(Table 1) Basalt geochemsitry at DSDP Hole 72-516F

Basalts from Hole 516F, DSDP Leg 72 on the Rio Grande Rise are tholeiitic in character but differ from normal mid-ocean ridge basalts in the South Atlantic in higher concentrations of incompatible elements such as Ti, K, V, Sr, Ba, Zr, Nb, and light rare-earth elements and in lower concentrations of Mg, Cr, and Ni. They contrast with previously reported basalts from the Rio Grande Rise, which were highly alkalic in character. The Rio Grande Rise basalts from Hole 516F (age 84.5 Ma) are generally similar to basalts from the eastern end of the Walvis Ridge (80-100 Ma). It is suggested that they either originated, like the Walvis Ridge, from a mantle hot spot that is different from the present-day hot spot (Tristan da Cunha) and that has changed composition with time, or from a spreading center that was shallow and chemically influenced by the adjacent hot spot, similar to the present-day Mid-Atlantic Ridge near the Azores and Tristan da Cunha.

(Table 1) Sound velocity, wet-bulk density, and acoustic impedance of some indurated sediment from DSDP Leg 64 Holes

The Pliocene-Quaternary sediments that we drilled at eight sites in the Gulf of California consist of silty clays to clayey silts, diatomaceous oozes, and mixtures of both types. In this chapter I have summarized various measurements of their physical properties, relating this information to burial depth and effective overburden pressure. Rapid deposition and frequent intercalations of mud turbidites may cause underconsolidation in some cases; overconsolidation probably can be excluded. General lithification begins at depths between 200 and 300 meters sub-bottom, at porosities between 55 and 60% (for silty clays) and as high as 70% (for diatomaceous ooze). Diatom-rich sediments have low strength and very high porosities (70-90%) and can maintain this state to a depth of nearly 400 meters (where the overburden pressure = 1.4 MPa). The field compressibility curves of all sites are compared to data published earlier. Where sediments are affected by basaltic sills, these curves clearly show the effects of additional loading and thermal stress (diagenesis near the contacts). Strength measurements on well-preserved hydraulic piston cores yielded results similar to those obtained on selected samples from standard drilling. Volumetric shrinkage dropped to low values at 100 to 400 meters burial depth (0.3 to 2.0 MPa overburden pressure). Porosity after shrinkage depends on the composition of sediments.