Profile of sediment echo sounding with links to ParaSound data files and swath sonar multibeam bathymetry during METEOR cruise M70/2b

Two highly active mud volcanoes located in 990-1,265 m water depths were mapped on the northern Egyptian continental slope during the BIONIL expedition of R/V Meteor in October 2006. High-resolution swath bathymetry and backscatter imagery were acquired with an autonomous underwater vehicle (AUV)-mounted multibeam echosounder, operating at a frequency of 200 kHz. Data allowed for the construction of ~1 m pixel bathymetry and backscatter maps. The newly produced maps provide details of the seabed morphology and texture, and insights into the formation of the two mud volcanoes. They also contain key indicators on the distribution of seepage and its tectonic control. The acquisition of high-resolution seafloor bathymetry and acoustic imagery maps with an AUV-mounted multibeam echosounder fills the gap in spatial scale between conventional multibeam data collected from a surface vessel and in situ video observations made from a manned submersible or a remotely operating vehicle.

Stable isotope stacks from GRIP and GISP ice cores

Recent efforts to link the isotopic composition of snow in Greenland with meteorological and climatic parameters have indicated that relatively local information such as observed annual temperatures from coastal Greenland sites, as well as more synoptic scale features such as the North Atlantic Oscillation (NAO) and the temperature seesaw between Jakobshaven, Greenland, and Oslo, Norway, are significantly correlated with d18O and dD values from the past few hundred years measured in ice cores. In this study we review those efforts and then use a new record of isotope values from the Greenland Ice Sheet Project 2 and Greenland Ice Core Project sites at Summit, Greenland, to compare with meteorological and climatic parameters. This new record consists of six individual annually resolved isotopic records which have been average to produce a Summit stacked isotope record. The stacked record is significantly correlated with local Greenland temperatures over the past century (r=0.471), as well as a number of other records including temperatures and pressures from specific locations as well as temperature and pressure patterns such as the temperature seesaw and the North Atlantic Oscillation. A multiple linear regression of the stacked isotope record with a number of meteorological and climatic parameters in the North Atlantic region reveals that five variables contribute significantly to the variance in the isotope record: winter NAO, solar irradiance (as recorded by sunspot numbers), average Greenland coastal temperature, sea surface temperature in the moisture source region for Summit (30°-20°N), and the annual temperature seesaw between Jakobshaven and Oslo. Combined, these variables yield a correlation coefficient of r=0.71, explaining half of the variance in the stacked isotope record.

Petrographic properties of tephras of DSDP Leg 56 Holes

Examining volcanic materials in deep sea sediments may be one of the most important tasks of the Deep Sea Drilling Project. The investigation of volcanic ash near young source volcanoes is particularly helpful in enabling us to infer the history of volcanism in and around the island arcs. In the area of the Japanese islands volcanic deposits are usually distributed east of the source by prevailing westerly winds. It is also possible that some deep sea tephra has its source in a large, already known land volcanism.

Boron contents and boron, carbon, and oxygen isotope data for ODP Sites 160-970 and 160-971

Products of two mud volcanoes from the distal part of the Mediterranean Ridge accretionary complex have been investigated regarding their B, C, and O stable isotope signatures. The mud breccias have been divided into mud matrix, lithified clasts, biogenic deposits, and authigenic cements and crusts related to fluid flow and cementation. Isotope geochemistry is used to evaluate the depth of mobilization of each phase in the subduction zone. B contents and isotope ratios of the mud and mud clasts show a general trend of B enrichment and decreasing d11B values with increasing consolidation (i.e., depth). However, the majority of the clast and matrix samples relate to moderate depths of mobilization within the wedge (1-2 km below seafloor). The carbonate cements of most of these clasts as well as the authigenic crusts, however, provide evidence for a deep fluid influence, probably associated with the décollement at 5-6 km depth. This interpretation is supported by d13C ratios of the crust, which indicate precipitation of C from thermogenic methane, and by the d11B ratios of pore-water samples of mud-breccia drill cores. Clams (Vesicomya sp.) living adjacent to fluid vents have d11B and d18O values corresponding to brines known in the area, which acted as the parent solution for shell precipitation. Such brines are most likely Miocene pore waters trapped at deep levels within the backstop to the accretionary prism, probably prior to desiccation of the Mediterranean in the Messinian (6-5 Ma). Combining all results, deep fluid circulation and expulsion are identified as the main processes triggering mud liquefaction and extrusion, whereas brines contribute only locally. Given the high B contents, mud extrusion has to be considered a major backflux mechanism of B into the hydrosphere.

Geochemistry of pore fluids from ODP Leg 134 sites

Depending on the temperature and the extent of diagenetic alteration of fluid chemistry, fluid flow at convergent margins may transfer important quantities of heat and mass between the crust and seawater, thereby influencing global mass, isotopic and heat budgets. In the North Aoba Basin, an intra-arc basin located at the New Hebrides Island Arc, alteration of volcanic ash to clay minerals and zeolites forms a CaCl2 brine, perhaps in less than 1 to 3 m.y. The brine results from an exchange of Ca for Na, K, and Mg, and an increase in Cl concentrations to a maximum of 1241 mM. The Cl increase is partly due to the transfer of H2O from the pore fluid into authigenic minerals, but water mass balances, d18O-Cl correlations, and Br/Cl ratios suggest that there is a source of Cl in the sediments. Concentration profiles indicate that Li is transferred from the fluid to solid phase at depths <300 meters below seafloor (mbsf), but at greater depths it is transferred from the solid to fluid phase, at temperatures possibly as low as 25°C. In the accretionary wedge extensive fluid flow appears to be confined to highly faulted regions. Although Cl concentrations less than seawater value are common at convergent margins, the New Hebrides margin contains little low-Cl fluid. Br/Cl ratios suggest the low-Cl fluid is from dilution, and d18O values indicate the water may be derived from mineral dehydration and mixing with meteoric water. The New Hebrides margin exhibits few surface manifestations of venting (e.g., sulfide-oxidizing benthic biological communities, carbonate crusts, mud volcanoes) and thus fluid fluxes may be smaller than at many other margins.

Geochemistry of rare earth elements in basalts from Walvis Ridge

Selected basalts from a suite of dredged and drilled samples (IPOD sites 525, 527, 528 and 530) from the Walvis Ridge have been analysed to determine their rare earth element (REE) contents in order to investigate the origin and evolution of this major structural feature in the South Atlantic Ocean. All of the samples show a high degree of light rare earth element (LREE) enrichment, quite unlike the flat or depleted patterns normally observed for normal mid-ocean ridge basalts (MORBs). Basalts from Sites 527, 528 and 530 show REE patterns characterised by an arcuate shape and relatively low (Ce/Yb)N ratios (1.46-5.22), and the ratios show a positive linear relationship to Nb content. A different trend is exhibited by the dredged basalts and the basalts from Site 525, and their REE patterns have a fairly constant slope, and higher (Ce/Yb)N ratios (4.31-8.50). These differences are further reflected in the ratios of incompatible trace elements, which also indicate considerable variations within the groups. Mixing hyperbolae for these ratios suggest that simple magma mixing between a 'hot spot' type of magma, similar to present-day volcanics of Tristan da Cunha, and a depleted source, possibly similar to that for magmas being erupted at the Mid-Atlantic Ridge, was an important process in the origin of parts of the Walvis Ridge, as exemplified by Sites 527, 528 and 530. Site 525 and dredged basalts cannot be explained by this mixing process, and their incompatible element ratios suggest either a mantle source of a different composition or some complexity to the mixing process. In addition, the occurrence of different types of basalt at the same location suggests there is vertical zonation within the volcanic pile, with the later erupted basalts becoming more alkaline arid more enriched in incompatible elements. The model proposed for the origin and evolution of the Walvis Ridge involves an initial stage of eruption in which the magma was essentially a mixture of enriched and depleted end-member sources, with the N-MORB component being small. The dredged basalts and Site 525, which represent either later-stage eruptives or those close to the hot spot plume, probably result from mixing of the enriched mantle source with variable amounts and variable low degrees of partial melting of the depleted mantle source. As the volcano leaves the hot spot, these late-stage eruptives continue for some time. The change from tholeiitic to alkalic volcanism is probably related either to evolution in the plumbing system and magma chamber of the individual volcano, or to changes in the depth of origin of the enriched mantle source melt, similar to processes in Hawaiian volcanoes.

Geochemistry and ages at DSDP Hole 19-192A

Conventional K-Ar and 40Ar/39Ar age data on altered basalts from DSDP Hole 192A on Meiji Guyot, Emperor Seamount chain, indicate a minimum age for the volcano of 61.9 ± 5.0 m.y. The K-Ar data are consistent with the early Maestrichtian date of the overlying sediments, but do not provide either a positive or negative test of the hypothesis that Meiji is older than Emperor volcanoes to the south. The most prominent alteration affecting the age measurements is potassium metasomatism, particularly of feldspar phenocrysts. The K-Ar apparent ages of feldspar separates from the Meiji basalts show that more than half of the potassium metasomatism occurred within the last 25 m.y. or so, and that if the potassium replacement rate has been constant, then the alteration of the Meiji basalts did not begin for 10 to 20 m.y. after the volcano formed.

Oxygen and hydrogen isotope ratios of pore waters from ODP sites in the Mediterranean Sea

Pore fluids from two ODP sites at Eastern Mediterranean mud volcanoes have been analyzed for their Cl concentration and their delta18O and deltaD isotopic composition. The Cl data span a wide range of concentrations, from extremely depleted with respect to seawater (as low as 60 mM) at the crest of Milano dome (site 970) to strongly enriched (up to 5.4 M) at Napoli dome (site 971). Chloride enrichment is known to be due to dissolving Messinian evaporites, whereas the source of the low-Cl fluid is deduced from stable isotope data presented here. The isotopic composition of the endmember fluid is found to be +10? for delta18O and -32? for deltaD for low- as well as for high-Cl waters. From this signature it can be concluded that neither gas hydrates nor meteoric water play a significant role in the freshening of the pore water. Several other processes altering the delta18O/deltaD composition of pore waters are discussed and considered to be of only negligible influence. The process characterizing the isotopic composition of the fluid is found to be clay mineral dehydration (mainly smectite-illite transformation), corresponding to a depth range of 3.5-7 km and an elevated temperature of about 120-165°C. A quantitative estimate shows that this reaction is capable of producing the observed extreme Cl depletion.