Foraminifera abundances and biostratigraphy of Cenozoic sediments from the Ontong Java Plateau

The Ontong Java Plateau in the western equatorial Pacific contains a deposition record of biserial planktonic foraminifers concentrated in the Paleogene, in which frequencies up to 67% of the planktonic foraminifers are reported, and in the late Neogene, in which a maximum frequency of 48% is reported. Biserial planktonic foraminifers are rare or absent in the latest Oligocene and early Miocene, an interval characterized by warm bottom water and low temperature gradients. These conditions supported a surface assemblage rather than the biserial planktonic foraminifers, whose Neogene species inhabited the oxygen minimum at intermediate depths in the upper water column. Biserial planktonic foraminifers tend to be of high frequency during high sea stands and low frequency during low sea level, presumably in response to the strengthening or weakening of the oxygen minimum. Species extinction and evolution events occur during low sea stands in the Neogene and sometimes correspond to strong reflection horizons of the plateau's seismic stratigraphy. The biserial species are useful biostratigraphic indexes in the plateau section. The last occurrence (LO) of Streptochilus martini corresponds with the Eocene/Oligocene boundary; S. subglobigerum without Neogloboquadrina acostaensis indicates Zone N15; S. latum occurs from the middle of Zone N16 to near the top of Zone N17; S. globigerum ranges from near the top of Zone N17 to the middle of Zone N19/N20; and the S. globulosum continuous range begins just before the first left-to-right coiling change of Pulleniatina, but the species becomes rare in the Pleistocene section.

Oceanographical and meterological observations in the Westafrican area of upwelling during the 'Deutsche Nordatlantische Expedition' 1937

In 1937 the "Meteor" performed the cruises of the first part of the "Deutsche Nordatlantische Expedition". This publication treats seven stations of three-day-anchoring occupied during that time, five of which are located on the shelf, one on the continental slope and one on a ridge between the Capverde islands. The Bohnecke current meter, an instrument developed for the expedition, is described briefly and it's accuracy studied by comparing the measurements of two instruments which operated simultaneously at the same depth. It is shown that it is very sensitive for movements of the anchored ship because of the very short measuring intervall (2 minutes). The influence of the ship's movements could not be eliminated completely, the mode of using the instrument at different depths being unsuitable for this. Considering the stratification the accuracy of it's representation by the mean temperature and salinity distributionis studied. It is shown that under certain conditions a distribution estimated from observed values gives more exact results. This especially applies to the TS-diagram. Station Meteor336, located on the shelf near Cape Juby, shows temperatures 4 °C less than the open ocean and so belongs to the area of upwelling. During the observation period, however, internal tides are prominent. The diurnal component is of considerable influence, the distinction from inertial oscillations (25.5 hours) not being possible, however. Station Meteor341, on the shelf off Spanish-Sahara, gives an excellent example of the movements in the centre of the area of upwelling. Changing it's direction by 45° at the beginning of the measurements, the wind causes a change of current direction at all depths which, after some inertial oscillations (period 28.3 hours), settles down to a final value. At the beginning and the end of the observations the current at the upper depths is directed off-shore, the angle between current and wind being 22°, while at the lower depths it is orientated towards the shore. The depth of the upper homogenous layer gives the origin of the water transported upwards When during the inertial oscillations the current goes offshore at all depths temporarily, a sudden disturbance occurs in the temperature measurements. Station Meteor311 is located similar to station Meteor341 but was occupied one month earlier. At that time the wind situation was unnormal, the usual wind direction of 45° occuring at the end of the station. Therefore an unnormally high vertical shear of current speed and direction has been observed, the current vector being directed off-shore at the surface and near the bottom, towards the coast inbetween. The TS-diagram shows that the bottom water is replaced first so that upwelling does not occur during observation time. The state reached at the end of the station does not seem to be stable. Station Meteor369, on the continental slope, is governed by internal waves. Besides the internal tide of 12.4 hours a wave of 6.5 hour period is observed, being possibly amplified by the large bottom slope. In 40 - 60 m depth, where the thermocline is located, a wave with 3.3 hour period is observed which is argued to be an internal boundary wave. Station Meteor334 is located on the shelf NW of the mouth of the Senegal river. A marked temperature stratification, associated with large disturbances, and nearly constant salinity have been found there. The current was going slowly towards S or SW in the upper 20 - 30 m, towards N underneath. At the boundary of the current systems intense turbulence developed,including as it seems a water type of less salinity which is transported from the Senegal river by the lower current. Station Meteor327, located at 100 m depth between two of the Capverde islands, shows oceanic characteristics. The semidiurnal tide is found mainly, the diurnal component having considerable influence. Furtheron an internal wave of 6 hour period is seen the maximum amplitude of which is moving slowly downwards. Two possibilities of explaining it are discussed. Station Meteor366 is found in the area of ceasing winds off the coast of upper Guinea. The temperature there depends strongly on the depth, the salinity being nearly constant. The currents are divided into an upper and a lower system with large variations in both of them. A change of wind direction of nearly 90° is supposed to be the reason. The variations in salinity accordingly are interpreted as the influence of fresh water outflow from land which is felt in a different way at different wind directions. In the last section the daily changes in air and water temperature are studied. The upwelling having large influence on these, a centre of the area of upwelling can be located at about 100 miles north of Cape Blanc (Station Meteor311). The semidiurnal tidal component is compared with previous results for the Atlantic Ocean yielding considerable differences for the direction and time of occurence of the current maximum which might be due to the topographical influences around the shelf.

Strontium isotope ratios of planktonic foraminifera from late Neogene sediment samples

A curve describing the variation of the strontium isotopic composition of seawater for the late Neogene (9 to 2 Ma) was constructed from 87Sr/86Sr analyses of marine carbonate in five Deep Sea Drilling Project (DSDP) sites: 502, 519, 588, 590, and 593. The strontium isotopic composition of the oceans increased between 9 and 2 Ma with several changes in slope. From 9 to 5.5 Ma, 87Sr/86Sr values were nearly constant at ~0.708925. Between 5.5 and 4.5 Ma, 87Sr/86Sr ratios increased monotonically at a rate of not, vert, similar 1 * 10**-4 per million years. The steep slope during this interval provides the potential for high resolution strontium isotope stratigraphy across the Miocene/Pliocene boundary. The rate of change of 87Sr/86Sr decreases to near zero again during the interval 4.5-2.5 Ma, and ratios average 0.709025. The relatively rapid increase of 87Sr/86Sr between 5.5 and 4.5 Ma must be related to changes in the flux or average 87Sr/86Sr ratios of the major inputs of Sr to the oceans. Quantitative modelling of these inputs suggests that the increase was most probably caused by an increase in the dissolved riverine flux of strontium to the oceans, an increase in the average 87Sr/86Sr composition of river water, or some combination of these parameters. Modelling of this period as a transient-state requires a pulse-like increase in the input of 87Sr to the oceans between 5.5 and 4.5 Ma. Alternatively, the 5.5-4.5 Ma period can be modelled as a simple transition from one steady-state to another if the oceanic residence time of strontium was eight times less than the currently accepted value of 4 Ma. During the time interval of steep 87Sr/86Sr increase, other geochemical and sedimentologic changes also occur including an increase in sediment accumulation rates, a drop in the calcite compensation depth (CCD), and a decrease in the delta13C of dissolved bicarbonate (i.e., "carbon shift"). The simplest mechanism to explain 87Sr/86Sr variation and these related geochemical changes is to invoke an increase in the dissolved chemical fluxes carried by rivers to the oceans. This, in turn, implies increased chemical denudation rates of the continents and shelves during the late Neogene. The increase in chemical weathering rates is attributed to increased exposure of the continents by eustatic regression, intensified glacial/interglacial cycles, and accelerated rates of global tectonism beginning at 5.5 Ma during the latest Miocene.

Geochemistry of serpentine muds of ODP Leg 125 holes

The <63-µm fractions of serpentinite muds from two seamounts on the Mariana and Izu-Bonin forearcs were analyzed for mineral composition by X-ray diffraction and for chemical composition by X-ray fluorescence. The silt fraction of the muds consists predominantly of chrysotile, brucite, and ample amorphous constituents. Chlorite and smectite are less abundant components. Of special interest is the occurrence of iowaite, a brucite-like, Cl-bearing mineral with a layered structure. Iowaite was not found in the samples from the summit site of one of the seamounts drilled; however, it is scattered throughout the strata, composing the flanks of both seamounts investigated. No systematic change of the iowaite abundance with depth was observed. The distribution of iowaite is confined to the surface of the flanks of the seamount. Based on the distribution on the mineral and its chemical composition, we suggest that the iowaite formed by oxidation of some of the ferrous iron in brucite contained in the serpentine mud as it contacted abyssal seawater during protrusion onto the seafloor. The resulting positive charge imparted to the brucite was compensated by the uptake of seawater chloride. Consequently, the formation of iowaite is restricted to the seafloor where oxygen and chloride are available for these reactions. The availability of oxygen is considered the limiting factor. We conclude that iowaite formation cannot be a major cause for the low chlorinity of pore fluids inside the seamounts.

Shell size variation of Neogloboquadrina pachyderma sin. in the Norwegian-Greenland Sea during the last 1.3 Myr

We present measurements of the maximum diameter of the planktonic foraminifer Neogloboquadrina pachyderma sin. from six sediment cores (Ocean Drilling Program sites 643, 644, 907, 909, 985 and 987) from the Norwegian-Greenland Sea. Our data show a distinct net increase in mean shell size of N. pachyderma sin. at all sites during the last 1.3 Ma, with largest shell sizes reached after 0.4 Ma. External factors such as glacial-interglacial variability and carbonate dissolution alone cannot account for the observed variation in mean shell size of N. pachyderma sin. We consider the observed shell size increase to mirror an evolutionary trend towards better adaptation of N. pachyderma sin. to the cold water environment after 1.1-1.0 Ma. Probably, the Mid Pleistocene climate shift and the associated change of amplitude and frequency of glacial-interglacial fluctuations have triggered the evolution of this planktonic foraminifer. Oxygen and carbon stable isotope analyses of different shell size classes indicate that the observed shell size increase could not be explained by the functional concept that larger shells promote increasing sinking velocities during gametogenesis. For paleoceanographic reconstructions, the evolutionary adaptation of Neogloboquadrina pachyderma sin. to the cold water habitat has significant implications. Carbonate sedimentation in highest latitudes is highly dependent on the presence of this species. In the Norwegian-Greenland Sea, carbonate-poor intervals before 1.1 Ma are, therefore, not necessarily related to severe glacial conditions. They are probably attributed to the absence of this not yet polar-adapted species. Further, transfer function and modern analog techniques used for the reconstruction of surface water conditions in high latitudes could, therefore, contain a large range of errors if they were applied to samples older than 1.1-1.0 Myrs.

Calcium isotope ratios of pore fluids and solid phase of organic rich sediments

Pore fluid calcium isotope, calcium concentration and strontium concentration data are used to measure the rates of diagenetic dissolution and precipitation of calcite in deep-sea sediments containing abundant clay and organic material. This type of study of deep-sea sediment diagenesis provides unique information about the ultra-slow chemical reactions that occur in natural marine sediments that affect global geochemical cycles and the preservation of paleo-environmental information in carbonate fossils. For this study, calcium isotope ratios (d44/40Ca) of pore fluid calcium from Ocean Drilling Program (ODP) Sites 984 (North Atlantic) and 1082 (off the coast of West Africa) were measured to augment available pore fluid measurements of calcium and strontium concentration. Both study sites have high sedimentation rates and support quantitative sulfate reduction, methanogenesis and anaerobic methane oxidation. The pattern of change of d44/40Ca of pore fluid calcium versus depth at Sites 984 and 1082 differs markedly from that of previously studied deep-sea Sites like 590B and 807, which are composed of nearly pure carbonate sediment. In the 984 and 1082 pore fluids, d44/40Ca remains elevated near seawater values deep in the sediments, rather than shifting rapidly toward the d44/40Ca of carbonate solids. This observation indicates that the rate of calcite dissolution is far lower than at previously studied carbonate-rich sites. The data are fit using a numerical model, as well as more approximate analytical models, to estimate the rates of carbonate dissolution and precipitation and the relationship of these rates to the abundance of clay and organic material. Our models give mutually consistent results and indicate that calcite dissolution rates at Sites 984 and 1082 are roughly two orders of magnitude lower than at previously studied carbonate-rich sites, and the rate correlates with the abundance of clay. Our calculated rates are conservative for these sites (the actual rates could be significantly slower) because other processes that impact the calcium isotope composition of sedimentary pore fluid have not been included. The results provide direct geochemical evidence for the anecdotal observation that the best-preserved carbonate fossils are often found in clay or organic-rich sedimentary horizons. The results also suggest that the presence of clay minerals has a strong passivating effect on the surfaces of biogenic carbonate minerals, slowing dissolution dramatically even in relation to the already-slow rates typical of carbonate-rich sediments.

Isotope ratios, IRD and planktonic foraminifera content during marine isotope stage 5 of sediment cores MD99-2303, MD99-2304 and MD95-2010

Variable climatic and oceanographic conditions characterized the last interglacial at high northern latitudes, probably related to changes in the strength of the Atlantic Meridional Overturning Circulation (AMOC). The magnitudes of these changes are comparable to the Holocene variability, and were thus significantly subdued compared to glacial climate changes. A thermal optimum occurred during the early part of the interglacial, followed by a period of reduced Atlantic inflow to the northernmost Nordic Seas. Subsequently, a new period with increased strength of the AMOC occurred. Significant amounts of Ice-Rafted Debris (IRD) were deposited in the northernmost Nordic Seas before any major change of the global ice volume. This implies an early onset of local ice sheet growth, probably the result of enhanced inflow of Atlantic water to the northernmost Nordic Seas contemporary with a Northern Hemisphere summer insolation minimum. Contrasting sea-land conditions provided large moisture fluxes towards land, giving rise to rapid, early glacial growth. Throughout the glacial part of Marine Isotope Stage (MIS) 5, millennial-scale cold events occurred along the axis of the warm water transport, from the subtropics all the way to the northernmost Nordic Seas. Correlation of IRD events from sites in the Fram Strait, on the Voring Plateau, and in the North Atlantic provides evidence that the major Northern Hemisphere ice sheets at times responded coherently to the same forcing. The widespread distribution of these events highlights the importance of the oceanic influence on the regional climate system.