Strontium isotope dating of ODP Leg 133 sediments

The strontium-isotope dating method, based on the strontium-isotope seawater curve, was used to date stratigraphic events recognized in carbonate sediments drilled during Leg 133 on the Queensland and Marion plateaus. The strontium isotope ages of these events are used to correlate paleoceanographic changes, delineated from oxygen isotope signals, and paleoenvironmental or facies changes recorded in the lithostratigraphy. Results indicate that a strong connection exists between prevailing paleoenvironmental conditions and the developmental style of a carbonate platform. Also, the strontium-isotope ages of discrete dolomite intervals within the sequences were determined, indicating that multiple dolomitization events took place and that a hydrodynamically driven process may be currently active within the modern carbonate platform.

Carbon and oxygen isotopic composition and age dating of sediments from ODP Leg 170 sites and Hole 205-1253A

In this data report we present results from stable isotope measurements (d13C and d18O) on bulk sediment at several sites located on a transect along a subduction margin offshore Costa Rica (Ocean Drilling Program Sites 1039, 1040, and 1253). Comparison of stable isotope compositions (d13C and d18O) of the pelagic carbonates Subunit U3C between the reference sites (Site 1039 and 1253) and the underthrust section (Site 1040) reveals similar d13C values and minor differences in d18O values within four specific intervals. Isotope stratigraphy was then used to further constrain the shipboard age models based on bio- and magnetostratigraphy. The resulting age models are in agreement with those derived from biostratigraphy and confirm that the sedimentation rate of the lower Subunit 3C is roughly constant on the order of 50 m/m.y. This is in contrast with the postulated very high sedimentation rates at ~12.7 Ma and lower sedimentation rates (~18 m/m.y.) in the lower part of the section between 16 and 13 Ma, as suggested by shipboard magnetostratigraphic datums.

Pollen record and dating of a sediment profile from Lake Voulkaria, Greece

A palynological investigation of a Holocene profile from Lake Voulkaria, western Greece, was carried out as a contribution to the environmental history of the coastal area of northwestern Acarnania and the Classical city of Palairos. It shows that deciduous oaks dominated the natural vegetation of the area throughout the Holocene. Until ca. 7000 B.C. Pistacia occurred abundantly, while other evergreen woody taxa were rare. At ca. 6300 B.C. an expansion of Carpinus orientalis/Ostrya can be observed. Around ca. 5300 B.C. spreading of Erica indicates a change to a drier climate and/or first human impact. Since ca. 3500 B.C. an increase of evergreen shrubs now clearly indicates land-use. The foundation of the Classical city of Palairos led to a temporary expansion of Phillyrea maquis. Within this period, molluscs of brackish water indicate the use of the lake as a harbour after the construction of a connection to the sea. The deciduous Quercus woodland recovered when human impact decreased in the area, and lasted until modern times.

Radiocarbon dating of peat profiles from the subarctic ecoclimatic region, west-central Canada

Long-term vegetation succession and permafrost dynamics in subarctic peat plateaus of west-central Canada have been studied through detailed plant macrofossil analysis and extensive AMS radiocarbon dating of two peat profiles. Peatland inception at these sites occurred around 5800-5100 yr BP (6600-5900 cal. BP) as a result of paludification of upland forests. At the northern peat plateau site, located in the continuous permafrost zone, palaeobotanical evidence suggests that permafrost was already present under the forested upland prior to peatland development. Paludification was initiated by permafrost collapse, but re-aggradation of permafrost occurred soon after peatland inception. At the southern site, located in the discontinuous permafrost zone, the aggradation of permafrost occurred soon after peatland inception. In the peat plateaus, permafrost conditions have remained very stable until present. Sphagnum fuscum-dominated stages have alternated with more xerophytic communities characterized by ericaceous shrubs. Local peat fires have occurred, but most of these did not cause degradation of the permafrost. Starting from 2800-1100 yr BP (2900-1000 cal. BP) consistently dry surface conditions have prevailed, possibly related to continued frost heave or nearby polygon crack formation.

Age determination and geochemical composition of sediment core DA04-31P

There is limited knowledge pertaining to the history of the Greenland Ice Sheet (GIS) during the last glacial-interglacial transition as it retreated from the continental margins to an inland position. Here we use multiproxy data, including ice-rafted debris (IRD); planktonic isotopes; alkenone temperatures; and tephra geochemistry from the northern Labrador Sea, off southwest Greenland, to investigate the deglacial response of the GIS and evaluate its implications for the North Atlantic deglacial development. The results imply that the southern GIS retreated in three successive stages: (1) early deglaciation of the East Greenland margins, by tephra-rich IRD that embrace Heinrich Event 1; (2) progressive retreat during Allerød culminating in major meltwater releases (d18O depletion of 1.2 per mil) at the Allerød-Younger Dryas transition (12.8-13.0 kyr B.P.); and (3) a final stage of glacial recession during the early Holocene (~9-11 kyr B.P.). Rather than indicating local temperatures of ambient surface water, the alkenones likely were transported to the core site by the Irminger Current. We attribute the timing of GIS retreat to the incursion of warm intermediate waters along the base of grounded glaciers and below floating ice shelves on the continental margin. The results lend support to the view that GIS meltwater presented a forcing factor for the Younger Dryas cooling.

Organic carbon geochemistry of ODP Leg 121 samples

Organic petrological and geochemical analyses were performed on samples cored on Broken Ridge and Ninetyeast Ridge in the Central Indian Ocean during Leg 121. Organic carbon (Corg) contents are less than 1% in each individual sample and average Corg values calculated for larger stratigraphic units are less than 0.2%. Generally, there is more organic matter in Cretaceous sediments than in Tertiary. In the Cretaceous, the bulk of the organic matter consists of terrigenous debris, but a significant contribution of marine-derived organic matter was found in some samples, especially in the early Maestrichtian on Broken Ridge (Site 754). The youngest Pliocene-Pleistocene sediments at Site 758 (northern part of Ninetyeast Ridge) contain a significant amount of clastic material transported to the site by the (distal) Bengal Fan. In these sediments, Corg contents of up to 0.9% were measured and are due to the inflow of terrigenous organic debris. Corg values are positively correlated with bulk sediment accumulation rates (i.e., sediments contain more organic matter at times of faster deposition). The size of terrigenous organic particles is generally small in all sediments. The extremely small number of particles in the Cretaceous sediments at Site 758 and their smaller grain size, compared to the Cretaceous sediments on Broken Ridge, indicate that Cretaceous surface water paleocurrents flowed from southeast to northwest in the Proto-Indian Ocean. In the central Indian Ocean, sediments deposited above the carbonate compensation depth consist of nannofossil and foraminiferal oozes. In contrast to Corg values, calcite contents in the sediments are negatively correlated with bulk sediment accumulation rates (i.e., carbonate oozes were deposited only during times of extremely slow sedimentation). Therefore, older sediments deposited in the young and still narrow Indian Ocean accumulated faster and are less carbonate-rich than Neogene sediments, although carbonate accumulation rates were higher.

Geochemistry of recent sediments of the East African continental margin, Arabian Sea

Chemical analyses have been carried out on 40 samples from the sediment surface and 210 samples from cores that were taken from the edge of the African continental block at the Arabian Sea (coasts of Somalia and Kenya, from Cape Guardafui to Mombasa) on the occasion of the Indian Ocean Expedition of the German research vessel "Meteor" during the years 1964/65. The carbonate content shows its maximum on the northern part of the continental shelf of Africa, where fossil reef debris furnish the detritic portion of carbonate. In the southern part of the continental shelf of Africa the portion of carbonate is low, as it is heavily diluted by the non-carbonatic detritus. It is also in the deep-sea that a lower carbonate content is encountered below the calcite compensation depth. Trace elements in the carbonates: On the shelf and in its vicinity Sr and Mg are enriched. The enrichment has been brought about by the portion of reef debris, as this latter contains aragonite (enrichment of Sr) as well as high-magnesium calcite. The greatest part of the slope contains carbonates that are poor in trace elements and mainly made up of foraminifera (and of coccoliths). Below the carbonate compensation depth another enrichment of Mg takes place in the carbonates, which is probably due to a selective dissolution of calcite in comparison to dolomite. The iron and manganese contents of the carbonates are high (iron higher in coast proximity, manganese higher in the depth), but not genuine, as they come about in the course of the extraction of the carbonates as a result of the dissolution of authigenic Mn-Fe-minerals. Non-carbonatic portion of the sediments: In coast proximity an enrichment of quartz comes about. Within the quartz-rich zone it is the elements V, Cr, Fe, Ti, and B that have been enriched in the non-carbonatic components. This enrichment must be attributed to an elevated content of heavy minerals. In the case of Ti and Fe the preliminary enrichment brought about by processes of lateritisation on the continent plays a certain role. Toward the deep-sea an enrichment of the elements Mn Ni, Cu, and Zn takes place; these enrichments must be explained by authigenic Mn-Fe-minerals. Within the Mn-rich zone a belt running parallel to the coast stands out that shows an increased Mn-enrichment. However, this increase in enrichment does not apply to the elements Ni, Cu, and Zn. It is probable that this latter increased enrichment comes about as a result of the migration of manganese to the sediment surface. (Within the sediments there prevail reductive conditions, in the presence of which Mn is capable of migration, whereas at the sediment surface its precipitation comes about under oxidizing conditions). The quantity of organic matter mainly is dependent on grain size and on the rate of sedimentation. On the shelf an impoverishment of organic matter is to be encountered, as the sediments are coarse-grained. In the depth the impoverishment must be explained on the strength of a small rate of sedimentation. Between those two ranges organic substance is enriched. P and N show an enrichment in comparison to Corg with this applying all the more the smaller the absolute quantity of Corg is. In this particular case one has to do with an enrichment coming about during the diagenetic processes of organic matter. A comparison with the sediments from the Indian and Pakistani continental border in Arabian Sea shows as follows: on the African continental border the coarse detrital material has been transported farther out to deep-sea, which has something to do with the greater inclination of the surface of sedimentation. Carbonate is found in greater abundance on the African side. Its chemical composition is influenced by reef-debris which is missing by Indian-Pakistani side. The content of organic matter is lower on the African side. Contrary to that, the enrichments of N and P compared to organic matter are of an equal order of magnitude on both sides of the Arabian Sea.

Geochemistry, mineralogy, and 40K-40Ar radiometric dating of DSDP Leg 84 basalts - Guatemala Trench

Geochemical (atomic absorption, neutron activation analyses), mineralogical (microprobe), and radiometric (40K - 40Ar) data are presented for five basalts from the Guatemala Trench area (Deep Sea Drilling Project, Leg 84). Strong geochemical and mineralogical differences distinguish two types among these basalts: (1) One basalt (Sample 567A-19,CC), recovered below Upper Cretaceous limestone has the following characteristics: it is quartz normative and has low TiO2, content, as well as low amounts of Cr, Ni and other transition metals, an LREE depleted pattern, and affinities of clinopyroxene phenocryst plotted into the field of tholeiitic and calc-alkalic pyroxenes. (2) Four alkaline basalts, recovered from the mafic and ultramafic acoustic basement, are nepheline normative and show high TiO2 content, high amounts of Cr, Ni and so on, an LREE enriched pattern and compositions of clinopyroxene phenocryst plotted close to or within the field of alkali basalt pyroxenes. These basalts are comparable to those recognized in the lower part of the Santa Elena complex and are clearly different from the oceanic basalts of the Cocos Plate. The radiometric age of the orogenic basalt seems to be close to 80 Ma. The alkaline basalts are clearly older, even if a discrepancy appears between the results of different analyses because of the secondary effects of alteration.

Ice-rafted debris in ODP Holes 177-1090D and 188-1165B

Constraining the nature of Antarctic Ice Sheet (AIS) response to major past climate changes may provide a window onto future ice response and rates of sea level rise. One approach to tracking AIS dynamics, and differentiating whole system versus potentially heterogeneous ice sheet sector changes, is to integrate multiple climate proxies for a specific time slice across widely distributed locations. This study presents new iceberg-rafted debris (IRD) data across the interval that includes Marine Isotope Stage 31 (MIS 31: 1.081-1.062 Ma, a span of ~19 kyr; Lisiecki and Raymo, 2005), which lies on the cusp of the mid-Brunhes climate transition (as glacial cycles shifted from ~41,000 yr to ~100,000 yr duration). Two sites are studied - distal Ocean Drilling Program (ODP) Leg 177 Site 1090 (Site 1090) in the eastern subantarctic sector of the South Atlantic Ocean, and proximal ODP Leg 188 Site 1165 (Site 1165), near Prydz Bay, in the Indian Ocean sector of the Antarctic margin. At each of these sites, MIS 31 is marked by the presence of the Jaramillo Subchron (0.988-1.072 Ma; Lourens et al., 2004) which provides a time-marker to correlate these two sites with relative precision. At both sites, records of multiple climate proxies are available to aid in interpretation. The presence of IRD in sediments from our study areas, which include garnets indicating a likely East Antarctic Ice Sheet (EAIS) origin, supports the conclusion that although the EAIS apparently withdrew significantly over MIS 31 in the Prydz Bay region and other sectors, some sectors of the EAIS must still have maintained marine margins capable of launching icebergs even through the warmest intervals. Thus, the EAIS did not respond in complete synchrony even to major climate changes such as MIS 31. Further, the record at Site 1090 (supported by records from other subantarctic locations) indicates that the glacial MIS 32 should be reduced to no more than a stadial, and the warm interval of Antarctic ice retreat that includes MIS 31 should be expanded to MIS 33-31. This revised warm interval lasted about 52 kyr, in line with several other interglacials in the benthic d18O records stack of Lisiecki and Raymo (2005), including the super-interglacials MIS 11 (duration of 50 kyr) and MIS 5 (duration of 59 kyr). The record from Antarctica-proximal Site 1165, when interpreted in accord with the record from ANDRILL-1B, indicates that in these southern high latitude sectors, ice sheet retreat and the effects of warming lasted longer than at Site 1090, perhaps until MIS 27. In the current interpretations of the age models of the proximal sites, ice sheet retreat began relatively slowly, and was not really evident until the start of MIS 31. In another somewhat more speculative interpretation, ice sheet retreat began noticeably with MIS 33, and accelerated during MIS 31. Ice sheet inertia (the lag-times in the large-scale responses of major ice sheets to a forcing) likely plays an important part in the timing and scale of these events in vulnerable sectors of the AIS.