Data and Code archive for the interpolation of surface ocean carbon dioxide

We have developed a statistical gap-filling method adapted to the specific coverage and properties of observed fugacity of surface ocean CO2 (fCO2). We have used this method to interpolate the Surface Ocean CO2 Atlas (SOCAT) v2 database on a 2.5°×2.5° global grid (south of 70°N) for 1985-2011 at monthly resolution. The method combines a spatial interpolation based on a 'radius of influence' to determine nearby similar fCO2 values with temporal harmonic and cubic spline curve-fitting, and also fits long term trends and seasonal cycles. Interannual variability is established using deviations of observations from the fitted trends and seasonal cycles. An uncertainty is computed for all interpolated values based on the spatial and temporal range of the interpolation. Tests of the method using model data show that it performs as well as or better than previous regional interpolation methods, but in addition it provides a near-global and interannual coverage.

Chemical composition of the chalcophanite rich surface of an encrusted rock ashore Lake Macquarie, Australia

Mineralogical interest in the nature of manganese oxide particulates in natural marine water (Suess, 1979), natural lake water (Klaveness, 1977), and simulated lake water (Giovanoli, 1980), prompted a search for such particulates in a large New South Wales coastal lake. The investigated waters did show the existence of manganese oxide replacement phenomena in fragmentary sedimentary rocks near the south margin of Lake Macquarie. The black crusts of manganese oxide discovered on rocks close to the waterline have revealed a three layers structure. Layer A (0-35 micron), adjacent to the rock, is composed essentially of kaolinite of weathering origin, together with low levels of manganese oxide without detectable Zn. Layer B (35-80 micron) follows as a manganese oxide layer containing admixed kaolinite and low amounts of Zn. Layer C (80-130 micron) is the closest to the surface and is made of Chalcophanite containing 10-15% of ZnO.

(Fig 1, page 350) A manganese nodule in the top part of the CHUBASCO station 17 core taken in the Pacific Ocean

The vast extent of pelagic deposits, covering about 70 per cent of the ocean floor, thus about half of the earth, makes them of obvious importance to all Earth Science. All the pelagic (eupelagic) sediments, whether largely of plankton remains or fine inorganic particles, have certain distinctive characteristics to reflect their environment of accumulation. The great segregation of manganese in pelagic sediments presents many problems. It is hypothesized that in the formation of present day nodules a relatively slow accumulation in order to permit deposition of more of the manganese as large nodules, rather than as the disseminated micronodules that are in larger proportion in the Tertiary.

(Table 1, page 400) Metal content of different manganese nodules from cruise VA-04 (R/V Valdivia) in the Pacific Ocean

Deep sea manganese nodules are considered as important natural resources for the future because of their Ni, Cu and Co contents. Their different shapes cannot be correlated clearly with their chemical composition. Surface constitution, however, can be associated with the metal contents. A classification of the nodules is suggested on the basis of these results. The iron content of the nodules strikingly shows relations to the physical properties (e.g. density and porosity). The method of density-measurement is the reason for this covariance. The investigation of freeze-dried nodular substance does not give this result. The Fe-rich nodules lose more hydration water than the Fe-poor ones during heat drying. The reason for this effect is the different crystallinity, respectively the particle size. The mean particle size is calculated on the basis of geometrical models. The X-ray-diffraction analysis proves the variation of crystallinity in connection with the Fe-content, too. The internal nodular textures also show characteristic distinctions.

Analysis of manganese deposits from the Pacific Ocean

Sea floor dredging by the H.M.S. Challenger, the U.S.S. Albatross, the U.S.S. EPC(R) 857, and vessels of the Scripps Institution of Oceanography shows that extensive deposits of manganese nodules are on the deep sea floor and that crusts of manganese dioxide cover many seamounts. Sea floor photography reveals that in some places these crusts are quite continuous and the nodules are closely packed. These crusts and nodules are fully oxidized and hydrated mixtures of man¬ganese and iron plus earthy impurities. Also, relatively high concen¬trations of the trace elements nickel, copper, and cobalt are present.

Ultrasonic measurement of anisotropic reflectivity from Water-Phenolic CE Interface

In this contribution, we experimentally test the effects of azimuth and tilt angle on the acoustic reflectivity of a liquid- anisotropic solid interface. For this study, we are using a large source transducer, and acquired data for samples with different tilt angles. We use Phenolic CE material, which is known to have orthorhombic symmetry. Our results show that changes of the tilt angle produce important variations on the reflectivity that are larger as the tilt increases. The most remarkable feature is the change of the critical angle with the azimuth, which shows a larger spread for larger tilts. The spectral components of the acquired waveforms also show characteristic features linked to the location of the critical angle, we particularly observed a drop in the peak frequency. These observations suggest that care must be taken about the interpretation and inversion of observed incidence and azimuth dependent seismic reflectivities and critical angles in obtaining information on a formation's anisotropy. Zip archive contains four segy files: - LAB_TI00, is not tilted sample in contact with water, - LAB_TI30, is 30degrees tilted sample in contact with water, - LAB_TI45, is 45 degrees tilted sample in contact with water, - LAB_TI90, is 90 degrees tilted sample in contact with water.

(Table XIV-1, Page 137-139) Physical characteristics of manganese nodules collected in the Pacific Ocean during cruise GH76-1 of R/V Hakurei Maru

Nodule samples obtained were described and studied on board for 1) observation of occurrence and morphology in and outside samplers, size classification, measurement of weight and calculation of population density (kg/m2); 2) photographing whole nodules on the plate marked with the frames of unit areas of both 0cean-70 (0.50 m2) and freefall grab (0.13 m2), and that of typical samples on the plate with a 5 cm grid scale: 3) observation of internal structures of the nodules on cut section; and 4) determination of mineral composition by X-ray diffractometer. The relation between nodule types and geological environment or chemical composition was examined by referring to other data of related studies, such as sedimentology. acoustic survey, and chemical analysis.

Chemical composition of a concretion dredged from lake Madüsee (lake Miedwie, Poland)

This article describes the bottom sediments, lake ores and limestone bedrock dredged from lake Mad¸see in Pommerania now known as lake Miedwie in Poland.

Annotated record of the detailed examination of Mn deposits from the H.M.S. Penguin expedition to the Coral Sea

The analyses of the samples from the Balfour Shoal show that these deposits contain a very large quantity of carbonate of lime, ranging from 88.7 per cent, on the summit to 71.9 per cent, in the deeper water at the base of the cone. The decrease in the quantity of carbonate of lime with increase of depth is not quite regular; still, a general fall in the percentage of lime is clearly indicated from shallower to deeper water. As might be expected in such a circumscribed area, there is a great uniformity both in the chemical composition and relative abundance of the organic and inorganic constituents of the deposits. In all cases the carbonate of lime is almost wholly made up of the dead shells which have fallen from the surface waters - belonging to Plankton organisms such as Pteropods, Heteropods, pelagic Foraminifera and coccoliths. The calcareous shells were in very many cases discoloured brown or black by depositions of the peroxide of manganese. On the north-east steep side of the Balfour Shoal there were indications that depositions of manganese peroxide were more abundant than elsewhere. In 1645 fathoms, there was an angular fragment of a mottled yellowish jasper coated with manganese peroxide, and in 1570 fathoms there were three characteristic spherical black manganese nodules from one-half to three-fourths of an inch in diameter, quite similar to those procured by the Challenger in many areas of the Pacific and Atlantic. In one of these nodules the nucleus was a sub-angular fragment of a light-coloured augite-granophyre.

(Table, page 95) Chemistry of bog manganese concretions and wad from the Columbia County, New York

Bog manganese was long ago reported from various places in Columbia county (1:54) and it seemed well to reexamine these occurrences. According to W. W. Mather in his report of the First District Survey, 1836-42, " in the counties of Columbia and Dutchess 50,000 tons of manganese could be procured without any great expense, if carefully prepared." He also stated that some of the bog manganese showed on analysis as high as 68.5 per cent manganese oxide and less than 5 per cent silica. At the direction of the State Geologist the writer has devoted most of the summer of 191 7 to this work. The results of this investigation, though not in any way confirming the quantitative results of Mr Mather, are herewith published as a matter of record and as an account of the manner of the occurrence and the genesis of postglacial bog manganese.

Annotated record of the detailed examination of Mn deposits from R/V Tokaidaigaku Maru II Cruise GDP-1 stations

The present paper, deals with the results of the bottom sampling. Sampling devices were a gravity corer for heat flow measurement and dredges of bucket type.