Chemistry of magmatic samples of ODP Holes 134-832B and 134-833B

New petrographic and compositional data were reported for 143 samples of core recovered from Sites 832 and 833 during Ocean Drilling Program (ODP) Leg 134. Site 832 is located in the center and Site 833 is on the eastern edge of the North Aoba Basin, in the central part of the New Hebrides Island Arc. This basin is bounded on the east (Espiritu Santo and Malakula islands) and west (Pentecost and Maewo islands) by uplifted volcano-sedimentary ridges associated with collision of the d'Entrecasteaux Zone west of the arc. The currently active Central Belt volcanic front extends through the center of this basin and includes the shield volcanoes of Aoba, Ambrym, and Santa Maria islands. The oldest rocks recovered by drilling are the lithostratigraphic Unit VII Middle Miocene volcanic breccias in Hole 832B. Lava clasts are basaltic to andesitic, and the dominant phenocryst assemblage is plagioclase + augite + orthopyroxene + olivine. These clasts characteristically contain orthopyroxene, and show a low to medium K calc-alkaline differentiation trend. They are tentatively correlated with poorly documented Miocene calc-alkaline lavas and intrusives on adjacent Espiritu Santo Island, although this correlation demands that the measured K-Ar of 5.66 Ma for one clast is too young, due to alteration and Ar loss. Lava clasts in the Hole 832B Pliocene-Pleistocene sequence are mainly ankaramite or augite-rich basalt and basaltic andesite; two of the most evolved andesites have hornblende phenocrysts. These lavas vary from medium- to high-K compositions and are derived from a spectrum of parental magmas for which their LILE and HFSE contents show a broad inverse correlation with SiO2 contents. We hypothesize that this spectrum results from partial melting of an essentially similar mantle source, with the low-SiO2 high HFSE melts derived by lower degrees of partial melting probably at higher pressures than the high SiO2, low HFSE magmas. This same spectrum of compositions occurs on the adjacent Central Chain volcanoes of Aoba and Santa Maria, although the relatively high-HFSE series is known only from Aoba. Late Pliocene to Pleistocene lava breccias in Hole 833B contain volcanic clasts including ankaramite and augite + olivine + plagioclase-phyric basalt and rare hornblende andesite. These clasts are low-K compositions with flat REE patterns and have geochemical affinities quite different from those recovered from the central part of the basin (Hole 832B). Compositionally very similar lavas occur on Merelava volcano, 80 km north of Site 833, which sits on the edge of the juvenile Northern (Jean Charcot) Trough backarc basin that has been rifting the northern part of the New Hebrides Island Arc since 2-3 Ma. The basal sedimentary rocks in Hole 833B are intruded by a series of Middle Pliocene plagioclase + augite +/- olivine-phyric sills with characteristically high-K evolved basalt to andesite compositions, transitional to shoshonite. These are compositionally correlated with, though ~3 m.y. older than, the high-HFSE series described from Aoba. The calc-alkaline clasts in Unit VII of Hole 832B, correlated with similar lavas of Espiritu Santo Island further west, presumably were erupted before subduction polarity reversal perhaps 6-10 Ma. All other samples are younger than subduction reversal and were generated above the currently subduction slab. The preponderance in the North Aoba Basin and adjacent Central Chain islands of relatively high-K basaltic samples, some with transitional alkaline compositions, may reflect a response to collision of the d'Entrecasteaux Zone with the arc some 2-4 Ma. This may have modified the thermal structure of the subduction zone, driving magma generation processes to deeper levels than are present normally along the reminder of the New Hebrides Island Arc.

Age determination of ODP Leg 120 samples

Conventional K-Ar and 40Ar/39Ar analyses on whole-rock samples are reported for basaltic samples retrieved on the Central and Southern Kerguelen plateaus during Ocean Drilling Program Leg 120. Sites 747, 749, and 750 recovered basalts from the plateau basement, whereas Site 748 drilled a lava flow interbedded with sediments of probable Albian age. The freshest core basalts from the basement yielded dates falling in the 110-100 m.y. interval. Sample 120-749C-15R-3 (26-31 cm) gave conventional K-Ar, total fusion, and plateau 40Ar/39Ar ages that are closely concordant: 111.5 ± 3.2 m.y., 109.9 ± 1.2 m.y., and 109.6 ± 0.7 m.y., respectively. Sample 120-750B-15R-5 (54-60 cm), when taking into account the analytical uncertainties, yields conventional K-Ar and 40Ar/39Ar plateau ages that can be considered similar: 101.2 ± 7.5 and 118.2 ± 5 m.y., respectively. Inspection of the 39Ar/40Ar vs. 36Ar/40Ar diagram does not reveal the occurrence of an initial argon component of radiogenic composition in the two samples. Accordingly, our results suggest that the formation of the basement of the Central Kerguelen Plateau was closed at 110 m.y.. Furthermore, these results are in agreement with a K-Ar age of 114 ± 1 m.y. mentioned in the literature for a basalt dredged in the 77°E Graben. The still scant amount of data indicates that the outpourings of the Central Kerguelen Plateau correspond rather well with widespread continental magmatism in Gondwanaland that is believed to mark the incipient opening of the eastern Indian Ocean. This implies a huge head for the mantle plume at the source of these liquids. Nevertheless, on land and at sea the exact duration of magmatism remains unknown. Therefore, a catastrophic pattern similar to that currently invoked for the Deccan Traps at the end of the Cretaceous, though possible, is not yet required by present geochronologic data.

Element and isotope composition of selected volcanics from the Bicol arc, Philippines

Pliocene to recent volcanic rocks from the Bulusan volcanic complex in the southern part of the Bicol arc (Philippines) exhibit a wide compositional range (medium- to high-K basaltic-andesites, andesites and a dacite/rhyolite suite), but are characterised by large ion lithophile element enrichments and HFS element depletions typical of subduction-related rocks. Field, petrographic and geochemical data indicate that the more silicic syn- and post-caldera magmas have been influenced by intracrustal processes such as magma mixing and fractional crystallisation. However, the available data indicate that the Bicol rocks as a group exhibit relatively lower and less variable 87Sr/86Sr ratios (0.7036-0.7039) compared with many of the other subduction-related volcanics from the Philippine archipelago. The Pb isotope ratios of the Bicol volcanics appear to be unlike those of other Philippine arc segments. They typically plot within and below the data field for the Philippine Sea Basin on 207Pb/204Pb versus 206Pb/204Pb and 208Pb/204Pb versus 206Pb/204Pb diagrams, implying a pre-subduction mantle wedge similar to that sampled by the Palau Kyushu Ridge, east of the Philippine Trench. 143Nd/144Nd ratios are moderately variable (0.51285-0.51300). Low silica (<55 wt%) samples that have lower 143Nd/144Nd tend to have high Th/Nd, high Th/Nb, and moderately low Ce/Ce* ratios. Unlike some other arc segments in the Philippines (e.g. the Babuyan-Taiwan segment), there is little evidence for the involvement of subducted terrigenous sediment. Instead, the moderately low 143Nd/144Nd ratios in some of the Bicol volcanics may result from subduction of pelagic sediment (low Ce/Ce*, high Th/Nd, and high Th/Nb) and its incorporation into the mantle wedge via a slabderived partial melt.

Ages of rocks and minerals from the Okhotsk-Chukotka volcanic belt

Current geochronological data on the Okhotsk-Chukotka volcanic belt (OCVB) and relevant problems are discussed. The belt evolution is suggested to be modeled based on 40Ar/39Ar and U-Pb dates more useful in several aspects than common K-Ar or Rb-Sr dates and methods of paleobotanical correlation. Based on new40Ar/39Ar and U-Pb dates obtained for volcanic rocks in the OCVB northern part, the younger (Coniacian) age is established for lower stratigraphic units in the Central Chukotka segment of the belt, and eastward migration of volcanic activity is shown for terminal stages of this structure evolution.

Geochemistry and ages at DSDP Hole 19-192A

Conventional K-Ar and 40Ar/39Ar age data on altered basalts from DSDP Hole 192A on Meiji Guyot, Emperor Seamount chain, indicate a minimum age for the volcano of 61.9 ± 5.0 m.y. The K-Ar data are consistent with the early Maestrichtian date of the overlying sediments, but do not provide either a positive or negative test of the hypothesis that Meiji is older than Emperor volcanoes to the south. The most prominent alteration affecting the age measurements is potassium metasomatism, particularly of feldspar phenocrysts. The K-Ar apparent ages of feldspar separates from the Meiji basalts show that more than half of the potassium metasomatism occurred within the last 25 m.y. or so, and that if the potassium replacement rate has been constant, then the alteration of the Meiji basalts did not begin for 10 to 20 m.y. after the volcano formed.

Volcanic rocks from the submarine Vityaz Ridge: their age, chemical and isotopic compositions

Results of geological studies at the submarine Vityaz Ridge carried out during cruises 37 and 41 of R/V Akademik Lavrent'ev in 2005 and 2006 are reported. The studied area is located at an near-island trench of the slope in the central part of the Kuril Island arc. Morphologically it consists of two parts: an inner volcanic arc represented by the Great Kuril Range and an outer arc corresponding to the submarine Vityaz Ridge. Diverse rocks composing the basement and the sedimentary cover of the ridge were recovered by dredging. Based on K-Ar dating and geochemistry, volcanics were divided into Paleocene, Eocene, late Oligocene, and Pliocene-Pleistocene complexes. Each of the complexes reflects a tectonomagmatic stage in the ridge evolution. Geochemical and isotope data on the volcanics indicate contribution of ancient crustal material in the magma source and, correspondingly, formation of this structure on the continental basement. Two-stage model ages (TDM2) vary in a wide range from zero values in mafic rocks to 0.77 Ga in felsic varieties, pointing to presence of Precambrian protolith in the source of the felsic rocks of the Vityaz Ridge. The Pliocene-Pleistocene volcanics are classed with tholeiitic, calc-alkaline, and subalkaline series, which differ in alkali contents and REE fractionation. Values of (La/Sm)_n and (La/Yb)_n ratios vary from 0.74 and 0.84 in the tholeiitic varieties to 1.19 and 1.44 in the calc-alkaline and 2.32 and 3.73 in the subalkaline rocks. All three varieties occur within the same volcanic edifices and formed during differentiation of magmatic melts that were channeled along fault zones from the mantle source slightly enriched in crustal component.

Age determinations of rocks from Vestfjella and Ahlmannryggen in Antarctica

The Proterozoic country rock at Ahlmannryggen consists of flat lying basaltic lo andesitic lava flows and sedimentary rocks intruded by dioritic sills (Borgmassivet Intrusives). The suites display a typical platform cover. K-Ar age determinations gave maximum ages of about 1200 Ma on the magmatic rocks. All these suites were intruded bv Proterozoic dikes dated also at about 1200 Ma. Localiy the Proterozoic rocks have a slaty cleavage grading into mylonitic texture which strike parallel to the Jutul Penck graben. Such tectonic structures were dated at 525 Ma using syntectonic white micas. Evidence of the break-up of Gondwana during the Early Jurassic/Triassic is given by dikes at Ahlmannryggen and lava flows, dikes and sills at Vestfjella. At Ahlmannryggen the initial rift phase is documented by the development of the Jutul Penck graben and the intrusion of the 200-250 Ma continental-tholeiitic dikes striking parallel to the graben axis. The lava flows, dikes and sills at Vestfjella represent a later stage of the Gondwana break-up at about 180 Ma that probably reflects the initial stage of the opening of the Weddell Sea.

Radiometric age determinations for basements of ODP Sites 123-765 and 123-766

The results of experiments in 40Ar/39Ar age dating using fresh basement material from Sites 765 and 766 of Leg 123 of the Ocean Drilling Program are inconsistent and cannot be used to constrain the basement age of the Argo Abyssal Plain in the Indian Ocean. However, a celadonite sample, which was precipitated during a low-temperature alteration event that affected the basement at Site 765, yielded a K-Ar age of 155.3 ±3.4 Ma. Celadonites, which have been dated using Rb-Sr methods for basement in the Atlantic Ocean (Staudigel et al., 1981, doi:10.1016/0012-821X(81)90186-2) and by K-Ar methods for the Troodos Ophiolite (Staudigel et al., 1986, doi:10.1130/0091-7613(1986)14<72:AASAOC>2.0.CO;2), and for sediments from the Pacific Ocean (Peterson et al., 1986, doi:10.2973/dsdp.proc.92.132.1986) yield ages that are up to 15 Ma younger than the age for the formation of basement. Thus, the celadonite age is retained as a reliable minimum age for basement at Site 765. This radiometric age is inconsistent with biostratigraphic ages, which indicate a maximum of late Berriasian (approximately 140 Ma) for Site 765, but is consistent with geophysical interpretations of marine magnetic anomalies and with the early north-south seafloor spreading history of the Argo Abyssal Plain region of the Indian Ocean.