Terrestrial organic matter in marine sediments of the Central Equatorial Atlantic

Terrestrial organic matter (OM) in pelagic sediments is discussed with regard to depositional processes and land-sea interactions in the modern and past glacial/interglacial Equatorial Atlantic. Special emphasis is placed on a critical evaluation of different analytical approaches (C/N, Rock-Eval Pyrolysis, stable carbon isotopes, palynology, organic petrology, and selected biomarkers) which are currently used for the qualitative and quantitative assessment of terrigenous organic carbon. If binary mixing equations are used to calculate terrestrial and marine proportions of organic carbon, we consider the definition of endmember values to be most critical since these values may be biased by a great number of independent controls. A combination of geochemical methods including optical studies (organic petrology and palynology) is therefore suggested to evaluate each individual proxy. Organic geochemical analyses performed on sediments from the modern and Late Quaternary Equatorial Atlantic evidence fluctuations in eolian supply of terrigenous OM related to changes in intensity of the trade winds. Quantification of this organic fraction leads to differing proportions depending on the approach applied, i.e. the organic carbon isotopic composition or maceral analyses. Modern distribution of terrigenous OM reveals a decrease in supply towards the basin contributing less than a fifth of the total OM in pelagic areas. Organic geochemical data indicate that sedimentation in the modern northeastern Brasil Basin is affected by lateral advection of reworked OM probably from southern source areas. Glacial/interglacial deposits from the pelagic Equatorial Atlantic (ODP Site 663), covering isotopic stages 12 and 11, reveal that deposition of terrigenous OM was higher under past glacial conditions, in correspondence to generally enhanced dust fluxes. Proportions of terrigenous OM, however, never exceed 50% of the total OM according to maceral analyses. Other estimates, recently proposed by Verardo and Ruddiman (1996), are considered to be too high probably for analytical reasons. Palynological records in the Equatorial Atlantic parallel dust records. Increased portions of grass pollen suggest the admixture of C4-plant material under modern and past glacial conditions. It is therefore assumed, as one possible interpetation, that C4-plant debris has an effect on sedimentary d13Corg and might explain differences between isotopic and microscopic quantitative estimates. Using the difference between these two records, we calculate that maximum supply of C4-material remains below 20% of the total OM for the deep modern and past glacial/interglacial Equatorial Atlantic.

Alkenone variations, total organic carbon and stable oxygen isotope ratios of the western Arabian Sea

We here present records of total organic carbon (TOC) and C37 alkenones, used as indicators for past primary productivity, from the western (WAS) and eastern Arabian Sea (EAS). New data from an open ocean site of the WAS upwelling area are compared with similar records from Ocean Drilling Program (ODP) Site 723 from the continental margin off Oman and MD 900963 from the EAS. These records together with other proxies used to reconstruct upwelling intensity, indicate periods of high productivity in tune with precessional forcing. On the basis of their phase relationship to boreal summer insolation they can be divided into three groups: in the WAS differences between monsoonal proxies (1) and productivity (2) document a combined signal of moderate SW monsoon winds and of strengthened and prolonged NE monsoon winds, whereas in the EAS phasing indicates maximum productivity (3) at times of stronger NE monsoon winds associated with precession-related maxima in ice volume.

Underway measurements of halocarbons (air) during POSEIDON cruise POS399 in June 2010

During the DRIVE (Diurnal and Regional Variability of Halogen Emissions) ship campaign we investigated the variability of the halogenated very short-lived substances (VSLS) bromoform (CHBr3), dibromomethane (CH2Br2) and methyl iodide (CH3I) in the marine atmospheric boundary layer in the eastern tropical and subtropical North Atlantic Ocean during May/June 2010. The highest VSLS mixing ratios were found near the Mauritanian coast and close to Lisbon (Portugal). With backward trajectories we identified predominantly air masses from the open North Atlantic with some coastal influence in the Mauritanian upwelling area, due to the prevailing NW winds. The maximum VSLS mixing ratios above the Mauritanian upwelling were 8.92 ppt for bromoform, 3.14 ppt for dibromomethane and 3.29 ppt for methyl iodide, with an observed maximum range of the daily mean up to 50% for bromoform, 26% for dibromomethane and 56% for methyl iodide. The influence of various meteorological parameters - such as wind, surface air pressure, surface air and surface water temperature, humidity and marine atmospheric boundary layer (MABL) height - on VSLS concentrations and fluxes was investigated. The strongest relationship was found between the MABL height and bromoform, dibromomethane and methyl iodide abundances. Lowest MABL heights above the Mauritanian upwelling area coincide with highest VSLS mixing ratios and vice versa above the open ocean. Significant high anti-correlations confirm this relationship for the whole cruise. We conclude that especially above oceanic upwelling systems, in addition to sea-air fluxes, MABL height variations can influence atmospheric VSLS mixing ratios, occasionally leading to elevated atmospheric abundances. This may add to the postulated missing VSLS sources in the Mauritanian upwelling region (Quack et al., 2007).

Geochemsitry of minerals and glass shards at DSDP Leg 67 Holes

During Leg 67, the Middle-America Trench transect off Guatemala was drilled across the convergent margin of southern Mexico and Central America south of the Tehuantepec Ridge. The data of Leg 66, north of the Tehuantepec Ridge, and that of Leg 67 provided the opportunity to establish a continuous chronology of airborne volcanic ashes intercalated within the sediments (Aubouin et al., 1979; von Huene et al., 1980). Sites of both expeditions are favorably located for obtaining a good record of the explosive volcanicity of these areas, given the proximity of the volcanic sources and the position of the sites under the prevailing winds.

Benthic foraminifera, stable isotope record and sedimentology of Holocene sediments in the Skagerrak

A high-resolution multi-proxy study of core MD99-2286 reveals a highly variable hydrographic environment in the Skagerrak from 9300 cal. yr BP to the present. The study includes foraminiferal faunas, stable isotopes and sedimentary parameters, as well as temperature and salinity reconstructions of a ca. 29 m long radiocarbon-dated core record. The multivariate technique fuzzy c-means was applied to the foraminiferal counts, and it was extremely valuable in defining subtle heterogeneities in the foraminiferal fauna data corresponding to hydrographic changes. The major mid-Holocene (Littorina) transgression, led to flooding of large former land areas in the North Sea, the opening of the English Channel and Danish straits and initiation of the modern circulation system. This is reflected by fluctuating C/N values and an explosive bloom of Hyalinea balthica. A slight indication of ameliorated conditions between 8000-5750 cal. yr BP is related to the Holocene Thermal Maximum. A subsequent increase in fresh water/Baltic water influence between 5750-4350 cal. yr BP is reflected by dominance of Bulimina marginata and depleted d18O-values. The Neoglacial cooling (after 4350 cal. yr BP) is seen in the Skagerrak as enhanced turbidity, increasing TOC-values and short-term changes in an overall Cassidulina laevigata dominated fauna suggesting a prevailing influence of Atlantic waters. This is in agreement with increased strength of westerly winds, as recorded for this period. The last 2000 years were also dominated by Atlantic Water conditions with generally abundant nutrient supply. However, during warm periods, particularly the Medieval Warm Period and the modern warming, the area was subject to a restriction in the supply of nutrients and/or the nutrient supply had a more refractory character.

Dinoflagellate cysts and pollen distribution of marine surface sediments off West Africa

An organic-walled dinoflagellate cyst analysis was carried out on 53 surface sediment samples from West Africa (17-6°N) to obtain insight in the relationship between their spatial distribution and hydrological conditions in the upper water column as well as marine productivity in the study area. Multivariate analysis of the dinoflagellate cyst relative abundances and environmental parameters of the water column shows that sea-surface temperature, salinity, marine productivity and bottom water oxygen are the factors that relate significantly to the distribution patterns of individual species in the region. The composition of cyst assemblages and dinoflagellate cyst concentrations allows the identification of four hydrographic regimes; 1) the northern regime between 17 and 14°N characterized by high productivity associated with seasonal coastal upwelling, 2) the southern regime between 12 and 6°N associated with high-nutrient waters influenced by river discharge 3) the intermediate regime between 14 and 12°N influenced mainly by seasonal coastal upwelling additionally associated with fluvial input of terrestrial nutrients and 4) the offshore regime characterized by low chlorophyll-a concentrations in upper waters and high bottom water oxygen concentrations. Our data show that cysts of Polykrikos kofoidii, Selenopemphix quanta, Dubridinium spp., Echinidinium species, cysts of Protoperidinium monospinum and Spiniferites pachydermus are the best proxies to reconstruct the boundary between the NE trade winds and the monsoon winds in the subtropical eastern Atlantic Ocean. The association of Bitectatodinium spongium, Lejeunecysta oliva, Quinquecuspis concreta, Selenopemphix nephroides, Trinovantedinium applanatum can be used to reconstruct past river outflow variations within this region.

Coastal erosion dynamics and storm characteristics of Bykovsky Peninsula

This study investigates the rate of erosion during the 1951-2006 period on the Bykovsky Peninsula, located north-east of the harbour town of Tiksi, north Siberia. Its coastline, which is characterized by the presence of ice-rich sediment (Ice Complex) and the vicinity of the Lena River Delta, retreated at a mean rate of 0.59 m/yr between 1951 and 2006. Total erosion ranged from 434 m of erosion to 92 m of accretion during these 56 years and exhibited large variability (sigma = 45.4). Ninety-seven percent of the rates observed were less than 2 m/yr and 81.6% were less than 1 m/yr. No significant trend in erosion could be recorded despite the study of five temporal subperiods within 1951-2006. Erosion modes and rates actually appear to be strongly dependant on the nature of the backshore material, erosion being stronger along low-lying coastal stretches affected by past or current thermokarst activity. The juxtaposition of wind records monitored at the town of Tiksi and erosion records yielded no significant relationship despite strong record amplitude for both data sets. We explain this poor relationship by the only rough incorporation of sea-ice cover in our storm extraction algorithm, the use of land-based wind records vs. offshore winds, the proximity of the peninsula to the Lena River Delta freshwater and sediment plume and the local topographical constraints on wave development.

Pollen analyses of sediment core GeoB9508-5

Millennial-scale dry events in the Northern Hemisphere monsoon regions during the last Glacial period are commonly attributed to southward shifts of the Intertropical Convergence Zone (ITCZ) associated with an intensification of the northeasterly (NE) trade wind system during intervals of reduced Atlantic meridional overturning circulation (AMOC). Through the use of high-resolution last deglaciation pollen records from the continental slope off Senegal, our data show that one of the longest and most extreme droughts in the western Sahel history, which occurred during the North Atlantic Heinrich Stadial 1 (HS1), displayed a succession of three major phases. These phases progressed from an interval of maximum pollen representation of Saharan elements between ~19 and 17.4 kyr BP indicating the onset of aridity and intensified NE trade winds, followed by a millennial interlude of reduced input of Saharan pollen and increased input of Sahelian pollen, to a final phase between ~16.2 and 15 kyr BP that was characterized by a second maximum of Saharan pollen abundances. This change in the pollen assemblage indicates a mid-HS1 interlude of NE trade wind relaxation, occurring between two distinct trade wind maxima, along with an intensified mid-tropospheric African Easterly Jet (AEJ) indicating a substantial change in West African atmospheric processes. The pollen data thus suggest that although the NE trades have weakened, the Sahel drought remained severe during this time interval. Therefore, a simple strengthening of trade winds and a southward shift of the West African monsoon trough alone cannot fully explain millennial-scale Sahel droughts during periods of AMOC weakening. Instead, we suggest that an intensification of the AEJ is needed to explain the persistence of the drought during HS1. Simulations with the Community Climate System Model indicate that an intensified AEJ during periods of reduced AMOC affected the North African climate by enhancing moisture divergence over the West African realm, thereby extending the Sahel drought for about 4000 years.

Accumulation rates and grain sizes of eolian dust in sediments of the Intertropical Convergence Zone in the northeast Pacific

A 328 cm-long piston core (KODOS 02-01-02) collected from the northeast equatorial Pacific at 16°12'N, 125°59'W was investigated for eolian mass fluxes and grain sizes to test these proxies as a tool for the paleo-position of the Intertropical Convergence Zone (ITCZ). The eolian mass fluxes of the lower interval below 250 cm (15.5-7.6 Ma) are very uniform at 5 +/- 1 mg/cm**2/kyr, while those of the upper interval above 250 cm (from 7.6 Ma) are over 2 times higher than the lower interval at 12 +/- 1 mg/cm**2/kyr. The median grain size of the eolian dusts in the lower interval increases from 8.4 Phi to 8.0 Phi downward, while that of the upper interval varies in a narrow range from 8.8 Phi to 8.6 Phi. The determined values compare well in magnitude to those of central Pacific sediments for the upper interval and equatorial and southeast Pacific sediments for the lower interval. This result suggests a possibility that the study site had been under the influence of southeast trade winds at its earlier depositional period due to the northerly position of the ITCZ, and subsequently of the northeast trade winds for a later period when the upper sediments were deposited. This interpretation is consistent with a mineralogical and geochemical study published elsewhere that assigned the provenance of the study core dust to Central/South America for the lower interval and to Asia for the upper interval. This study suggests that the distinct differences in eolian mass flux and grain size observed across the ITCZ can be used to trace the paleo-latitude of the ITCZ.

Sea-surface temperature reconstruction of ODP Hole 175-1078C

A prominent feature in the Southeast Atlantic is the Angola-Benguela Front (ABF), the convergence between warm tropical and cold subtropical upwelled waters. At present, the sea-surface temperature (SST) gradient across the ABF and its position are influenced by the strength of southeasterly (SE) trade winds. Here, we present a record of changes in the ABF SST gradient over the last 25 kyr. Variations in this SST contrast indicate that periods of strengthened SE trade-wind intensity occurred during the Last Glacial Maximum, the Younger Dryas, and the Mid to Late Holocene, while Heinrich Event 1, the early part of the Bølling-Allerød, and the Early Holocene were periods of weakened SE trade-winds.

Dinoflagellate cyst of sediment core M35003-4 southeast of Grenada

High-resolution, well-dated calcareous dinoflagellate cyst and organic carbon records from a 58 kyr sediment core (M35003-4) located southeast of the island of Grenada show that rapid and pronounced changes in cyst association and accumulation and organic carbon deposition occurred, controlled by (1) a significant southward shift in the position of the North Equatorial Current during the last glacial period and the Younger Dryas cold interval and (2) rapid changes in local productivity in marine isotopic stage 3 that are associated with variations in Orinoco River nutrient discharge and coastal upwelling strength. Prominent cyst accumulation peaks representing extremely oligotrophic and stratified thermocline conditions mimic the Greenland ice core and northern Atlantic Dansgaard/Oeschger stadials and Heinrich events. We provide new evidence for a coupled tropical/high-latitude Atlantic climate system during the last glacial period and suggest that changes in the zonality of the low-latitude winds may play an important role in modulating rapid interhemispheric climate variability.

Petrographic properties of tephras of DSDP Leg 56 Holes

Examining volcanic materials in deep sea sediments may be one of the most important tasks of the Deep Sea Drilling Project. The investigation of volcanic ash near young source volcanoes is particularly helpful in enabling us to infer the history of volcanism in and around the island arcs. In the area of the Japanese islands volcanic deposits are usually distributed east of the source by prevailing westerly winds. It is also possible that some deep sea tephra has its source in a large, already known land volcanism.

Inorganic geochemical record of ODP Holes 117-722B and 117-724C

High-resolution sampling from late Pleistocene (last 400 k.y.) sediments of Site 722 (upper 16 m) and Site 724 (upper 70 m), and subsequent inorganic geochemical analysis, has defined the history of productivity in the northwest Arabian Sea. Eolian dust input from the Arabian Peninsula and Somalia is characterized by the record of Ti/Al and Cr/Al. This dust record displays strong precessional periodicity (cycles at 25 k.y.) suggesting the Southwest Monsoon and associated winds play a key role in transporting terrigenous material from the land. High biological productivity results in the accumulation of biogenic CaCO3 and opal in the sediments, the latter having an unexpectedly minor contribution to the total mass flux. Due to dilution of the CaCO3 record by the terrigenous component, the record of biological productivity is best exemplified by Ba. Its record, together with that of other metals recording biological association and redox variability (Cu, Ni, Zn, V, U) clearly identifies the interglacial episodes as being more biologically productive. The striking agreement between Ba and the d18O record in planktonic foraminifers suggests that the supply of nutrients during these periods of high productivity is linked to ocean-wide changes in ocean fertility, and not just local upwelling conditions. High levels of phosphate accumulation in interglacial sediments is attributed to both diagenetic phosphorite formation and biogenic skeletal debris. This study provides a detailed record of productivity variation in the northwest Arabian Sea during the late Pleistocene.

Isopollen maps for 18,000 years B.P. of the offshore of Northwest Africa: Evidence for paleowind circulation

Distribution patterns of the most important pollen types from southern European and northwest African source areas for the 18,000 years B.P. time slice are reconstructed from pollen records of 14 well-dated deep-sea cores located between 37° and 9°N and compared with the modern pollen distribution in this area. It is concluded that the belt with maximum African Easterly Jet transport did not shift latitudinally during the last glacial-interglacial transition but remained at about 20°N. Furthermore, it is substantiated that the trade winds did not shift latitudinally during the last glacial-interglacial transition. This evidence is not compatible with an atmospheric circulation model that assumes a zone of surface westerlies in the northern part of northwest Africa. Trade winds during glacial episodes did, however, intensify, especially from about 36° to 24° N.

Composition of hydrothermal manifestations in the World Ocean

The monograph summarizes results of studies of hydrothermal fields on the ocean floor, hydrothermal plumes and metalliferous sediments. Hydrothermal ore manifestations formed in different geodynamic settings, with different character of volcanism in different facial conditions of deposition are described. Causes of non-uniformity of hydrothermal system functioning in different parts of the ocean and therefore variability of hydrothermal deposits are under consideration. On the base of found relationships of these irregularities with geodynamics, volcanism and sedimentation a new classification of hydrothermal processes and genetic models of hydrothermal ore formation in the ocean have been created. Regularities of hydrothermal sedimentary material dispersion in bottom waters are discussed.