Upper Eocene to Oligocene strontium, carbon and oxygen isotope record of DSDP holes

We improved upper Eocene to Oligocene deep-sea chronostratigraphic control by integrating isotope (87Sr/86Sr, delta18O, delta13C) stratigraphy and magnetostratigraphy. Most previous attempts to establish the timing of isotope fluctuations have relied upon biostratigraphic age estimates which have uncertainties of 0.5 to over 4.0 m.y. Deep Sea Drilling Project (DSDP) Site 522 contains the best available upper Eocene to Oligocene magnetostratigraphic record which allows first-order correlations of isotope records (87Sr/86Sr, delta18O, delta13C) to the Geomagnetic Polarity Time Scale (GPTS). Empirical calibrations between the 87Sr/86Sr of foraminifera and magnetochronology at Site 522 allow more precise correlation of ,unknown' samples with the GPTS. For example, shallow water and high-latitude sections may be tied into the deep-sea record. Sr-isotope stratigraphic resolution for the latest Eocene to Oligocene is approximately 2 m.y.

Sedimentology and stable carbon and oxygen isotope record of the Central Arctic

Stable oxygen and carbon isotope and sedimentological-paleontological investigations supported by accelerator mass spectrometry 14C datings were carried out on cores from north of 85°N in the eastern central Arctic Ocean. Significant changes in accumulation rates, provenance of ice-rafted debris (IRD), and planktic productivity over the past 80,000 years are documented. During peak glacials, i.e., oxygen isotope stages 4 and 2, the Arctic Ocean was covered by sea ice with decreased seasonal variation, limiting planktic productivity and bulk sedimentation rates. In early stage 3 and during Termination I, major deglaciations of the circum-Arctic regions caused lowered salinities and poor oxygenation of central Arctic surface waters. A meltwater spike and an associated IRD peak dated to ~14-12 14C ka can be traced over the southern Eurasian Basin of the Arctic Ocean. This event was associated with the early and rapid deglaciation of the marine-based Barents Sea Ice Sheet. A separate Termination Ib meltwater event is most conspicuous in the central Arctic and is associated with characteristic dolomitic carbonate IRD. This lithology suggests an origin of glacial ice from northern Canada and northern Greenland where lower Paleozoic platform carbonates crop extensively out.

Stable carbon and oxygen isotope record of foraminifera from ODP holes 104-643A and 104-644A

Continuous sediment sections spanning the last 2.8 Ma have been studied using stable isotope stratigraphy and sedimentological methods. By using paleomagnetic reversals as a chronostratigraphic tool, climatic and paleoceanographic changes have been placed in a time framework. The results show that the major expansion of the Scandinavian Ice Sheet to the coastal areas occurred in the late Neogene period at about 2.8 Ma. Relatively high-amplitude glacials appeared until about 2 Ma. The period between 2.8 and 1.2 Ma was marked by cold surface water conditions with only weak influx of temperate Atlantic water as compared with late Quaternary interglacials. During this period, climatic variations were smaller in amplitude than in the late Quaternary. The Norwegian Sea was a sink of deep water throughout the studied period but deep water ventilation was reduced and calcite dissolution was high compared with the Holocene. Deep water formed by other processes than today. Between 2 and 1.2 Ma, glaciations in Scandinavia were relatively small. A transition toward larger glacials took place during the period 1.2 to 0.6 Ma, corresponding with warmer interglacials and increasing influx of temperate surface water during interglacials. A strong thermal gradient was present between the Norwegian Sea and the northeastern Atlantic during the Matuyama (2.5-0.7 Ma). This is interpreted as a sign of a more zonal and less meridional climatic system over the region as compared with the present situation. The transition towards more meridionality took place over several hundred thousand yr. Only during the last 0.6 Ma has the oceanographic and climatic system of the Norwegian Sea varied in the manner described from previous studies of the late Quaternary.

Stable carbon and oxygen isotope analyses of Neogloboquadrina pachyderma

Detailed records of the carbon and oxygen isotopic ratios of Neogloboquadrina pachyderma are compared between nine high-latitude sediment cores, from the Northern and Southern Hemispheres, covering the last 140000 yrs. The strong analogies between the delta13C records permit to define a delta13C stratigraphic scale, with three clear cut transitions simultaneous with the oxygen isotopic transitions 6/5 (125 kyrs.), 5/4 (65 kyrs.), and 2/1 (13 kyrs.). The delta13C records of N. pachyderma in the high-latitude cores, which follow the changes in delta13C of the surface water TCO2 near areas of deep water formation present trends similar to the benthic foraminifera delta13C records in cores V19-30 and M12-392, although amplitudes of the isotopic shifts are different. This implies that a large part of the observed variations represents global changes in the carbon distribution between biosphere and ocean. The 13C/12C ratios of N. pachyderma in the North Atlantic cores display larger regional variations at 18 kyrs. B.P. than at present. To explain these differences, we have plotted the 18 kyrs. B.P. delta13C values of N. pachyderma from 17 cores distributed N of 40°N. Comparison with published surface water temperature distribution at 18 kyrs. B.P. indicates that a strong divergent cyclonic cell, centered approximatively 55°N and 15°W, was active during most of the last ice-age maximum. This hydrology, analogous to the present Weddell Sea, explains the published evidences of bottom water formation, if located on the northern flank of the gyre, and the strong polar front on the southern flank, probable location of intermediate water formation.