) indicating a middle Eocene to late Eocene/earliest Oligocene age for a glauconitic silt/sandstone. At Site 693 (70°S, 14°W) early Oligocene siliciclastic mud contains a low diversity palynoflora. In an upper Oligocene section (Site 693) only rare, reworked Mesozoic palynomorphs were encountered. Palynological data from Kerogen analyses, dinocysts, and sporomorphs are used to reconstruct the climatic change on the South Orkney microcontinent from the middle Eocene to the late Eocene/earliest Oligocene at Site 696 and the late early Oligocene/early late Oligocene time interval at Site 693 near the continental margin. The middle Eocene was a warm period in the Orkney region with good growing conditions for a warm temperate Nothofagus/conifer forest with an admixture of Proteaceae. Temperate surface water masses, which allowed the growth of a reasonably diverse dinocyst assemblage (ca. 15-20 species), persisted until the end of the Eocene at Site 696. Late early Oligocene sediments of Site 693 (Antarctic continental margin) contain only a low diversity dinocyst flora (two species). The major Cenozoic cooling event in the Weddell Sea region probably occurred at the Eocene/Oligocene boundary. A second dramatic climatic deterioration seems to have taken place during the late early/early late Oligocene, when dinocysts disappeared at the Dronning Maud Land margin area.

Geochemistry of basalts from ODP Hole 113-690C

Basalts from Maud Rise, Weddell Sea, are vesicular and olivine-phyric. Major, trace, and rare earth element concentrations are similar to those of alkali basalts from ocean islands and seamounts. The rocks are low in MgO, Cr, Ni, and Sc, and high in TiO2, K2O, P2O5, Zr, and LREE contents. The abundance of "primary" biotite and apatite in the matrix indicates the melting of a hydrous mantle. Prevalence of olivine and absence of plagioclase in the rocks suggests that the volatile in the melt was an H2O-CO2 mixture, where H2O was <0.5. Mantle derived xenocrysts in the basalt include corroded orthopyroxene, chromite, apatite, and olivine. Olivine (Fo90) is too magnesian to be in equilibrium with the basalts, as they contain only 5-6 wt% MgO. Based on the presence of mantle xenocrysts, the high concentration of incompatible elements, the spatial and chemical affinity with other ocean island basalts from the area, and the relative age of the basalt (overlain by late Campanian sediments), it is suggested that Maud Rise was probably generated by hot-spot activity, possible during a ridge crest jump prior to 84 Ma (anomaly 34 time). Iddingsite, a complex intergrowth of montmorillonite and goethite, is the major alteration product of second generation olivine. It is suggested that iddingsite crystallized at low temperatures (<200°C) from an oxidized fluid during deuteric alteration. Vesicles are commonly filled by zeolites which have been replaced by K-feldspars.