Characteristics of soils from the Quartermain Mountain area, Antarctica

Soil-forming processes and soil development rates are compared and contrasted on glacial deposits in two adjacent and coeval valleys of the Quartermain Mountains, which are important because they display Miocene glacial stratigraphy and some of the oldest landforms in the McMurdo Dry Valleys. More than 100 soil profiles were examined on seven drift sheets ranging from 115 000 to greater than 11.3 million years in age in Beacon Valley and Arena Valley. Although the two valleys contain drifts of similar age, they differ markedly in ice content of the substrate. Whereas Arena Valley generally has 'dry-frozen' permafrost in the upper 1 m and minimal patterned ground, Beacon Valley contains massive ice buried by glacial drift and ice-cored rock glaciers and has ice-cemented permafrost in the upper 1 m and considerable associated patterned ground. Arena Valley soils have twice the rate of profile salt accumulation than Beacon Valley soils, because of lower available soil water and minimal cryoturbation. The following soil properties increase with age in both valleys: weathering stage, morphogenetic salt stage, thickness of the salt pan, the quantity of profile salts, electrical conductivity of the horizon of maximum salt enrichment, and depth of staining. Whereas soils less than 200 000 years and older soils derived from sandstone-rich ground moraine are Typic Anhyorthels and Anhyturbels, soils of early Quaternary and older age, particularly on dolerite-rich drifts, are Petronitric Anhyorthels. Arena Valley has the highest pedodiversity recorded in the McMurdo Dry Valleys. The soils of the Quartermain Mountains are the only soils in the McMurdo Dry Valleys known to contain abundant nitrates.

Nd isotopic composition of fossil fish teeth and debris from ODP Legs 138, 165, and 202

Changes in circulation associated with the shoaling of the Isthmus of Panama and the Caribbean carbonate crash in the Miocene were investigated using Nd isotopes from fossil fish teeth and debris from two sites in the Caribbean Basin (Ocean Drilling Program Sites 998 and 999) and two sites in the eastern equatorial Pacific (Sites 846 and 1241). The total range for e-Nd values measured from 18 to 4.5 Ma in the Caribbean is -7.3 to 0. These values are higher than Atlantic water masses (~-11) and range up to values equivalent to contemporaneous Pacific water masses, confirming that flow into the Caribbean Basin was composed of a mixture of Pacific and Atlantic waters, with an upper limit of almost pure Pacific-sourced waters. Throughout the Caribbean record, particularly during the carbonate crash (10-12 Ma), low carbonate mass accumulation rates (MARs) correlate with more radiogenic e-Nd values, indicating increased flow of corrosive Pacific intermediate water into the Caribbean Basin during intervals of dissolution. This flow pattern agrees with results from general ocean circulation models designed to study the effect of the shoaling of the Central American Seaway. Low carbonate MARs and high e-Nd values also correlate with intervals of increased Northern Component Water production and, therefore, enhanced conveyor circulation, suggesting that the conveyor may respond to changes in circulation associated with shoaling of the Central American Seaway. Reduced Pacific throughflow related to shoaling of the seaway led to a gradual increase in carbonate preservation and more Atlantic-like e-Nd values following the carbonate crash.

Calcium carbonate contents and carbon and oxygen isotope compositions of bulk carbonate, ODP Leg 165 sediments

Two recently drilled Caribbean sites contain expanded sedimentary records of the late Paleocene thermal maximum, a dramatic global warming event that occurred at ca. 55 Ma. The records document significant environmental changes, including deep-water oxygen deficiency and a mass extinction of deep-sea fauna, intertwined with evidence for a major episode of explosive volcanism. We postulate that this volcanism initiated a reordering of ocean circulation that resulted in rapid global warming and dramatic changes in the Earth's environment.