(Table 1) K-Ar age and inert-gas-isotopes at DSDP Holes 68-501, 69-504B and 69-505B

Conventional K-Ar ages have been determined and inert-gas abundances have been measured on representative samples of altered rocks from Deep Sea Drilling Project Holes 501, 504B, and 505B in an attempt to correlate their degree of alteration with inert-gas and K-Ar data. Samples taken from the first 60 meters below the sediment/basalt interface give significantly higher ages than would be expected from the magnetic stratigraphy, though at greater depths the calculated ages are in broad agreement with the expected age. The inert gas ratios 20Ne/36Ar, 36Ar/84Kr, and 84Kr/130Xe also show a marked discontinuity at the 60-meter depth, and all these effects are interpreted as being a consequence of low-temperature alteration produced by burial metamorphism and by interaction with sea water (halmyrolysis).

Table 4. Trace gas concentrations from samples taken at Ginninderra

We assess the performance of an inverse Lagrangian dispersion technique for its suitability to quantify leakages from geological storage of CO2. We find the technique is accurate ((QbLS/Q)=0.99, sigma=0.29) when strict meteorological filtering is applied to ensure that Monin-Obukhov Similarity Theory is valid for the periods analysed and when downwind enrichments in tracer gas concentration are 1% or more above background concentration. Because of their respective baseline atmospheric concentrations, this enrichment criterion is less onerous for CH4 than for CO2. Therefore for geologically sequestered gas reservoirs with a significant CH4 component, monitoring CH4 as a surrogate for CO2 leakage could be as much as 10 times more sensitive than monitoring CO2 alone. Additional recommendations for designing a robust atmospheric monitoring strategy for geosequestration include: continuous concentration data; exact inter-calibration of up- and downwind concentration measurements; use of an array of point concentration sensors to maximise the use of spatial information about the leakage plume; and precise isotope ratio measurement to confirm the source of any concentration elevations detected.

(Table 1) Downhole variation of potassium, apparent K-Ar age, and inert gas abundances at DSDP Holes 69-504B, 70-504B and 83-504B

Ne, Ar, Kr, Xe, and K2O were measured in representative samples of holocrystalline basalt from DSDP Hole 504B. No hiatus in inert gas abundance is recognized at the base of the "oxic" alteration zone and the extent rather than the nature of alteration appears to determine these abundances. When the inert gas abundances are separately plotted against K2O, two distinct trends of loss emerge, one for alteration involving K-gain, the other for K-loss. Apparent whole-rock K-Ar ages are anomalous in the upper 50 m of basement, and below 300 m sub-basement. In the intervening zone of basement, celadonization adds sufficient potassium and eliminates enough "primary" 40Ar early in the history of the basalts for "excess" 40Ar to become subordinate to radiogenic 40Ar in basalts showing potassium enrichment greater than 0.2%. Stratigraphically correct K-Ar ages are obtained, therefore, from K-enriched basalts of the oxic alteration zone.