Organic geochemistry, visual composition, atomic ratios, and reflectance at DSDP Site 87-582, 87-583 and 87-584

Geochemical analyses of organic matter were carried out on Quaternary sediments from Sites 582 and 583 (Nankai Trough) and on Pliocene to Miocene sediments from Site 584 (Japan Trench), DSDP Leg 87, to evaluate petroleum-generating potential and to characterize the organic matter. The vitrinite-huminite reflectances of indigenous materials for these sites are less than 0.3% indicating the immature nature of the sediments. The sediments, however, contain remarkable amounts of recycled organic materials. The Quaternary sediments from Sites 582 and 583 contain small amounts of amorphous organic matter (less than 0.75 wt.% organic carbon and 66-90% amorphous debris), which is composed of predominantly recycled, oxidized, and over-matured (or matured) Type III material. The amount of hydrocarbon yield indicates that those sediments have lean-source potential for commercial hydrocarbon generation. The Pliocene to Miocene sediments from Site 584 contain organic matter (0.3-1.09 wt.% organic carbon) of predominantly amorphous debris (68-96%) that originated in two sources, an indigenous Type II material and a recycled, over-matured material. Pyrolysis shows an upward increase in the section of hydrocarbon yield and the same trend is also observed in organic-carbon content. The amount of the yield indicates that the Miocene sediments have lean-to-fair source potential and the Pliocene sediments have fair-to-good source potential.

Magnesium/Calcium ratios and sea surface temperature estimation for sediments of the Timor Sea

We use a multiproxy approach to monitor changes in the vertical profile of the Indonesian Throughflow as well as monsoonal wind and precipitation patterns in the Timor Sea on glacial-interglacial, precessional, and suborbital timescales. We focus on an interval of extreme climate change and sea level variation: marine isotope (MIS) 6 to MIS 5e. Paleoproductivity fluctuations in the Timor Sea follow a precessional beat related to the intensity of the Australian (NW) monsoon. Paired Mg/Ca and d18O measurements of surface- and thermocline-dwelling planktonic foraminifers (G. ruber and P. obliquiloculata) indicate an increase of >4°C in both surface and thermocline water temperatures during Termination II. Tropical sea surface temperature changed synchronously with ice volume (benthic d18O) during deglaciation, implying a direct coupling of high- and low-latitude climate via atmospheric and/or upper ocean circulation. Substantial cooling and freshening of thermocline waters occurred toward the end of Termination II and during MIS 5e, indicating a change in the vertical profile of the Indonesian Throughflow from surface- to thermocline-dominated flow.

Feldspar Pb-isotope ratios for earliest Pleistocene sediments of the sub-polar North Atlantic Ocean

Relatively little is known in detail about the locations of the early Pleistocene ice-sheets responsible for ice-rafted debris (IRD) inputs to the sub-polar North Atlantic Ocean during intensification of northern hemisphere glaciation (iNHG). To shed new light on this problem, we present the first combined in-depth analysis of IRD flux and geochemical provenance of individual sand-sized IRD deposited in the sub-polar North Atlantic Ocean during the earliest large amplitude Pleistocene glacial, marine isotope stage (MIS) 100 (~2.52 Ma), arguably the key glacial during iNHG. IRD provenance is assessed using laser ablation lead (Pb) isotope analyses of single feldspar grains. We find that the Pb-isotope composition (206Pb/204Pb, 207Pb/204Pb and 208Pb/204Pb) of individual ice-rafted (>150 µm) feldspars deposited at DSDP Site 611A, ODP Site 981 and IODP Site U1308 during MIS 100 records a shift from predominantly Archaean-aged circum-North Atlantic Ocean continental sources during early glacial ice-rafting events to dominantly Palaeozoic and Proterozoic-aged sources during full glacial conditions. The distribution of feldspars in Pb-Pb space for full glacial MIS 100 more closely resembles that documented for feldspars deposited at the centre of the last glacial IRD belt (at IODP/DSDP Site U1308/609) during ambient (non-Heinrich-event) ice-rafting episodes of MIS 2 (~23.8 ka) than that documented for MIS 5d (~106 ka). Comparison of our early Pleistocene and last glacial cycle datasets suggests that MIS 100 was characterised by abundant iceberg calving from large ice-sheets on multiple continents in the high northern latitudes (not just on Greenland).

Stable carbon and oxygen isotope ratios of bulk sediment from the Weddell Sea

Carbon isotope measurements were made on bulk sediments from the well preserved calcareous sequences recovered at ODP Sites 689 and 690 on the Maud Rise, Weddell Sea, Antarctica. The very positive delta13C values that characterize the late Paleocene and the rapid trend toward lighter values in the early Eocene established in other sites are clearly recorded here and may be of value for long-distance stratigraphic correlation. However, values in the late Eocene are significantly more positive than have been reported from other areas. The general pattern of the records from Sites 689 and 690 is sufficiently unlike those previously reported from lower latitudes that we suggest that carbon isotope data should be used only with considerable caution for correlating sequences from such high latitudes with lower latitude records.

Cadmium/Calcium and stable isotope ratios of benthic foraminifera from the northeast Atlantic Ocean

The delta13C and Cd measurements from benthic foraminifera from Biogeochemical Ocean Flux Study (BOFS) northeast Atlantic Ocean sediment cores are presented. The delta13C values in glacial foraminifera are consistent with those from elsewhere in the North Atlantic Ocean. For intermediate water (1000 - 2000 m water depth), delta13C values were higher at the last glacial maximum than in present North Atlantic Deep Water (NADW), whereas for deep water (>2000 m) they were lower during the glacial maximum. The Cd concentrations of glacial northeast Atlantic intermediate water were lower than those of present NADW. However, deepwater Cd concentrations increased to values between NADW and present Pacific Deep Water (PDW). The delta13C and Cd data are consistent and show that the northeast Atlantic Ocean was strongly stratified with 13C enriched, low Cd intermediate water overlying 13C depleted, high Cd deep water. The glacial water column comprised two different water masses: deep water, similar in character to present Antarctic Bottom Water (AABW), and intermediate water, different in character from both AABW and NADW, and any present intermediate-depth North Atlantic water. The characteristics of glacial intermediate water were, however, similar to present near-surface waters in the North Atlantic, which suggests rapid ventilation of the glacial ocean to depths of up to 2000 m by cold, nutrient-depleted young surface waters.

Foraminiferal isotope ratios from IODP Site U1313

Large-amplitude millennial-scale climate oscillations have been identified in late Pleistocene climate archives from around the world. These oscillations appear to be of larger amplitude during times of enlarged ice sheets. This observation suggests the existence of a relationship between large-amplitude millennial variations in climate and extreme glacial conditions and therefore that the emergence of millennial-scale climate variability may be linked to the Pliocene intensification of northern hemisphere glaciation (iNHG). Here we test this hypothesis using new late Pliocene high-resolution (ab. 400 year) records of ice-rafted debris deposition and stable isotopes in planktic foraminiferal calcite (Globigerinoides ruber) generated from Integrated Ocean Drilling Program Site U1313 in the subpolar North Atlantic (a reoccupation of the classic Deep Sea Drilling Project Site 607). Our records span marine oxygen isotope stages (MIS) 103-95 (ab. 2600 to 2400 ka), the first interval during iNHG (ab. 3.5 to 2.5 Ma) in which large-amplitude glacial-interglacial cycles and inferred sea level changes occur. Our records reveal small-amplitude variability at periodicities of ab. 1.8 to 6.2 kyr that prevails regardless of (inter)glacial state with no significant amplification during the glacials MIS 100, 98, and 96. These findings imply that the threshold for the amplification of such variability to the proportions seen in the marine archive of the last glacial was not crossed during the late Pliocene and, in view of all available data, likely not until the Mid-Pleistocene Transition.

Argon ratios, 40Ar/39Ar datings and biostratigraphic ages of ODP Leg 165 sites

Drilling in the Caribbean Sea during Ocean Drilling Program Leg 165 has recovered a large number of silicic tephra layers and led to the discovery of three major episodes of explosive volcanism that occurred during the last 55 m.y. on the margins of this evolving ocean basin. The earliest episode is marked by Paleocene to early Eocene explosive volcanism on the Cayman Rise, associated with activity of the Cayman arc, an island arc that was the westward extension of the Sierra Maestra volcanic arc in southern Cuba. Caribbean sediments also document a major mid- to late Eocene explosive volcanic episode that is attributed to ignimbrite-forming eruptions on the Chortis Block in Central America to the west. This event is contemporaneous with the first phase of activity of the Sierra Madre volcanic episode in Mexico, the largest ignimbrite province on Earth. In the Caribbean sediments, a Miocene episode of explosive volcanism is comparable to the Eocene event, and also attributed to sources in the Central American arc to the west. Radiometric 40Ar/39Ar dates have been obtained for biotites and sanidines from 27 tephra layers, providing absolute ages for the volcanic episodes and further constraining the geochronology of Caribbean sediments. Volcanic activity of the Cayman arc is attributed to the northward subduction of the leading edge of the oceanic plate that carried the Caribbean oceanic plateau. Although the factors generating the large episodes of Central American explosive volcanism are unclear, we propose that they are related to contemporary major readjustments of plate tectonic configuration in the Pacific.

Age determination, foraminiferal abundance and stable isotope ratios of sediment core CH82-20

A core from the Mid-Atlantic Ridge at 43.5°N and ~3 km water depth shows distinct evidence of the deglacial events known as Heinrich event 1 (probably the marine equivalent of Oldest Dryas cooling in Europe) and the Younger Dryas. The Heinrich event, dated at three levels to between 14.3 and 15.0 ka, is marked by a minimum in foraminifera per gram, by maxima in rates of sedimentation, ice rafted debris per gram, and relative abundance of N. pachyderma (s.), and by a delta18O minimum in planktonic foraminifera. The Younger Dryas event is marked by peak abundance of N. pachyderma (s.) and a planktonic delta18O maximum. Benthic foraminiferal delta13C reaches minimum values during both the Heinrich event and the Younger Dryas. Our data indicate pronounced changes in surface water properties were coupled with reduced production of North Atlantic Deep Water at each of these times.

Benthic and planktic foraminiferal stable isotope records combined with Nd isotope ratios of ODP Hole 198-1210B

The Pacific Ocean is the largest water body on Earth, and circulation in the Pacific contributed significantly to climate evolution in the latest Cretaceous, the culmination of a period of long-term cooling. Here, we present new high-resolution late Campanian to Maastrichtian benthic and planktic foraminiferal stable isotope data and a neodymium (Nd) isotope record obtained from sedimentary ferromanganese oxide coatings of Ocean Drilling Program Hole 1210B from the tropical Pacific Ocean (Shatsky Rise). These new records resolve 13 million years in the latest Cretaceous, providing insights into changes in surface and bottom water temperatures and source regions of deep to intermediate waters covering the carbon isotope excursions of the Campanian-Maastrichtian Boundary Event (CMBE) and the Mid-Maastrichtian event (MME). Our new benthic foraminiferal d18O and Nd isotope records together with published Nd isotope data show markedly parallel trends across the studied interval over a broad range of bathyal to abyssal water depths interpreted to reflect changes in the intensity of deep-ocean circulation in the tropical Pacific. In particular, we observe a three-million-year-long period of cooler conditions in the early Maastrichtian (72.5 to 69.5 Ma) when a concomitant change toward less radiogenic seawater Nd isotope signatures probably marks a period of enhanced admixture and northward flow of deep waters with Southern Ocean provenance. We suggest this change to have been triggered by intensified formation and convection of deep waters in the high southern latitudes, a process that weakened during the MME (69.5 to 68.5 Ma). The early Maastrichtian cold interval is closely related to the negative and positive carbon isotope trends of the CMBE and MME. The millions-of-years long duration of these carbon cycle perturbations suggests a tectonic forcing of climatic cooling, possibly related to changes in ocean basin geometry and bathymetry.

Stable oxygen and carbon isotope ratios of Pliocene benthic foraminifera in the Atlantic Ocean

Large changes in benthic foraminiferal delta180 and delta13C occurred during the Pliocene (between 3.0 and 2.0 Ma) at Hole 665A. Oxygen isotopic compositions increased to maximum values at 2.4 Ma, correlating with an 18O enrichment observed at Hole 552A and other locations (Shackleton et al., 1984). As at Hole 606 (Keigwin, 1986), however, maximum delta180 values at 2.4 Ma were not as great as at Hole 552A, and enrichments in delta180 also occurred before 2.4 Ma. We believe that the section representing sediments from 2.5 to 2.7 or 2.8 Ma is missing at Hole 552A because of incomplete core recovery. Consequently, the older delta180 increases are not found at Hole 552A. Benthic foraminiferal delta13C values are much lower at Hole 665A than at Hole 552A, approaching the low values observed in the Pliocene Pacific Ocean. This geographic distribution of delta13C suggests that, like late Quaternary glaciations, the equatorial Atlantic Ocean was dominated during the Pliocene by deep water that originated in the Southern Ocean and had chemical characteristics very similar to the Pacific Ocean. Reduced O2 values were probably associated with low delta13C values and contributed to increased preservation of organic carbon during enriched 180 intervals of the Pliocene equatorial Atlantic.

Stable isotope record, Mg/Ca ratios and age model of St. Stephens Quarry, Alabama

In the largest global cooling event of the Cenozoic Era, between 33.8 and 33.5 Myr ago, warm, high-CO2 conditions gave way to the variable 'icehouse' climates that prevail today. Despite intense study, the history of cooling versus ice-sheet growth and sea-level fall reconstructed from oxygen isotope values in marine sediments at the transition has not been resolved. Here, we analyse oxygen isotopes and Mg/Ca ratios of benthic foraminifera, and integrate the results with the stratigraphic record of sea-level change across the Eocene-Oligocene transition from a continental-shelf site at Saint Stephens Quarry, Alabama. Comparisons with deep-sea (Sites 522 (South Atlantic) and 1218 (Pacific)) d18O and Mg/Ca records enable us to reconstruct temperature, ice-volume and sea-level changes across the climate transition. Our records show that the transition occurred in at least three distinct steps, with an increasing influence of ice volume on the oxygen isotope record as the transition progressed. By the early Oligocene, ice sheets were ~25% larger than present. This growth was associated with a relative sea-level decrease of approximately 105 m, which equates to a 67 m eustatic fall.