Magnetic properties of ODP Site 175-1075

We present sediment magnetic and chemical analysis of cyclic ocean sediments of the upwelling region of the Lower Congo Basin (equatorial Atlantic). We investigated two >100-k.y. intervals from Ocean Drilling Program Site 1075 to analyze the hysteresis properties, sources of magnetic susceptibility, anhysteretic remanent magnetizations, thermomagnetic behavior, and element concentrations of Fe, Ca, Ti, Mn, and K using an X-ray fluorescence (XRF) core scanner. The upper interval was sampled between 14 and 32 meters composite depth (mcd; 0.09-0.21 Ma) and the lower between 141 and 163 mcd (1.31-1.54 Ma) at a resolution of 20 cm, which represents a temporal resolution of 2.0 and 1.3 k.y., respectively. XRF core-scanner data were acquired at 5-cm intervals. The measurements show that ferri(o)magnetic minerals have no significant influence on the cyclicity of the magnetic susceptibility, which is dominated by paramagnetic and diamagnetic minerals and reflects changes of sediment input from the Congo River. The Fe, Ti, K, and Mn concentrations covary with the magnetic susceptibility where high concentrations of these elements correlate with intervals of high susceptibility and low concentrations with intervals of low susceptibility. The Ca counts correlate well with the calcium carbonate concentration but do not show the same cyclicity as the other elements or the susceptibility. With the exception of the Ca concentration, which is significantly higher in the upper interval, and the magnetic grain size, which indicates that less fine grained magnetite is present in the lower interval, no significant differences in the properties of the upper and the lower intervals were detected.

Mineralogy and major element oxide composition of sediments from ODP Hole 172-1063D

Dansgaard-Oeschger (D-O) cycles in sediment at Site 1063 are characterized by distinct fluctuations in physical properties. Stadials are marked by low bulk density and interstadials by high bulk density. Compressional (P-)wave velocity is in phase with bulk density over some but not all depth intervals. Four of the D-O cycles straddling the oxygen isotope Stage 4/5 boundary have been studied in detail to understand the origin of the physical properties changes. Sediment on the Bermuda Rise is comprised of three main components: calcite, aluminosilicate minerals, and biogenic silica. Calcite concentrations vary from 1% to 43% of bulk sediment and are highest during interstadials. Aluminosilicate concentrations vary from 52% to 92% of bulk sediment and are highest during stadials. The major element ratios Al2O3/TiO2 and K2O/Al2O3 show increases across bulk density cycles, suggesting a change in the composition of aluminosilicates. This interpretation is supported by mineralogical analyses, which show a subtle change in clay composition. Biogenic silica concentrations vary from 0% to 23% of bulk sediment and are also highest during stadials. However, the abundance of silica varies significantly from one D-O cycle to another. Silt and fine sand abundance also increase during the first of the four stadials. This coarsening of sediment coincides with the increase in biogenic silica. The low grain density and high porosity associated with biogenic silica result in intervals of low bulk-sediment density. The abundance of biogenic silica closely matches P-wave velocity, suggesting that silica imparts a greater rigidity to the sediment.

Eocene sedimentary calcium carbonate contents and stable isotope composition of benthic foraminifera

'Hyperthermals' are intervals of rapid, pronounced global warming known from six episodes within the Palaeocene and Eocene epochs (~65-34 million years (Myr) ago) (Zachos et al., 2005, doi:10.1126/science.1109004; 2008, doi:10.1038/nature06588; Roehl et al., 2007, doi:10.1029/2007GC001784; Thomas et al., 2000; Cramer et al., 2003, doi:10.1029/2003PA000909; Lourens et al., 2005, doi:10.1038/nature03814; Petrizzo, 2005, doi:10.2973/odp.proc.sr.198.102.2005; Sexton et al., 2006, doi:10.1029/2005PA001253; Westerhold et al., 2007, doi:10.1029/2006PA001322; Edgar et al., 2007, doi:10.1038/nature06053; Nicolo et al., 2007, doi:10.1130/G23648A.1; Quillévéré et al., 2008, doi:10.1016/j.epsl.2007.10.040; Stap et al., 2010, doi:10.1130/G30777.1). The most extreme hyperthermal was the 170 thousand year (kyr) interval (Roehl et al., 2007) of 5-7 °C global warming (Zachos et al., 2008) during the Palaeocene-Eocene Thermal Maximum (PETM, 56 Myr ago). The PETM is widely attributed to massive release of greenhouse gases from buried sedimentary carbon reservoirs (Zachos et al., 2005; 2008; Lourenbs et al., 2005; Nicolo et al., 2007; Dickens et al., 1995, doi:10.1029/95PA02087; Dickens, 2000; 2003, doi:10.1016/S0012-821X(03)00325-X; Panchuk et al., 2008, doi:10.1130/G24474A.1) and other, comparatively modest, hyperthermals have also been linked to the release of sedimentary carbon (Zachos et al., 2008, Lourens et al., 2005; Nicolo et al., 2007; Dickens, 2003; Panchuk et al., 2003). Here we show, using new 2.4-Myr-long Eocene deep ocean records, that the comparatively modest hyperthermals are much more numerous than previously documented, paced by the eccentricity of Earth's orbit and have shorter durations (~40 kyr) and more rapid recovery phases than the PETM. These findings point to the operation of fundamentally different forcing and feedback mechanisms than for the PETM, involving redistribution of carbon among Earth's readily exchangeable surface reservoirs rather than carbon exhumation from, and subsequent burial back into, the sedimentary reservoir. Specifically, we interpret our records to indicate repeated, large-scale releases of dissolved organic carbon (at least 1,600 gigatonnes) from the ocean by ventilation (strengthened oxidation) of the ocean interior. The rapid recovery of the carbon cycle following each Eocene hyperthermal strongly suggests that carbon was resequestered by the ocean, rather than the much slower process of silicate rock weathering proposed for the PETM (Zachos et al., 2005; 2003). Our findings suggest that these pronounced climate warming events were driven not by repeated releases of carbon from buried sedimentary sources (Zachos et al., 2008, Lourens et al., 2005; Nicolo et al., 2007; Dickens, 2003; Panchuk et al., 2003) but, rather, by patterns of surficial carbon redistribution familiar from younger intervals of Earth history.

Geochemistry of volcanivlastic sediments of ODP Sites 134-832 and 134-833

Volcaniclastic sediments of North Aoba Basin (Vanuatu) recovered during Ocean Drilling Program (ODP) Leg 134 show a mineralogical and chemical overprint of low grade hydrothermal alteration superimposed on the primary magmatic source compositions. The purpose of this study was to identify authigenic mineral phases incorporated in the volcaniclastic sediments, to distinguish authigenic chemical and mineralogical signals from the original volcaniclastic mineralogical and chemical compositions, and to determine the mechanism of authigenic minerals formation. Mineralogical, micro-chemical and bulk chemical analyses were utilized to identify and characterize authigenic phases and determine the original unaltered ash compositions. 117 volcaniclastic sediment samples from North Aoba Basin Sites 832 and 833 were analyzed. Primary volcaniclastic materials accumulated in North Aoba Basin can be divided into three types. The older basin-filling sequences show three different magmatic trends: high K, calc-alkaline, and low K series. The most recent accumulations are rhyodacitic composition and can be attributed to Santa Maria or Aoba volcanic emissions. Original depositional porosity of volcaniclastic sediments is an important factor in influencing distribution of authigenic phases. Finer-grained units are less altered and retain a bulk mineralogical and chemical composition close to the original pyroclastic rock composition. Coarser grained units (microbreccia and sandstones) are the major hosts of authigenic minerals. At both sites, authigenic minerals (including zeolites, clay minerals, Mg-carbonates, and quartz) exhibit complex zonation with depth that crosses original ash depositional boundaries and stratigraphic limits. The zeolite minerals phillipsite and analcime are ubiquitous throughout the altered intervals. At Site 832, the first zeolite minerals (phillipsite) occur in Pleistocene deposits as shallow as 146 meters below seafloor (mbsf). At Site 833 the first zeolite minerals (analcime) occur in Pleistocene deposits as shallow as 224 mbsf. The assemblage phillipsite + analcime + chabazite appears at 635 mbsf (Site 832) and at 376 mbsf (Site 833). Phillipsite + analcime + chabazite + thomsonite + heulandite are observed between 443 and 732 mbsf at Site 833. Thomsonite is no longer observed below 732 mbsf at Site 833. Heulandite is present to the base of the sections cored. The zeolite assemblages are associated with authigenic clay minerals (nontronite and saponite), calcite, and quartz. Chlorite is noticeable at Site 832 as deep as 851 mbsf. Zeolite zones are present but are less well defined at Site 832. Dolomite and rare magnesite are present below 940 m at Site 832. The coarse-grained authigenic mineral host intervals exhibit geochemical signatures that can be attributed to low grade hydrothermal alteration. The altered intervals show evidence of K2O, CaO, and rare earth elements mobilization. When compared to fine-grained, unaltered units, and to Santa Maria Island volcanics rocks, the altered zones are relatively depleted in rare earth elements, with light rare earth elements-heavy rare earth elements fractionation. Drilling at Site 833 penetrated a sill complex below 840 m. No sill was encountered at Site 832. Complex zonation of zeolite facies, authigenic smectites, carbonates and quartz, and associated geochemical signatures are present at both sites. The mineralogical and chemical alteration overprint is most pronounced in the deeper sections at Site 832. Based on mineralogical and chemical evidence at two locations less than 50 km apart, there is vertical and lateral variation in alteration of the volcaniclastic sediments of North Aoba Basin. The alteration observed may be activated by sill intrusion and associated expulsion of heated fluids into intervals of greater porosity. Such spatial variation in alteration could be attributed to the evolution of the basin axis associated with subduction processes along the New Hebrides Trench.

Age determination and color reflectance of ODP Hole 165-1002D

Attempts to place Palaeolithic finds within a precise climatic framework are complicated by both uncertainty over the radiocarbon calibration beyond about 21,500 14C years bp (Reimer et al., 2004) and the absence of a master calendar chronology for climate events from reference archives such as Greenland ice cores or speleothems (Svensson et al., 2006, doi:10.1016/j.quascirev.2006.08.003). Here we present an alternative approach, in which 14C dates of interest are mapped directly onto the palaeoclimate record of the Cariaco Basin by means of its 14C series (Hughen et al., 2004, doi:10.1126/science.1090300), circumventing calendar age model and correlation uncertainties, and placing dated events in the millennial-scale climate context of the last glacial period. This is applied to different sets of dates from levels with Mousterian artefacts, presumably produced by late Neanderthals, from Gorham's Cave in Gibraltar: first, generally accepted estimates of about 32,000 14C years bp for the uppermost Mousterian levels (Pettitt and Bailey, 2000; Bronk Ramsey et al., 2002, doi:10.1111/1475-4754.00040); second, a possible extended Middle Palaeolithic occupation until about 28,000 14C years bp (Finlayson et al., 2006, doi:10.1038/nature05195); and third, more contentious evidence for persistence until about 24,000 14C years bp (Finlayson et al., 2006, doi:10.1038/nature05195). This study shows that the three sets translate to different scenarios on the role of climate in Neanderthal extinction. The first two correspond to intervals of general climatic instability between stadials and interstadials that characterized most of the Middle Pleniglacial and are not coeval with Heinrich Events. In contrast, if accepted, the youngest date indicates that late Neanderthals may have persisted up to the onset of a major environmental shift, which included an expansion in global ice volume and an increased latitudinal temperature gradient. More generally, our radiocarbon climatostratigraphic approach can be applied to any 'snapshot' date from discontinuous records in a variety of deposits and can become a powerful tool in evaluating the climatic signature of critical intervals in Late Pleistocene human evolution.

Foraminifer, coarse fraction and carbonate characteristics of sediments from ODP Leg 198 sites on Shatsky Rise

Holes 1209A and 1211A on Southern High, Shatsky Rise contain expanded, nearly continuous records of carbonate-rich sediment deposited in deep water of the equatorial Pacific Ocean during the Paleocene and Eocene. In this study, we document intervals of carbonate dissolution in these records by examining temporal changes in four parameters: carbonate content, coarse size fraction (>38 µm), benthic foraminiferal abundance, and planktonic foraminiferal fragmentation ratio. Carbonate content is not a sensitive indicator of carbonate dissolution in the studied sections, although rare intervals of low carbonate may reflect times of relatively high dissolution. The proportion of coarse size fraction does not accurately record carbonate dissolution either because the relative abundance of nannofossils largely determines the grain-size distribution. Benthic abundance and fragmentation covary (r**2 = 0.77) and are probably the best indicators for carbonate dissolution. For both holes, records of these parameters indicate two episodes of prominent dissolution. The first of these occurs in the upper Paleocene (~59-58 Ma) and the second in the middle to upper Eocene (~45-33.7 Ma). Other intervals of enhanced carbonate dissolution are located in the upper Paleocene (~56 Ma) and in the upper lower Eocene (~51 Ma). Enhanced preservation of planktonic foraminiferal assemblages marks the start of both the Paleocene and Eocene epochs.

Late Triassic palynology of the Wombat Plateau, northwestern Australia

Cores from Leg 122, Sites 759, 760, 761, and 764, were sampled at intervals of one sample per 1.5-m section in the Upper Triassic sequences. Spores, pollen, acritarchs, freshwater algae, and dinoflagellate cysts were studied to establish a palynostratigraphic framework for the Late Triassic. The palynological sequence is interpreted in terms of Australian spore-pollen zones: the Carman Samaropollenites speciosus Zone, the Norian Minutosaccus crenulatus Zone, and the Rhaetian Ashmoripollis reducta Zone. The Samaropollenites speciosus Zone-Minutosaccus crenulatus Zone boundary is marked by the change of pollen abundance and has a gradual character. Therefore, a transitional uppermost Carnian to Norian Samaropollenites speciosus/Minutosaccus crenulatus Zone is used. Age-determining dinoflagellate cysts are present in the Norian and Rhaetian sediments.

Age model and Plio-Pleistocene benthic stable oxygen isotope ratios of ODP Site 184-1143 in the Sourh China Sea

Based on benthic foraminiferal delta18O from ODP Site 1143, a 5-Myr astronomical timescale for the West Pacific Plio-Pleistocene was established using an automatic orbital tuning method. The tuned Brunhes/Matuyama paleomagnetic polarity reversal age agrees well with the previously published age of 0.78 Ma. The tuned ages for several planktonic foraminifer bio-events also agree well with published dates, and new ages for some other bio-events in the South China Sea were also estimated. The benthic delta18O from Site 1143 is highly coherent with the Earth's orbit (ETP) both at the obliquity and precession bands for the last 5 Myr, and at the eccentricity band for the last 2 Myr. In general, the 41-kyr cycle was dominant through the Plio-Pleistocene although the 23-kyr cycle was also very strong. The 100-kyr cycle became dominant only during the last 1 Myr. A comparison of the benthic delta18O between the Atlantic (ODP 659) and the East and West Pacific (846 and 1143) reveals that the Atlantic-Pacific benthic oxygen isotope difference ratio (Delta delta18OAtl-Pac) displays an increasing trend in three time intervals: 3.6-2.7 Ma, 2.7-2.1 Ma and 1.5-0.25 Ma. Each of the intervals begins with a rapid negative shift in Delta delta18OAtl-Pac, followed by a long period with an increasing trend, corresponding to the growth of the Northern Hemisphere ice sheet. This means that all three intervals of ice sheet growth in the Northern Hemisphere were accompanied at the beginning by a rapid relative warming of deep water in the Atlantic as compared to that of the Pacific, followed by its gradual relative cooling. This general trend, superimposed on the frequent fluctuations with glacial cycles, should yield insights into the processes leading to the boreal glaciation. Cross-spectral analyses of the Delta delta18OAtl-Pac with the Earth's orbit suggests that after the initiation of Northern Hemisphere glaciation at about 2.5 Ma, obliquity rather than precession had become the dominant force controlling the vertical structure or thermohaline circulation in the paleo-ocean.

Clay mineralogy of ODP Site 188-1165

The Ocean Drilling Program Leg 188 Site 1165 was drilled on the Wild Drift on the Continental Rise off Prydz Bay, East Antarctica to a total depth of 999.1 meters below seafloor (mbsf). It recovered an extensive suite of terrigenous and hemipelagic sediments of early Miocene to Pleistocene age. Of special interest in this study is the sediment column between 0 and 50 mbsf, which consists of a well-preserved section of Pliocene-Pleistocene-age sediments that was sampled at 10-cm intervals. Multiproxy study of this interval could show possible intervals of expansions of the ice-sheet across the continental shelves and express the climatic evolution in Antarctica, particularly during the 'middle' Pliocene warm period (3.15 to 2.85 Ma) which may provide an indication of how the Earth responds to a rise of its surface temperature. According to the existing age model, the upper 50 mbsf stratigraphic sequence of Site 1165 reaches back to ~4.9 Ma. Throughout this interval, the clay-mineral content is characterized by fluctuations of individual clay minerals, particularly smectite and chlorite. The smectite concentration varies mainly between 0% and 30%. Illite fluctuates less between 50% and 80%, and kaolinite varies mainly between 10% and 20%. Chlorite concentrations are mainly 0% to 10%. There is also a noticeable change in magnetic susceptibility at ~34 mbsf that is clearly indicated in the composition of the clay-mineral suite. At this level, smectite decreases and illite, kaolinite and chlorite show some variability. In particular, there is a slight but persistent increase in chlorite. The results from the Plio-Pleistocene transition, with evenly fluctuating smectite and illite contents and the gradually increasing chlorite content, may indicate cooler conditions compared to the mid-Pliocene conditions. Slight increase in illite content and decrease in smectite content towards Pleistocene supports the previous assumption. The results from the mid-Pliocene with the increasing smectite content and decreasing illite content may indicate warmer and possibly interglacial conditions.

Chronology and annual proxy data of Lago Grande di Monticchio sediments

We present new annual sedimentological proxies and sub-annual element scanner data from the Lago Grande di Monticchio (MON) sediment record for the sequence 76-112 thousand years before present (ka). They are combined with the previously published decadal to centennial resolved pollen assemblage in order to provide a comprehensive reconstruction of six major abrupt stadial spells (MON 1-6) in the central Mediterranean during early phase of the last glaciation. These climatic oscillations are defined by intervals of thicker varves and high Ti-counts and coincide with episodes of forest depletion interpreted as Mediterranean stadial conditions (cold winter/dry summer). Our chronology, labelled as MON-2014, has been updated for the study interval by tephrochronology and repeated and more precise varve counts and is independent from ice-core and speleothem chronologies. The high-resolution Monticchio data then have been compared in detail with the Greenland ice-core d18O record (NorthGRIP) and the northern Alps speleothem d18Ocalcite data (NALPS). Based on visual inspection of major changes in the proxy data, MON 2-6 are suggested to correlate with Greenland stadials (GS) 25-20. MON 1 (Woillard event), the first and shortest cooling spell in the Mediterranean after a long phase of stable interglacial conditions, has no counterpart in the Greenland ice core, but coincides with the lowest isotope values at the end of the gradual decrease in d18Oice in NorthGRIP during the second half of the Greenland interstadial (GI) 25. MON 3 is the least pronounced cold spell and shows gradual transitions, whereas its NorthGRIP counterpart GS 24 is characterized by sharp changes in the isotope records. MON 2 and MON 4 are the longest most and pronounced oscillations in the MON sediments in good agreement with their counterparts identified in the ice and spelethem records. The length of MON 4 (correlating with GS 22) supports the duration of stadial proposed by the NALPS timescales and suggests ca 500 yr longer duration than calculated by the ice-core chronologies GICC05modelext and AICC2012. Absolute dating of the cold spells provided by the MON-2014 chronology shows good agreement among the MON-2014, the GICC05modelext and the NALPS timescales for the period between 112 and 100 ka. In contrast, the MON-2014 varve chronology dates the oscillations MON 4 to MON 6 (92-76 ka) ca. 3,500 years older than the most likely corresponding stadials GS 22 to GS 20 by the other chronologies.

Grain size distribution of Oligocene and Miocene sediments from the Indus Fan

The Owen Ridge south of Oman represents oceanic crust that was uplifted by compressional tectonic forces in the early Miocene. Build-out of the Indus Fan led to deposition of a thick sequence of turbidites over the site of the Ridge during the late Oligocene and early Miocene. Early Miocene uplift of the Ridge led to a pelagic cap of nannofossil chalks. Two short sequences of turbidites from the pre- and syn-uplift phases were chosen for detailed grain size analysis. The upper Oligocene section at Site 731 is composed of thin (centimeter-decimeter scale) graded mud turbidites separated by relatively thick (decimeter-meter scale) intervals of homogeneous, non-bioturbated clayey siltstones. These finer intervals are unusually silt-rich (about 60%) for ungraded material and were probably deposited as undifferentiated muds from a series of turbidity current tails. By contrast, the lower Miocene section at Site 722 is comprised of a sequence of interbedded turbidites and hemipelagic carbonates. Sharp-based silt turbidites are overlain by burrow-mottled marly nannofossil chalks. The Oligocene sequence may have accumulated in an overbank setting on the middle fan - the local topographic position favoring frequent deposition from turbidity current tails and occasional deposition from the body of a turbidity flow. Uplift of the Ridge in the early Miocene led to pelagic carbonate deposition interrupted only by turbidity currents capable of overcoming a topographic barrier. Further uplift eventually led to entirely pelagic carbonate deposition.

Stable oxygen isotope record and benthic foraminiferal abundances in Cretaceous sediments of Demerara Rise

During the mid-Cretaceous period, the global subsurface oceans were relatively warm, but the origins of the high temperatures are debated. One hypothesis suggests that high sea levels and the continental configuration allowed high-salinity waters in low-latitude epicontinental shelf seas to sink and form deep-water masses (Brass et al., 1982, doi:10.1038/296620a0; Arthur and Natland, 1979; Chamberlin, 1906). In another scenario, surface waters in high-latitude regions, the modern area of deep-water formation, were warmed through greenhouse forcing (Bice and Marotzke, 2001, doi:10.1029/2000JC000561), which then propagated through deep-water circulation. Here, we use oxygen isotopes and Mg/Ca ratios from benthic foraminifera to reconstruct intermediate-water conditions in the tropical proto-Atlantic Ocean from 97 to 92 Myr ago. According to our reconstruction, intermediate-water temperatures ranged between 20 and 25 °C, the warmest ever documented for depths of 500-1,000 m. Our record also reveals intervals of high-salinity conditions, which we suggest reflect an influx of saline water derived from epicontinental seas around the tropical proto-North Atlantic Ocean. Although derived from only one site, our data indicate the existence of warm, saline intermediate waters in this silled basin. This combination of warm saline intermediate waters and restricted palaeogeography probably acted as preconditioning factors for the prolonged period of anoxia and black-shale formation in the equatorial proto-North Atlantic Ocean during the Cretaceous period.

Stable isotope record of Cibicidoides spp. from Late Miocene sediments of the Southern Ocean

Deepwater circulation plays an important role in climate modulation through its redistribution of heat and salt and its control of atmospheric CO2. Oppo and Fairbanks (1987, doi:10.1016/0012-821X(87)90183-X) showed that the Southern Ocean is an excellent monitor of deepwater circulation changes for two reasons: (1) the Southern Ocean is a mixing reservoir for incoming North Atlantic Deep Water and recirculated water from the Pacific and Indian oceans; and (2) the nutrient/delta13C tracers of deepwater are not significantly changed by surficial processes within the Southern Ocean. We can extend these principles to the late Miocene because tectonic changes in the Oligocene and early and middle Miocene developed near-modern basinal configurations. However, on these time scales, changes in the oceanic carbon reservoir and mean ocean nutrient levels also affect the delta13C differences between ocean basins. From 9.8 to 9.3 Ma, Southern Ocean delta13C values oscillated between high North Atlantic values and low Pacific values. The Southern Ocean recorded delta13C values similar to Pacific values from 9.2 to 8.9 Ma, reflecting a low contribution of Northern Component Water (NCW). The delta13C differences between the NCW and Pacific Outflow Water (POW) end-members were low from 8.9 to 8.0 Ma, making it difficult to discern circulation patterns. NCW production may have completely shutdown at 8.6 Ma, allowing Southern Component Water (SCW) to fill the North Atlantic and causing the delta13C values in the North Atlantic, Pacific, and Southern oceans to converge. Deepwater delta13C patterns resembling the modern distributions evolved by 7.0 Ma: delta13C values were near 1.0 per mil in the North Atlantic; 0.0 per mil in the Pacific; and 0.5 per mil in the Southern Ocean. Development of near-modern delta13C distributions by 7.0 Ma resulted not only from an increase in NCW flux but also from an increase in deepwater nutrient levels. Both of these processes increased the delta13C difference between the North Atlantic and Pacific oceans. Deepwater circulation patterns similar to today's operated as early as 9.8 Ma, but were masked by the lower nutrient/delta13C differences. During the late Miocene, 'interglacial' intervals prevailed during intervals of NCW production, while 'glacial' intervals occurred during low NCW production.

Silicoflagellate abundance in ODP Holes 183-1138A and 183-1140A

The biostratigraphic distribution and abundance of lower Oligocene and Miocene to Pleistocene silicoflagellates are documented from Ocean Drilling Program Leg 183 Holes 1138A and 1140A, on the Kerguelen Plateau. The Distephanus speculum speculum forma pseudofibula plexus is found in the upper Miocene in Hole 1138A, but other important biostratigraphic markers are not available. Diversity and abundance of silicoflagellates vary considerably in Hole 1138A, with silicoflagellates more abundant in the Pliocene and Pleistocene and some intervals of the Miocene barren of silicoflagellates or containing only limited numbers of specimens. The silicoflagellates of Hole 1140A include a new skeletal morphology, described here as Distephanus speculum speculum forma cylindrus. Silicoflagellates were generally abundant throughout the lower and middle Miocene in Hole 1140A.

Elemental and stable isotopic composition of some metalliferous and pelagic sediments at DSDP Leg 70 Holes

Nontronite, the main metalliferous phase of the Galapagos mounds, occurs at subsurface depths of about 2 to 20 meters; Mn-oxide material is limited to the upper 2 meters of the mounds. The nontronite forms intervals of up to a few meters' thickness, consisting essentially of 100% nontronite granules, which alternate with intervals of normal pelagic sediment. Electron microprobe analyses of nontronite granules from different core samples indicate that: (1) there is little difference in major element composition between nontronites from varying locations within the mounds, with adjacent granules from a given sample having very similar compositions; (2) individual granules show little internal variation in composition. This indicates that the granules are composed of a single mineral of essentially constant composition, consistent with relatively uniform conditions of Eh and composition during nontronite formation. Mn-oxide crusts have very low Fe contents, a feature characteristic of rapidly deposited Mn-oxide crusts formed under hydrothermal influences. The rare-earth element (REE) abundances of the nontronites are generally extremely low, totalling less than several ppm. Two samples have the negatively Ce anomaly typical of authigenic precipitates formed relatively rapidly from seawater. A Mn-oxide crust sample has low REE contents, typical of Mn-oxide crusts formed under hydrothermal influences, but no negative Ce anomaly. A sample of unusual Mn-Fe-oxide mud has relatively high REE concentrations and a seawater-type pattern; both of these features are also found for metalliferous sediments from the East Pacific Rise. The oxygen and hydrogen isotopic composition of the nontronites define a restricted field within a d18O-dD plot. In manganiferous sediments, d18O and dD appear to decrease with increase in the Mn-oxide content of the sediment. From the d18O values of the nontronites, formation temperatures in the range of about 20-30°C have been estimated. By comparison, temperatures of up to 11.5 °C at a 9-meter depth have been directly measured within the mounds (Corliss et al., 1979), and heat-flow data suggest present basement/sediment interface temperatures of 15-25°C. In a plot of Fe + Mn vs. d18O, the Mn-oxide crust and Mn-Fe-ooze plot near the tie-lines for authigenic Mn nodules and silicate phases, implying that they have formed in isotopic equilibrium with seawater at or close to bottom-water temperatures.