Diatom abundance in ODP Leg 178 holes

This paper documents the biostratigraphic distribution and abundance of diatoms from sites drilled during Ocean Drilling Program Leg 178, off the Pacific margin of the Antarctic Peninsula. Drift sediments cored on the continental rise at Sites 1095, 1096, and 1101 have good recovery and a well-defined paleomagnetic record. Well-preserved diatoms are present throughout the upper Miocene to middle Pliocene and in the upper Quaternary section of these sites. The stratigraphic occurrence of diatom species through these intervals defines numerous datum levels. Diatom events are given absolute age estimates through direct correlation to the established paleomagnetic stratigraphy of Sites 1095, 1096, and 1101. Leg 178 diatom biostratigraphic results enable the development of a regional stratigraphic framework for the Pacific sector of the Southern Ocean and record the interaction of open-ocean and shelf-margin diatom floras.

Major element concentrations in spinel, olivine and pyroxene from peridotites of ODP Hole 210-1277 of the Newfoundland margin

Serpentinized spinel peridotites of the Newfoundland margin drilled during ODP Leg 210 at Site 1277 have preserved, relic mineral compositions similar to the most depleted abyssal peridotites worldwide and different from those of the conjugate Iberian margin. The samples are derived from mass flows containing clasts of peridotite and gabbro and from in-situ basement, and are mostly mylonitic cpx-poor spinel harzburgites with Cr-rich spinels (Cr#0.35-0.66). Melting of the Newfoundland mantle occurred in the spinel peridotite field and probably exceeded the cpx-out phase boundary for some samples. Using proposed spinel peridotite melting models and experimentally derived phase diagrams, the Newfoundland harzburgites can be modeled as a residue after extraction of 14 to 20-25% melting. Basalts that are interleaved with mass flow deposits on top of the peridotite basement resemble normal to transitional mid-ocean ridge basalt. This, together with the unusually high Cr# of some spinel harzburgites suggest that the formation of basalts and partial melting of the underlying peridotite are not cogenetic. Among mantle samples some of the Newfoundland harzburgites approach mineral compositions of the Bay of island ophiolite and ophiolites from Japan that represent peridotites formed in an arc-setting. Thus, the peridotites drilled at Site 1277 may represent inherited (Caledonian or older) subarc mantle that was exhumed close to the ocean floor during the rifting evolution of the Atlantic. Compared to the spinel harzburgites from Newfoundland, the peridotites from the conjugate Iberian margin are, on average, less depleted and provide evidence for local equilibration in the plagioclase stability field. This can either be explained by an inherited, primary, Ca-richer composition of the Iberia peridotite, or, alternatively, by local melt impregnation and stagnation during continental rifting, and thus refertilizing previously depleted (arc-related) peridotite.

Revision of the early-middle Pleistocene calcareous nannofossil biochronology

The extant nannofossil biostratigraphic and biochronologic framework for the early-middle Pleistocene time interval has been tested through the micropaleontological analysis of globally distributed high-quality low- to mid-latitude deep-sea successions. The quantitative temporal distribution patterns of relative abundances of selected taxa were reconstructed in critical intervals, and the following biohorizons were defined: first occurrence of medium-sized Gephyrocapsa spp. (bmG); last occurrence of Calcidiscus macintyrei (tCm); first occurrence of large Gephyrocapsa spp. (blG); last occurrence of large Gephyrocapsa spp. (tlG); first occurrence of Reticulofenestra asanoi (bRa); re-entrance of medium-sized Gephyrocapsa spp. (reemG) and last occurrence of Reticulofenestra asanoi (tRa). The detailed patterns of abundance change at these biohorizons were used to generate a detailed biostratigraphy, and the biostratigraphic data were transformed into a precise biochronology by means of correlation to isotope stratigraphies and astronomical timescales. The degree of isochrony or diachrony of the biohorizons was evaluated. Biohorizons tlG and tRa are isochronous occurring close to marine isotope stages (MIS)55 and MIS 22, respectively, and bmG and blG are slightly diachronous on the order of 30-40 kyr, whereas biohorizons tCm, reemG and bRa are confirmed as diachronous on the order of 100, 80 and 60 kyr, respectively. Some of the events are clearly controlled by environmental conditions, e.g. the last occurrence of R. asanoi, related to significant environmental changes associated with the first large-amplitude glaciation of the late Quaternary, MIS 22.

Holocene millenial-scale productivity record in the Mediterranean Sea

The calcareous nannofossil assemblages of Ocean Drilling Program Hole 963D from the central Mediterranean Sea have been investigated to document oceanographic changes in surface waters. The studied site is located in an area sensitive to large-scale atmospheric and climatic systems and to high- and low-latitude climate connection. It is characterized by a high sedimentation rate (the achieved mean sampling resolution is <70 years) that allowed the Sicily Channel environmental changes to be examined in great detail over the last 12 ka BP. We focused on the species Florisphaera profunda that lives in the lower photic zone. Its distribution pattern shows repeated abundance fluctuations of about 10-15%. Such variations could be related to different primary production levels, given that the study of the distribution of this species on the Sicily Channel seafloor demonstrates the significant correlation to productivity changes as provided by satellite imagery. Productivity variations were quantitatively estimated and were interpreted on the basis of the relocation of the nutricline within the photic zone, led by the dynamics of the summer thermocline. Productivity changes were compared with oceanographic, atmospheric, and cosmogenic nuclide proxies. The good match with Holocene master records, as with ice-rafted detritus in the subpolar North Atlantic, and the near-1500-year periodicity suggest that the Sicily Channel environment responded to worldwide climate anomalies. Enhanced Northern Hemisphere atmospheric circulation, which has been reported as one of the most important forcing mechanisms for Holocene coolings in previous Mediterranean studies, had a remarkable impact on the water column dynamics of the Sicily Channel.

Geochemistry of plagioclase from the Mid-Atlantic Ridge

We have studied the chemical zoning of plagioclase phenocrysts from the slow-spreading Mid-Atlantic Ridge and the intermediate-spreading rate Costa Rica Rift to obtain the time scales of magmatic processes beneath these ridges. The anorthite content, Mg, and Sr in plagioclase phenocrysts from the Mid-Atlantic Ridge can be interpreted as recording initial crystallisation from a primitive magma (~11 wt% MgO) in an open system. This was followed by crystal accumulation in a mush zone and later entrainment of crystals into the erupted magma. The initial magma crystallised plagioclase more anorthitic than those in equilibrium with any erupted basalt. Evidence that the crystals accumulated in a mush zone comes from both: (1) plagioclase rims that were in equilibrium with a Sr-poor melt requiring extreme differentiation; and (2) different crystals found in the same thin section having different histories. Diffusion modelling shows that crystal residence times in the mush were <140 years, whereas the interval between mush disaggregation and eruption was ?1.5 years. Zoning of anorthite content and Mg in plagioclase phenocrysts from the Costa Rica Rift show that they partially or completely equilibrated with a MgO-rich melt (>11 wt%). Partial equilibration in some crystals can be modelled as starting <1 year prior to eruption but for others longer times are required for complete equilibration. This variety of times is most readily explained if the mixing occurred in a mush zone. None of the plagioclase phenocrysts from the Costa Rica Rift that we studied have Mg contents in equilibrium with their host basalt even at their rims, requiring mixing into a much more evolved magma within days of eruption. In combination these observations suggest that at both intermediate- and slow-spreading ridges: (1) the chemical environment to which crystals are exposed changes on annual to decadal time scales; (2) plagioclase crystals record the existence of melts unlike those erupted; and (3) disaggregation of crystal mush zones appears to precede eruption, providing an efficient mechanism by which evolved interstitial melt can be mixed into erupted basalts.

Occurence of foraminifera and other microfossils in sediment core CRP-2/2A (Table 1)

Sparse to moderately abundant foraminiferal assemblages from Oligocene and Lower Miocene sediments in the CRP-2/2A drillhole contain C.27 genera and 42 species of calcareous benthic foraminifera. No planktic or agglutinated taxa were observed. On the basis of their faunal characteristics, four Foraminiferal Units are defined in drillhole succession: Foraminiferal Unit I (26.91-193.95 mbsf), mostly sparse assemblages with Elphidium magellanicum and Cribroelphidium sp.; Foraminiferal Unit II (193.95-342.42 mbsf), mostly moderately abundant assemblages with Cassidulinoides aequilatera and Eponides bradyi; Foraminiferal Unit III (342.42-486.19 mbsf), moderately abundant to sparse assemblages characterised by Cassidulinoides chapmani and Stainforthia sp.; and Foraminiferal Unit IV, Improverished (486.19-624.15, total depth, mbsf), with mostly barren residues, but with large Milioliidae recorded in situ at various horizons in the drill core. Foraminiferal Units I-IV lack taxa allowing correlation to standard zonal schemes. Inspection of faunal records from CIROS-1 and DSDP 270 indicates that, although the faunas show an overall similarity, CRP-2/2A Foraminiferal Units I-IV are not identifiable at these sites. The units are therefore most likely to reflect local environmental changes, and probably will prove useful for local correlation, but their lateral extent is undetermined. All four assemblages apparently represent various glacially-influenced shelf environments, and appear to reflect a long term deepening trend from Units IV to II, from perhaps inner to mid or outer-shelf depths, followed by a return to shallower, inner shelf, conditios for Unit I.

Stable oxygen and carbon isotopes from ODP sites on Maud Rise and Kerguelen Plateau

Paleogene stable oxygen and carbon isotopes were measured in formainifera from ODP Sites 689 and 690 at Maud Rise in the Atlantic Ocean sector of the Southern Ocean, and from Sites 738, 744, 748 and 749 at the southern Kerguelen Plateau in the Indian Ocean sector. These data were compared with sedimentological data from the same sample set. Both benthic and planktic d18O values document a cooling trend beginning around 49.5 Ma at all sites. During the late middle Eocene planktic d18O values indicate a steepening latitudinal temperature gradient from 14°C at the northern sites towards 10°C at the southernmost sites. Terrigeneous sand grains of probably ice rafted origin and clay mineral assemblages point to the existence of a limited East Antarctic ice cap with some glaciers reaching sea level as early as middle Eocene time around 45.5 Ma. Between 45 and 40 Ma, average paleotemperatures were between 5° and 7°C in deep and intermediate water masses, while near-surface water masses ranged between 6° and 10°C. During the late Eocene, between 40 and 36 Ma, average temperatures further decreased to 4°-5°C in the deep and intermediate water masses and to 5°-8°C near the sea surface. Abruptly increasing d18O values at approximately 35.9 Ma exactly correlate with a sharp pulse in the deposition of ice-rafted material on the Kerguelen Plateau, a dramatic change in clay mineral composition, and an altered Southern Ocean circulation indicated by a differentiation of benthic d13C values between sites, increasing opal concentrations and decreasing carbonate contents. For planktic and benthic foraminifera this d18O increase ranges between 1.0 and 1.3 per mil, and between 0.9 and 1.4 per mil, respectively. We favour a hypothesis that explains most of the d18O shift at 35.9 Ma with a buildup of a continental East Antarctic ice sheet. Consequently, relatively warm Oligocene Antarctic surface water temperatures probably are explained by a temperate, wet-based nature of the ice sheet. This would also aid in the fast build-up of an ice sheet by enhancing the moisture transport on to the continent.

Chemistry of earliest Cretaceous bentonites

Bentonites (i.e., smectite-dominated, altered volcanic ash layers) were discovered in Berriasian to Valanginian hemipelagic (shelfal) to eupelagic (deep-sea) sediments of the Wombat Plateau (Site 761), Argo Abyssal Plain (Sites 261, 765), southern Exmouth Plateau (Site 763), and Gascoyne Abyssal Plain (Site 766). A volcaniclastic origin with trachyandesitic to rhyolitic ash as parent material is proved by the abundance of well-ordered montmorillonite, fresh to altered silicic glass shards, volcanogenic minerals (euhedral sanidine, apatite, slender zircon), and rock fragments, and by a vitroclastic ultra-fabric (smectitized glass shards). For the Argo Abyssal Plain, we can distinguish four types of bentonitic claystones of characteristic waxy appearance: (1) pure smectite bentonites, white to light gray, sharp basal contacts, and a homogeneous cryptocrystalline smectite matrix, (2) thin, greenish-gray bentonitic claystones having sharp upper and lower contacts, (3) gray-green bentonitic claystones mottled with background sedimentation and a distinct amount of terrigenous and pelagic detrital material, and (4) brick-red smectitic claystones having diffuse sedimentary contacts and a doubtful volcanic origin. For the other drill sites, we can distinguish between (1) pure bentonitic claystones similar in appearance and chemical composition to Type 1 of the Argo Abyssal Plain (except for gradual basal contacts) and (2) impure bentonitic claystones containing textures of volcanogenic smectite and pyroclastic grains with terrigenous and pelagic components resulting from resedimentation or bioturbation. The ash layers were progressively altered (smectitized) during diagenesis. Silicic glass was first hydrated, then slightly altered (etched with incipient smectite authigenesis), then moderately smectitized (with shard shape still intact), and finally, completely homogenized to a pure smectite matrix without obvious relict structures. Volcanic activity was associated with continental breakup and rapid subsidence during the "juvenile ocean phase." Potential source areas for a Neocomian post-breakup volcanism include Wombat Plateau, Joey and Roo rises, Scott Plateau, and Wallaby Plateau/Cape Range Fracture Zone. Westward-directed trade winds transported silicic ash from these volcanic source areas to the Exmouth Plateau and, via turbidity currents, into the adjacent abyssal plains. The Wombat and Argo abyssal plain bentonites are interpreted, at least in parts, as proximal or distal ash turbidites, respectively.

Carbonate content and d13C record of a Jordan Cretaceous outcrop (Section GM3 (Ghawr Al Mazar (Ghor al Mazrar))

An evaluation of the global synchronicity and duration of "3rd-order" sea-level fluctuations during the Cretaceous greenhouse has been hampered by poor constraints on potential climatic and tectonic drivers, and limitations of geochronology and chronostratigraphic correlation. To provide insight into the nature of such sea-level fluctuations, here we present a new Late Cretaceous record from the Jordanian Levant Platform, comprising a detailed physical-, bio-, chemo- and sequence stratigraphy. Carbonate content of these strata reflects overall sequence stratigraphic development, and demonstrates a dramatic 3rd-order-scale cycle that is also apparent in the d°C record. Updated radioisotopic constraints and astrochronologic testing provide support for the inference of an ~1 million year long sea-level oscillation associated with this 3rd-order cycle, which likely reflects a long-period obliquity (1.2 Myr) control on eustasy and stratigraphic sequence development, linked to the global carbon cycle. The observation of cyclic sea-level fluctuations on this time scale suggests sustained global modulation of continental fresh-water-storage. The hypothesized link between astronomical forcing and sea-level forms a baseline approach in the global correlation of sequence boundaries.

Radiogenic isotope trace composition of the Labrador Sea

Geological reconstructions and general circulation models suggest that the onset of both Northern Hemisphere glaciation, 2.7 Myr ago, and convection of Labrador Sea Water (LSW) were caused by the closure of the Panama Gateway ~4.5 Myr ago. Time series data that have been obtained from studies of ferromanganese crusts from the northwestern Atlantic suggest that radiogenic isotopes of intermediate ocean residence time (Pb and Nd) can serve as suitable tracers to reconstruct these events. However, it has been unclear until now as to whether the changes that have been observed in isotope composition at this time are the result of increased thermohaline circulation or due to the effects of increased glacial weathering. In this paper we adopt a box model approach to demonstrate that the shifts in radiogenic isotope compositions are unlikely to be due to changes in convection in LSW but can be explained in terms of increases of erosion levels due to the glaciation of Greenland and Canada. Furthermore, we provide experimental evidence for the incongruent release of a labile fraction of strongly radiogenic Pb and nonradiogenic Nd from continental detritus eroding into the Labrador Sea. This can be attributed to the glacial weathering of old continents and accounts for the paradox that one of the areas of the world most deficient in radiogenic Pb should provide such a rich supply of radiogenic Pb to the oceans. An important general conclusion is that the compositions of radiogenic isotopes in seawater are not always a reflection of their continental sources. Perhaps more importantly, the transition from chemical weathering to mechanical erosion is likely to result in significant variations in radiogenic tracers in seawater.

Annual average Sr/Ca measurements from Porites lutea coral at Ha'afera Island, Tonga

In the South Pacific Convergence Zone (SPCZ), the variability in a sub-seasonally resolved microatoll Porites colony Sr/Ca record from Tonga and a previously published high-resolution record from Fiji are strongly influenced by sea surface temperature (SST) over the calibration period from 1981 to 2004 (R^2 = 0.67 - 0.68). However, the Sr/Ca-derived SST correlation to instrumental SST decreases back in time. The lower frequency secular trend (~1°C) and decadal-scale (~2 - 3°C) modes in Sr/Ca-derived SST are almost two times larger than that observed in instrumental SST. The coral Sr/Ca records suggest that local effects on SST generate larger amplitude variability than gridded SST products indicate. Reconstructed d18O of seawater (d18Osw) at these sites correlate with instrumental sea surface salinity (SSS; r = 0.64 - 0.67) but not local precipitation (r = -0.10 to - 0.22) demonstrating that the advection and mixing of different salinity water masses may be the predominant control on d18Osw in this region. The Sr/Ca records indicate SST warming over the last 100 years and appears to be related to the expansion of the western Pacific warm pool (WPWP) including an increasing rate of expansion in the last ~20 years. The reconstructed d18Osw over the last 100 years also shows surface water freshening across the SPCZ. The warming and freshening of the surface ocean in our study area suggests that the SPCZ has been shifting (expanding) southeast, possibly related to the southward shift and intensification of the South Pacific gyre over the last 50 years in response to strengthened westerly winds.

Silicoflagellates of ODP Leg 119 samples

The occurrence of Quaternary and Oligocene silicoflagellates at two Ocean Drilling Program (ODP) Leg 119 Holes (736A and 744A) on the Kerguelen Plateau in the Southern Ocean was investigated to compare species distributions to Northern Hemisphere floras. This abstract gives the data determined (Tables 1 and 2) for 24 samples and few preliminary remarks. Quaternary assemblages of Hole 736A are noteworthy for the absences of key North Pacific zonal guide species such as Bachmannocena quadrangula, Dictyocha aculeata, Dictyocha subarctios, and Distephanus octangulatus (Bukry and Monechi, 1985). Other species such as Distephanus floridus, Distephanus speculum elongatus, and Mesocena octagona show limited ranges in Hole 736A and may help to subdivide the Quaternary locally. The late Oligocene assemblages of Hole 744A contain widely distributed species of Distephanus and Naviculopsis, which permit correlation to lower latitude assemblages. They also contain the high-latitude acme of Distephanus raupii which was first noted at Deep Sea Drilling Project (DSDP) Hole 278 (56°3.42'S, 160°04.29'E, water depth 3689 m) by Perch-Nielsen (1975) and Bukry (1975). Study of Hole 744A assemblages suggests that D. raupii developed from pentagonal Dictyocha deflandrei deflandrei. A final note on the Hole 744A assemblages is the brief late Oligocene acme (25%) of Dictyocha sp. aff. D. spinosa in Sample 119-744A-13H-4, 65-67 cm, which provides a direct correlation to the acme (16%) in DSDP Sample 29-278-31R-CC (Perch-Nielsen, 1975) in the Southern Ocean. Most of the taxonomy used in the tables is documented in earlier publications of the DSDP Initial Reports (see Bukry in Volumes 16, 35, 37, 40, 44, 49, 54, 67, 68, 69, 81, and 95). Also, see Loeblich et al. (1968) and Perch-Nielsen (1985) for extensive taxonomy and illustrations.

Geochemistry at DSDP Leg 70 Holes

The hydrothermal mounds on the southern flank of the Galapagos Spreading Center are characterized by the following main features: 1) They are located over a young basement (0.5 to 0.85 m.y. of age) in a region known for its high sedimentation rate (about 5 cm/10**3 y.) because it is part of the equatorial high biological productivity zone. 2) They are located in a region with generally high heat flow (8 to 10 HFU). The highest heat-flow measurements (up to 10**3 HFU) correspond to mound peaks (Williams et al., 1979), where temperatures up to 15°C were measured during a dive of the submersible Alvin (Corliss et al., 1978). 3) They are often located on small vertical faults which displace the basement by a few meters (Lonsdale, 1977) and affect the 25- to 50-meter-thick sediment cover. Most of these characteristics have also been observed in the other three known cases of hydrothermal deposits with mineral parageneses similar to that of the Galapagos mounds. However, the case of the hydrothermal mounds south of the Galapagos Spreading Center is unique because of the unusual thickness of the hydrothermal deposits present. The mounds are composed of several, up to 4.5-meter-thick, layers of green clays which, in one case (Hole 509B), are overlain by about 1.4 meters of Mn-oxide crust. We suspect that such a large accumulation of hydrothermal products results from the "funnelling" of the hydrothermal solutions exiting from a highly permeable basement along the faults. This chapter reports a preliminary study of those green clays collected by hydraulic piston coring of the Galapagos mounds during Deep Sea Drilling Project (DSDP) Leg 70 of the D/V Glomar Challenger. Green clays have also been reported from three presently or recently active hydrothermal areas in or close to spreading centers.

Magnetic properties of two cores from the Iberian Margin

Magnetic properties of late Quaternary sediments on the SW Iberian Margin are dominated by bacterial magnetite, observed by transmission electron microscopy (TEM), with contributions from detrital titanomagnetite and hematite. Reactive hematite from eolian dust, together with low organic matter concentrations and the lack of sulfate reduction, lead to dissimilatory iron reduction and availability of Fe(II) for abundant magnetotactic bacteria. Magnetite grain-size proxies (kARM/k and ARM/IRM) and S-ratios (sensitive to hematite) vary on stadial/interstadial timescales, contain orbital power, and mimic planktic d18O. The detrital/biogenic magnetite ratio and hematite concentration are greater during stadials and glacial isotopic stages, reflecting increased detrital (magnetite) input during times of lowered sea level, coinciding with atmospheric conditions favoring hematitic dust supply. Magnetic susceptibility, on the other hand, has a very different response being sensitive to coarse detrital multidomain (MD) magnetite associated with ice-rafted debris (IRD). High susceptibility and/or magnetic grain size coarsening, mark Heinrich stadials (HS), particularly HS2, HS3, HS4, HS5, HS6 and HS7, as well as older Heinrich-like detrital layers, indicating the sensitivity of this region to fluctuations in the position of the polar front. Relative paleointensity (RPI) records have well-constrained age models based on planktic d18O correlation to ice-core chronologies, however, they differ from reference records (e.g. PISO) particularly in the vicinity of glacial maxima, mainly due to inefficient normalization of RPI records in intervals of enhanced detrital/eolian hematite input.

Biogenic flux and primary production of sediment traps in the Atlantic and the Southern Ocean

Fluxes of organic carbon normalised to a depth of 1000 m from 18 sites in the Atlantic and the Southern Ocean are presented, comprising nine biogeochemical provinces as defined by Longhurst et al. (1995. Journal of Plankton Research 17, 1245-1271). For comparison with primary production, we used a recent compilation of primary production values derived from CZCS data (Antoine et al., 1996. Global Biogeochemical Cycles 10, 57-69). In most cases, the seasonal patterns stood reasonably well in accordance with the carbon fluxes. Particularly, organic carbon flux records from two coastal sites off northwest and southwest Africa displayed a more distinct correlation to the primary production in sectors (1 x 1°) which are situated closer to the coastal environments. This was primarily caused by large upwelling filaments streaming far offshore, resulting in a cross-shelf carbon transport. With respect to primary production, organic carbon export to a water depth of 1000 m, and the fraction of primary production exported to a depth of 1000 m (export fraction=EF1000), we were able to distinguish between: (1) the coastal environments with highest values (EF1000=1.75-2.0%), (2) the eastern equatorial upwelling area with moderately high values (EF1000=0.8-1.1%), (3) and the subtropical oligotrophic gyres that yielded lowest values (EF1000=0.6%). Carbon export in the Southern Ocean was low to moderate, and the EF1000 value seems to be quite low in general. Annual organic carbon fluxes were proportional to primary production, and the export fraction EF1000 increased with primary production up to 350 gCm**-2 yr**-1. Latitudinal variations in primary production were reflected in the carbon flux pattern. A high temporal variability of primary production rates and a pronounced seasonality of carbon export were observed in the polar environments, in particular in coastal domains, although primary production (according to Antoine et al., 1996. Global Biogeochemical Cycles 10, 57-69), carbon fluxes, and the export fraction remained at low.