Sedimentation rates and geochemistry of three cores from eastern tropical Pacific

We have generated approx. 300 Kyr records of biogenic opal, calcite, and organic carbon (Corg) for three cores in the eastern and central equatorial Pacific Ocean and have compared the records to determine whether common periods of biogenic sedimentation have occurred throughout the region. We find that Corg has been deposited in common pulses throughout the area, while opal has a much more local pattern of variation. Calcite varies regionally, but the record is shaped by superimposed dissolution and productivity processes. The most intense Corg peak occurs at 18 ka and can have greater than 2 times the Holocene Corg content. Other major Corg peaks occur 150 ka and perhaps at 280 ka. We have compared the Corg record in one of the cores, V19-28, to a model deepwater oxygen record developed from d13C data in the nearby V19-30 to test whether the Corg record has been mostly shaped by degradation or by the rain of organic matter from the euphotic zone. We found no coherence between the two records, implying that the Corg record is primarily a measure of productivity. By comparing the opal, calcite, and Corg records in V19-28, a core which is at or above the lysocline, we found that both increased calcite and opal deposition matches high Corg accumulation. We also found, however, that the calcite and opal records were uncorrelated, so that episodes of high opal deposition do not necessarily accumulate calcite rapidly. We hypothesize that at least two different plankton communities have been dominant in the waters above this site, one rich in opal-secreting plankton and one more dominated by calcite producers. The opal-rich plankton community was dominant during the intervals 10-15 ka and 35-60 ka.

(Table T2) Integrated intensity (peak area) of matrix minerals of ODP Hole 173-1068A

Mass-wasting deposits characterize the Upper Jurassic(?) to Lower Cretaceous sedimentary record of the Iberia Abyssal Plain. These deposits include olistostromes at Site 897, olistostromes and/or possible rock-fall deposits at Site 899, a breccia succession at Site 1068, slumped and fractured deposits at Site 1069, and a breccia succession at Site 1070. Whereas the exact origin of these deposits is uncertain, the regional common occurrence of middle to upper Mesozoic mass-wasting deposits suggests that they record the early rifting evolution of the west Iberia margin. This data report presents both qualitative and semiquantitative results from XRD analyses of the breccia matrix at Site 1068. In this study the matrix is defined as the fine-grained particles (as viewed through a binocular microscope) plus cement. Results are based on analytical methods that aimed to isolate the desired matrix from larger clast contamination prior to XRD analyses. In addition, the breccia was sampled at a higher resolution than was conducted aboard ship, producing a more complete description of downcore matrix mineralogical changes. The data presented here may be used to (1) further justify the subunit designation of Unit IV made aboard ship, (2) help determine to what degree the matrix and the larger clasts (studied in thin section aboard ship; Shipboard Scientific Party, 1998, doi:10.2973/odp.proc.ir.173.106.1998) are compositionally distinct, (3) help identify the extent of hydrothermal fluid migration in the breccia, and (4) support the proposed shipboard hypothesis that the Site 1068 breccia succession resulted from multiple mass-wasting.

Paleomagnetic and stable isotope measurements and distribution of benthic foraminifera in sediment core PS1388-3 from the Antarctic continental margin in the eastern Weddell Sea

A stable isotope record from the eastern Weddell Sea from 69°S is presented. For the first time, a 250,000-yr record from the Southern Ocean can be correlated in detail to the global isotope stratigraphy. Together with magnetostratigraphic, sedimentological and micropalaeontological data, the stratigraphic control of this record can be extended back to 910,000 yrs B.P. A time scale is constructed by linear interpolation between confirmed stratigraphic data points. The benthic d18O record (Epistominella exigua) reflects global continental ice volume changes during the Brunhes and late Matuyama chrons, whereas the planktonic isotopic record (Neogloboquadrina pachyderma) may be influenced by a meltwater lid caused by the nearby Antarctic ice shelf and icebergs. The worldwide climatic improvement during deglaciations is documented in the eastern Weddell Sea by an increase in production of siliceous plankton followed, with a time lag of approximately 10,000 yrs, by planktonic foraminifera production. Peak values in the difference between planktonic and benthic d13C records, which are 0.5 per mil higher during warm climatic periods than during times with expanded continental ice sheets, also suggest increased surface productivity during interglacials in the Southern Ocean.

(Table 1) Age of sediments with anomalously high Hg concentrations in core BDP-98, Lake Baikal

Mercury distribution was examined in the sediments of Lake Baikal that were sampled within the scope of the Baikal Drilling International Project in 1996-1999. The Hg concentrations in the ancient sediments are close to those in the modern sediments with the exception of a few peak values, whose ages coincide with those of active volcanism in adjacent areas. Mercury was demonstrated to be contained in the sediments in the adsorbed Hg0 mode, predominantly in relation with organic matter. When the organic matter of the bottom sediments is decomposed in the course of lithification, Hg is retained in the sediments adsorbed on the residual organic matter, and the concentration of this element corresponds to its initial content in the bottom sediments during their accumulation. Mercury concentrations in lithologically distinct bottom sediments of Lake Baikal and its sediments as a whole depend on the climate. Sediments that were formed during warm periods of time contain more Hg than those produced during cold periods or glaciation. Periodical variations in the Hg concentrations in the bottom sediments of Lake Baikal reflect the variations in the contents of this element in the Earth's atmosphere in the Late Cenozoic, which were, in turn, controlled by the climatic variations on the planet and, thus, can be used for detailed reconstructions of variations in the average global temperature near the planet's surface.

(Table 1) Mass-accumulation rates for the non-authigenic, inorganic, crystalline, eolian component of sediments recovered at DSDP Hole 62-463

Elevated regions in the central parts of ocean basins are excellent for study of accumulation of eolian material. The mass-accumulation rates of this sediment component appear to reflect changes in the influx of volcanic materials through the Early Cretaceous to Recent history of Deep Sea Drilling Project Site 463, on the Mid-Pacific Mountains. Four distinct episodes of eolian accumulation occurred during the Cretaceous: two periods of moderate accumulation, averaging about 0.2 to 0.3 g/cm**2/10**3 yr, 67 to 70.5 m.y. ago and 91 to 108 m.y. ago; a period of low accumulation, approximately 0.03 g/cm**2/10**3 yr, 70.5 to 90 m.y. ago; and a period of high accumulation, about 0.9 g/cm**2/10**3 yr, 109 to 117 m.y. ago (bottom of the hole). Much of the Cenozoic section is missing from Site 463. Upper Miocene to Recent sediments record an upward increase in accumulation rates, from less than 0.01 to about 0.044 g/cm**2/10**3 yr. The late Pliocene-Pleistocene peak may reflect the change to glacial-wind regimes, as well as an increase in volcanic source materials.

Nd-isotope ratios of Cretaceous sediment samples

The role that meridional overturning circulation (MOC) patterns played in poleward heat transport during the extreme warmth of the Early to Late Cretaceous is a fundamental and unresolved question in climate dynamics. In order to address this question we must determine where deep waters formed, and how they may have circulated during periods of extreme warmth. Here we present late Albian through Maastrichtian (105 to 65 Ma) Nd isotope records from Deep Sea Drilling Project (DSDP) and Ocean Drilling Program (ODP) sites in the proto-Indian Ocean and the tropical Pacific. Comparison of these data with previously published records indicates deep-water formation in the Indian sector of the Southern Ocean began at least ?105 Ma, extending the record of high-latitude convection back into the Early Cretaceous prior to the peak warmth of the mid-Cretaceous. The growing body of data supports a mode of MOC in part characterized by high-latitude downwelling during the peak of greenhouse warmth of the Mesozoic and Cenozoic. However, this mode of MOC likely was characterized by numerous locations of deep convection that were regionally important, but not significant in terms of a globally overturning circulation due to paleogeographic and bathymetric barriers.

Planktonic foraminiferal abundances and stable isotope ratios in middle Miocene sediments of the North Atlantic and the southwestern Pacific

A three-fold expansion of the Antarctic ice sheet at 13.60, 12.82, and 11.60 Ma has been inferred from delta18O maxima analyzed in planktonic and benthic foraminiferal tests, although accompanying changes in sea surface temperature have not been detailed. We present estimated changes in middle Miocene surface-water temperatures based on analysis of delta18O in planktonic foraminifera collected at mid-latitude Deep Sea Drilling Project sites in the North Atlantic and South Pacific oceans. We also identify periods of ice-sheet growth based on comparisons of benthic and planktonic foraminiferal delta18O values. Our results indicate: (1) a distinct cooling of the sea surface from 13.6 to 13.5 Ma immediately following a peak in ice volume at 13.6 Ma, (2) a cooling of the sea surface during a period of increasing ice volume from 13.2 to 13.0 Ma, and (3) a development of the Antarctic ice sheet during a period of cooling of the sea surface centered at 11.6 Ma.

Age determination and stable isotope records of sediment core M78/1_235-1

Paleoenvironmental studies and climate models demonstrate that fluvial runoff and moisture availability in the Caribbean hinterland react very sensitively to climatic variations. Late Pleistocene and Holocene climate records document pronounced dry and wet periods over tropical South America mainly caused by shifts of the Intertropical Convergence Zone (ITCZ). However, forcing mechanisms for changes in the ITCZ position remain controversial. Here we present high-resolution foraminiferal Ba/Ca and d18Oseawater records from a core located within the Orinoco River outflow documenting abrupt hydrological changes in the Orinoco catchment area during the deglacial and Holocene. Our data, obtained from the surface-dwelling foraminifera Globigerinoides ruber (pink), show an abrupt increase in Ba/Ca ratios in the early Holocene, starting ~600 yr after the end of the Younger Dryas (YD) cold interval at ca. 10.8 ka and suggesting a massive reorganization of moisture sources in northern South America. In contrast, the salinity dependent d18Oseawater from the same samples shows a gradual decrease starting at the end of the YD. The offset of our Ba/Ca peak excludes meltwater release in conjunction with the northern Andean glacier retreat well before the end of the YD as a forcing mechanism. We suggest that the Ba/Ca record documents an abrupt increase in Ba-rich waters of a northern Andean source caused by the insolation-driven shift of the ITCZ and/or enhanced monsoon activity.