Velocity-density systematics for basalts at DSPD Leg 54 Holes

Precise velocity and density measurements at atmospheric and elevated pressures have been obtained on basalts drilled in 13 holes during Leg 54. The vp-sigma data show systematics which are controlled by the degree of crystallinity (or conversely, glassiness), microstructure, and original mineralogy and chemistry. Extensively fractionated basalts with marked iron enrichment produce anomalously low measured velocities at densities above 2.90 g/cm**3. Also, the effective in situ pressure acting on Leg 54 basalts is less than hydrostatic, and perhaps close to zero. At zero effective pressure, the measured velocities average 2.5 km/s higher than East Pacific Rise upper crustal velocities determined by seismic refraction. This implies that the in situ velocities are undoubtedly a result of the highly fragmented nature of East Pacific Rise crust.

Quartz content and mass accumulation rates at DSDP Hole 86-576A

The amount and the accumulation rate of quartz were measured in 33 samples from Hole 576A. The amount and source of mineral aerosol being deposited in the northwest Pacific during the Cenozoic are evaluated using these data. When Hole 576A is compared to a Cenozoic record in the central North Pacific, a strong uniformity in the composition of the mineral aerosol across the North Pacific is seen. The data suggest that Hole 576A entered the influence of the westerlies about 15 m.y. ago and that since that time the rates of sediment deposition have increased. Only the dramatic change in quartz accumulation 2.5 m.y. ago can be clearly related to a climatic event, but a gradual increase in quartz accumulation through the Miocene and early Pliocene is probably a result of increasing Northern Hemisphere aridity and intensified atmospheric activity associated with global cooling during the interval.

Mass-accumulation rates for the non-authigenic, inorganic, crystalline, eolian component of sediments recovered at DSDP Sites 62-464 to 62-466

The mass-accumulation rate (MAR) of the non-authigenic, inorganic, crystalline component of deep-sea sediments from the Pacific aseismic rises apparently reflects influx of eolian sediment. The eolian sediment usually is dominated by volcanic material, except during glacial times. Sediments from Hess Rise provide a discontinuous record of eolian MARs. During Albian to Cenomanian time, the influx of volcanic material was fairly high (0.35-0.6 g/cm**2/10**3 yr), recording the latest stages of the Albian volcanism that formed Hess Rise. From the Campanian through the Paleocene, influx of eolian sediment was low, averaging 0.03 g/cm**2/10**3 yr. None of the four Hess Rise drill sites show evidence of the Late Cretaceous volcanic episode recorded at many sites now in the equatorial to subtropical Pacific. Pliocene to Pleistocene samples record a peak in volcanic influx about 4 to 5 m.y. ago, which has been well documented elsewhere. The several-fold increase in eolian accumulation rates elsewhere which are correlated with the onset of severe northernhemisphere glaciation 2.5 m.y. ago is not obvious in the Hess Rise data.

Siliceous components of Pliocene-Holocene sediments of the South Atlantic

The Pliocene-Holocene sediments recovered on ODP Leg 114 from Holes 699A, 701C, and 704B are the subject of a detailed investigation to interpret changes in the Oceanographic environment of the South Atlantic in the vicinity of the Polar Front Zone (PFZ). The cores sample sediments at shallow (Hole 704B, 2532 m), intermediate (Hole 699A, 3716 m), and basinal (Hole 701C, 4647 m) depths. Sites 699 and 704 come under the influence of the Antarctic Circumpolar Current (ACC) and Circumpolar Deep Water. It is possible that the upper reaches of Antarctic Bottom Water (AABW) may also affect Hole 699A. Site 701 is influenced by AABW. Closely spaced samples were analyzed for grain-size distribution, sand fraction components, biosiliceous microfossils, organic carbon, and water content. PFZ migrations are traced using changes in bulk sedimentaccumulation rates and the abundance of the diatoms Actiniscus ssp. and Genus et species indet. 1 Fenner (1991), as well as changes in sediment grain size and composition. Diatomaceous sediments of Gilbert age in Hole 699A indicate that the PFZ was positioned over this site, but during the Gauss it migrated north, bringing in less productive Antarctic Surface Water. All cores document a very gradual southerly movement of the PFZ throughout the Matuyama (with some sharp fluctuations of the northen PFZ border over Site 704 between 1.45 and 1.83 m.y.). This regressive shift culminated in the late Matuyama. The latest Matuyama to earliest Brunhes record in Hole 699A has been removed by a hiatus lasting from 1.0 to 0.6 m.y., which was probably caused by intensification of the deep-reaching ACC. The corresponding interval in Hole 704B, the shallowest core, contains evidence of winnowing. Sharp fluctuations of large amplitude and high frequency in the lithology of the sediments from Hole 704B in the eastern South Atlantic, starting at about 0.75 m.y. and characterizing the whole Brunhes Epoch, record the rapid movement of the northern border of the PFZ over the site. These reflect strong glacial/interglacial alternations in climate. To a lesser extent, lithologic fluctuations in Hole 701C reflect the same phenomenon, whereas in Hole 699A the lithology does not vary as dramatically.

Calcite accumulation in the eastern equatorial Pacific

The eastern equatorial Pacific (EEP) is an important center of biological productivity, generating significant organic carbon and calcite fluxes to the deep ocean. We reconstructed paleocalcite flux for the past 30,000 years in four cores collected beneath the equatorial upwelling and the South Equatorial Current (SEC) by measuring ex230Th-normalized calcite accumulation rates corrected for dissolution with a newly developed proxy for "fraction of calcite preserved". This method produced very similar results at the four sites and revealed that the export flux of calcite was 30-50% lower during the LGM compared to the Holocene. The internal consistency of these results supports our interpretation, which is also in agreement with emerging data indicating lower glacial productivity in the EEP, possibly as a result of lower nutrient supply from the southern ocean via the Equatorial Undercurrent. However, these findings contradict previous interpretations based on mass accumulation rates (MAR) of biogenic material in the sediment of the EEP, which have been taken as reflecting higher glacial productivity due to stronger wind-driven upwelling.

Stress field of basaltic rocks of ODP Hole 127-794C

We carried out an experiment to estimate in-situ stresses at ODP Hole 794C (water depth: 2809 m) from the basaltic core samples by deformation rate analysis (DRA). Site 794 is located at the northern end of the Yamato Basin and 70 km west of the eastern Japan Sea intraplate or interplate convergent zone. Stress previously applied to a rock specimen is identified in the inelastic strain behavior of the specimen under uniaxial compression by the method used. Natural remanent magnetization of the sample was also measured to get a reference for the orientation of the horizontal stresses. The vertical, maximum, and minimum horizontal in-situ stresses estimated at a depth of 582 mbsf are 36.4, 43.1, and 31.2 MPa, respectively. The average of the largest and the least horizontal stresses is nearly equal in value to the vertical stress. This suggests that the site is in the stress field of the strike slip regime at the depth, while the stress field of the reverse fault regime has been estimated from the focal mechanism solutions of the earthquakes whose hypocenters are located near or on the convergent boundary. The directions of the largest and the least horizontal stress are estimated to be northeast-southwest and in northwest-southeast, respectively, in taking account of rotation tectonics of the Japan Sea since its formation. The directions of the largest and the least horizontal stresses are opposite to those determined from the earthquakes. These discrepancies of our results with those from earthquakes may be due mainly to the fact that the site is not in the convergent zone.

Age determination of hornblende in ODP Site 188-1165 and DSDP Hole 28-268

Sediments from Ocean Drilling Program Site 1165 in the Indian Ocean sector of the Southern Ocean (off Prydz Bay) contain a series of layers that are rich in ice-rafted debris (IRD). Here we present evidence that IRD-rich layers at Site 1165 at 7, 4.8, and 3.5 Ma record short-lived, massive discharges of icebergs from Wilkes Land and Adélie Land, more than 1500 kilometers to the east of the depositional site. This distant source of icebergs is clearly defined by the presence of IRD hornblende grains with 40Ar/39Ar ages of 1200-1100 Ma and 1550-1500 Ma, ages that are not found on the East Antarctic continent in locations closer to Site 1165. This observation requires enormous amounts of detritus-carrying drifting icebergs, most likely in the form of large icebergs. These events probably reflect destabilization, surge, and break-up of ice streams on the Wilkes Land and Adélie Land margins of the East Antarctic Ice Sheet, in the vicinity of the low-lying Aurora and Wilkes Basins. They occurred under warming conditions, but each coast seems to have produced ice-rafting events independently, at different times. The data presented here constitute the first evidence of far-traveled icebergs from specific source areas around the East Antarctic perimeter. Launch of these icebergs may have happened during quite dramatic events, perhaps analogous to "Heinrich Events" in the North Atlantic.

Agricultural pesticide in sediment cores from the Lac de Saint-André, France

Agricultural pesticide use has increased worldwide during the last several decades, but the long-term fate, storage, and transfer dynamics of pesticides in a changing environment are poorly understood. Many pesticides have been progressively banned, but in numerous cases, these molecules are stable and may persist in soils, sediments, and ice. Many studies have addressed the question of their possible remobilization as a result of global change. In this article, we present a retro-observation approach based on lake sediment records to monitor micropollutants and to evaluate the long-term succession and diffuse transfer of herbicides, fungicides, and insecticide treatments in a vineyard catchment in France. The sediment allows for a reliable reconstruction of past pesticide use through time, validated by the historical introduction, use, and banning of these organic and inorganic pesticides in local vineyards. Our results also revealed how changes in these practices affect storage conditions and, consequently, the pesticides' transfer dynamics. For example, the use of postemergence herbicides (glyphosate), which induce an increase in soil erosion, led to a release of a banned remnant pesticide (dichlorodiphenyltrichloroethane, DDT), which had been previously stored in vineyard soil, back into the environment. Management strategies of ecotoxicological risk would be well served by recognition of the diversity of compounds stored in various environmental sinks, such as agriculture soil, and their capability to become sources when environmental conditions change.

Supplementary material: XRF core scanning data, CaCO3 values, foraminiferal carbon and oxygen isotope data, Mg/Ca data, clay mineralogy and helium isotope results

The Paleocene-Eocene Thermal Maximum (PETM; ~56 Ma) is associated with abrupt climate change, carbon cycle perturbation, ocean acidification, as well as biogeographic shifts in marine and terrestrial biota that were largely reversed as the climatic transient waned. We report a clear exception to the behavior of the PETM as a reversing climatic transient in the eastern North Atlantic (Deep-Sea Drilling Project Site 401, Bay of Biscay) where the PETM initiates a greatly prolonged environmental change compared to other places on Earth where records exist. The observed environmental perturbation extended well past the d13C recovery phase and up to 650 kyr after the PETM onset according to our extraterrestrial 3He-based age-model. We observe a strong decoupling of planktic foraminiferal d18O and Mg/Ca values during the PETM d13C recovery phase, which in combination with results from helium isotopes and clay mineralogy, suggests that the PETM triggered a hydrologic change in western Europe that increased freshwater flux and the delivery of weathering products to the eastern North Atlantic. This state change persisted long after the carbon-cycle perturbation had stopped. We hypothesize that either long-lived continental drainage patterns were altered by enhanced hydrological cycling induced by the PETM, or alternatively that the climate system in the hinterland area of Site 401 was forced into a new climate state that was not easily reversed in the aftermath of the PETM.

Magnetic susceptibility of deep-sea cores from the Scotia Sea

We studied two deep-sea cores from the Scotia Sea to reconstruct past atmospheric circulation in the southern hemisphere and to resolve a long-standing debate on the interpretation of magnetic susceptibility (MS) records in Southern Ocean (SO) sediment. High-sedimentation sites MD07-3134 (0.2 - 1.2 m/kyr) and MD07-3133 (0.3 - 2 m/kyr) cover the last 92.5 kyr and 36 kyr, respectively. Both exhibit a one-to-one coupling of the MS and Ca2+ signal to the non-sea salt (nss) Ca2+ signal of the EDML ice core, clearly identifying atmospheric circulation as means of distribution. Comparison of additional proxies also excludes major influence by volcanic sources, sea-ice, icebergs, or oceanic current transport. The close resemblance of the dust proxies over the last glacial cycle, in turn, allows for the establishment of an age model of unprecedented resolution and precision for SO deep-sea sediment because atmospheric transport involves no major leads or lags. This is of particular importance because MS is routinely measured on deep-sea cores in the SO but the sediments usually lack biogenic carbonate and therefore had only limited stratigraphic control so far. Southern South America (SSA) is the likely source of eolian material because Site MD07-3133, located closer to the continent, has slightly higher MS values than Site MD07-3134, and also the MS record of Patagonian Site SALSA shows comparable variability. Patagonia was the dust source for both the Scotia Sea and East Antarctica. Dust fluxes were several times higher during glacial times, when atmospheric circulation was either stronger or shifted in latitude, sea level was lowered, shelf surfaces were exposed, and environmental conditions in SSA were dominated by glaciers and extended outwash plains. Hence, MS records of SO deep-sea sediment are reliable tracers of atmospheric circulation, allowing for chronologically-constrained reconstructions of the circum Antarctic paleoclimate history.

Borehole temperature, submarine permafrost methane concentrations and pore water chemistry measured on borehole BK2, central Laptev Sea shelf

Submarine permafrost degradation has been invoked as a cause for recent observations of methane emissions from the seabed to the water column and atmosphere of the East Siberian shelf. Sediment drilled 52 m down from the sea ice in Buor Khaya Bay, central Laptev Sea revealed unfrozen sediment overlying ice-bonded permafrost. Methane concentrations in the overlying unfrozen sediment were low (mean 20 µM) but higher in the underlying ice-bonded submarine permafrost (mean 380 µM). In contrast, sulfate concentrations were substantially higher in the unfrozen sediment (mean 2.5 mM) than in the underlying submarine permafrost (mean 0.1 mM). Using deduced permafrost degradation rates, we calculate potential mean methane efflux from degrading permafrost of 120 mg/m**2 per year at this site. However, a drop of methane concentrations from 190 µM to 19 µM and a concomitant increase of methane d13C from -63 per mil to -35 per mil directly above the ice-bonded permafrost suggest that methane is effectively oxidized within the overlying unfrozen sediment before it reaches the water column. High rates of methane ebullition into the water column observed elsewhere are thus unlikely to have ice-bonded permafrost as their source.

Sedimentation rate, bulk density, accumulation rate of terrigenous material and grain sizes of ODP Leg 167 sites

The terrigenous mineral fraction of sediments recovered by drilling during Ocean Drilling Program Leg 167 at Sites 1018 and 1020 is used to evaluate changes in the source and transport of fine-grained terrigenous sediment and its relation to regional climates and the paleoceanographic evolution of the California Current system during the late Pleistocene. Preliminary time scales developed by correlation of oxygen isotope stratigraphies with the global SPECMAP record show average linear sedimentation rates in excess of 100 m/m.y., which provide an opportunity for high-resolution studies of terrigenous flux, grain size, and mineralogy. The mass flux of terrigenous minerals at Site 1018 varies from 5 to 30 g/(cm**2 x k.y.) and displays a general trend toward increased flux during glacials. The terrigenous record at Site 1020 shows a similar pattern of increased glacial input, but overall accumulation rates are significantly lower. Spectral analysis demonstrates that most of this variability is concentrated in frequency bands related to orbital cycles of eccentricity, tilt, and precession. Detailed grain-size analysis performed on the isolated terrigenous mineral fraction shows that sediments from Site 1018 are associated with higher energy transport and depositional regimes than those found at Site 1020. Grain-size data are remarkably uniform throughout the last 500 k.y., with no discernible difference observed between glacial and interglacial size distributions within each site. X-ray diffraction analysis of the <2-µm clay component suggests that the deposition of minerals found at Site 1020 is consistent with transport from a southern source during intervals of increased terrigenous input.

Physical properties, sedimentation rates, and accumulation rates of bottom sediments from the Laptev Sea collected during SPASIBA-91 Russian-French Program

Humidity and wet and dry bulk densities were determined for bottom sediments of the Lena River marginal filter within a 700 km section from the outer boundary of the river delta. Earlier determinations of suspended matter concentration in water, material and grain-size composition and age of sediments were made along the same section. Sediment matter fluxes (accumulation rates), their changes in space and time (about 14 ka) were inferred from measurements of physical parameters. A correlation was found between the physical parameters of bottom sediments and changes in the Lena river marginal filter including those caused by sea-level fluctuations.

Eolian deposition on the Ontong Java Plateau

The record of eolian deposition on the Ontong Java Plateau (OJP) since the Oligocene (approximately 33 Ma) has been investigated using dust grain size, dust flux, and dust mineralogy, with the goal of interpreting the paleoclimatology and paleometeorology of the western equatorial Pacific. Studies of modern dust dispersal in the Pacific have indicated that the equatorial regions receive contributions from both the Northern Hemisphere westerly winds and the equatorial easterlies; limited meteorological data suggest that low-altitude westerlies could also transport dust to OJP from proximal sources in the western Pacific. Previous studies have established the characteristics of the grain-size, flux, and mineralogy records of dust deposited in the North Pacific by the mid-latitude westerlies and in the eastern equatorial Pacific by the low-latitude easterlies since the Oligocene. By comparing the OJP records with the well-defined records of the mid-latitude westerlies and the low-latitude easterlies, the importance of multiple sources of dust to OJP can be recognized. OJP dust is composed of quartz, illite, kaolinite/chlorite, plagioclase feldspar, smectite, and heulandite. Mineral abundance profiles and principal components analysis (PCA) of the mineral abundance data have been used to identify assemblages of minerals that covary through all or part of the OJP record. Abundances of quartz, illite, and kaolinite/chlorite covary throughout the interval studied, defining a mineralogical assemblage supplied from Asia. Some plagioclase and smectite were also supplied as part of this assemblage during the late Miocene and Pliocene/Pleistocene, but other source areas have supplied significant amounts of plagioclase, smectite, and heulandite to OJP since the Oligocene. OJP dust is generally coarser than dust deposited by the Northern Hemisphere westerlies or the equatorial easterlies, and it accumulates more rapidly by 1-2 orders of magnitude. These relationships indicate the importance of the local sources on dust deposition at OJP. The grain-size and flux records of OJP dust do not exhibit most of the events observed in the corresponding records of the Northern Hemisphere westerlies or the equatorial easterlies, because these features are masked by the mixing of dust from several sources at OJP. The abundance record of the Asian dust assemblage at OJP, however, does contain most of the features characteristic of dust flux by means of the Northern Hemisphere westerlies, indicating that the paleoclimatic and paleometeorologic signal of a particular source area and wind system can be preserved in areas well beyond the region dominated by that source and those winds. Identifying such a signal requires "unmixing" the various dust assemblages, which can be accomplished by combining grain-size, flux, and mineralogic data.