Settlement characteristics of quartz grains on certain sediment surface forms of tidal beaches along the Baltic and Wadden Sea

Sind in einem Sediment, das unter dem Einfluß einer Strömung abgelagert wurde, richtungsanzeigende Indikatoren vorhanden, so werden sie je nach den momentanen Bedingungen, die zur Zeit der Sedimentation herrschten, ein mehr oder weniger gutes Abbild der Strömungsverhältnisse liefern. Zahlreich sind Strömungsanzeiger organischen Ursprungs, wie z. B. Molluskenschalen u. a. Doch auch anorganische Partikel in Psephiten und Psammiten lassen häufig in ihrer Lagerung eine Abhängigkeit von der Strömungsrichtung erkennen: sie sind "geregelt". Die Autoren der verschiedenen Arbeiten, in denen Regelungen in klastischen Sedimenten untersucht wurden, gingen von der Tatsache aus, daß viele Sedimentpartikel statistisch gesehen keine Kugelform, sondern eine längliche Gestalt besitzen. Die langen Achsen dieser länglich geformten Sedimentkörner werden im folgenden als "Langachsen" bezeichnet. In Sanden sind es vor allem Quarzkörner von annähernd zylindrischer oder ellipsoidischer Form ("Langquarze"), die geeignet sind, durch die Lage ihrer Langachsen strömungsbedingte Regelungen anzuzeigen. Mit der Orientierung solcher Langquarze in marinen und fluviatilen Sanden haben sich bisher vorwiegend amerikanische Autoren befaßt. So untersuchten z. B. Dapples & Rominger (1945) die Sandsohle eines künstlichen Gerinnes. Sie stellten fest, daß die Hauptorientierungsrichtung der Langquarze mit der Strömungsrichtung des fließenden Wassers zusammenfiel. Dabei zeigte das spitze Ende tropfenförmiger ("polarer") Quarze stromab und das stumpfe Ende stromauf. Nanz (1955) maß die Langachsenrichtungen von Langquarzen in Sanden des nassen und trockenen Strandes von Texas und Florida und fand, daß sich diese Achsen vorwiegend parallel zur Auf- und Ablaufrichtung der Wellen und damit senkrecht zum Streichen der Strandlinie einregeln. Curray (1956 b) beobachtete die gleiche Regelung. Er wies ferner darauf hin, daß in Strandwällen und Strandhaken die bevorzugte Richtung der Langquarze senkrecht zum Streichen des Sedimentkörpers liegt. Zahlreiche weitere Autoren beschäftigten sich ebenfalls mit den Fragen der Langquarzregelung, so Schwarzacher (1951), Griffith & Rosenfeld (1953), Vollbrecht (1953), Rusnak (1956), Wendler (1956), Sriramadas (1957). Ganz allgemein war das Ergebnis aller dieser Untersuchungen, daß die aus einer Strömung abgelagerten Langquarze eine Regelung parallel zur Strömungsrichtung zeigen. Eigene Untersuchungen und Überlegungen ergaben, daß die bisher veröffentlichten Ergebnisse und die an sie angeschlossenen Vorstellungen z. T. bestätigt werden können, jedoch z. T. auch erheblich modifiziert werden müssen.

Contencentrations of reduced inorganic sulfur forms in Mediterranean Sea waters

The first data on content of inorganic reduced sulfur compounds [H2S, S°, S2O3(2-), SO3(2-)] were obtained at two stations in the northeastern Levant Sea (Mediterranean Basin). With lower detection limit for the mentioned sulfur forms of 30 nM, sulfide forms were not found, while thiosulfate concentration varied from 178 to 890 nM (from 24 to 78 % of total reduced S), and S° varied from 156 to 1090 nM. Vertical distribution of these compounds showed irregular character; correlation between total reduced S maxima, fluorescence, and increase of nutrient element content near the lower pycnocline boundary was observed. The maximum total sulfur concentration in the surface layer was likely due an anthropogenic influence. The ''starting'' mechanism that controls appearance and distribution of sulfur compounds in oxygen-containing water is the process of bacterial sulfate reduction in micropatches of fresh organic detritus. Reduced sulfur forms participate further in a series of chemical and biochemical processes. Contribution of hydrolysis of organic sulfur-containing compounds is insignificant for the region in study.

Seasonal production patterns of planktonic foraminifera in the NE Atlantic Ocean

Sediment trap samples from OMEX 2 (49°N, 13°W) provide a continuous record of the seasonal succession of planktonic foraminifera in the midlatitude North Atlantic and reveal a complex relationship between periods of production and specific hydrographic conditions. Neogloboquadrina pachyderma dextral coiling (d.), Globigerina bulloides, and Globorotalia inflata are found in great numbers during both the spring and summer seasons, whereas Globigerina quinqueloba, Globorotalia hirsuta, Globorotalia scitula, and Globigerinita glutinata are associated predominantly with the increase in productivity during the spring bloom. Globigerinella aequilateralis, Orbulina universa, and Globigerinoides sacculifer are restricted to late summer conditions following the establishment of a warm, well-stratified surface ocean. An annually integrated fauna from the sediment trap, comprising ~13,000 individuals, is used to evaluate the accuracy of five faunal-based statistical methods of paleotemperature estimation. All of the temperature reconstruction techniques produce estimates of ~16°C and ~11°C for summer and winter surface temperature, respectively, which are in excellent agreement with regional hydrographic data and suggest that the sediment trap assemblage is well represented in the core top faunas. Analysis of the key species that dominate the OMEX 2 sediment trap fauna, G. bulloides, G. inflata, and N. pachyderma d., based on d18O derived temperatures from North Atlantic core top samples, suggests that seasonal variations in planktonic foraminiferal production are nonuniform across the midlatitudes and that this is likely to complicate reconstructing past seasonal hydrographic dynamics using these taxa.

(Table 2) Production parameters of phytoplankton and some associated parameters in the area of the Titanic Polygon

Studies were carried out mostly in the area of RMS Titanic wreck site (41°44'N, 49°57'W) located above the continental slope and the south of the Grand Banks of Newfoundland. In a period from 18.06 to 24.09.2001 five surveys of production characteristics of surface phytoplankton were conducted over 5-9 days. Mean values of these characteristics obtained during the surveys were 9.2-11.7 mg C/m**3 per day for primary production (C_phs), 0.102-0.188 mg/m**3 for chlorophyll a (C_chls), and 4.44-7.42 mg C/mg chl. a per hour for assimilation number (AN). The main reason for low C_phs variability was a significant inverse relationship (R=-0.66) between AN and C_chls found over the research area. When cold shelf waters dominated in the area (27.07 to 19.08.2001), C_chls values for the slope region (0.125+/-0.031 µg/l) and for the outer shelf (0.130+/-0.040 µg/l) were similar. During strengthening of influence of warmer slope waters within area (from 29.08 to 13.09.2001), C_chls concentration within surface waters of the outer shelf was 0.152+/-0.039 µg/l and exceeded one for the slope region (0.094+/-0.004 µg/l) by factor 1.6. Against the background of low Cchls values, the High values of integral primary production in the water column (510-1010 mg C/m**2 per day) at low C_chls values measured within the area were determined both by high assimilation activity of phytoplankton and by the deep (30-40 m) maximum of primary production. Main reasons for formation of such a maximum were high chlorophyll concentration within the layer of the deep chlorophyll maximum (up to 0.5-2.5 µg/l) and in the relatively high solar irradiance within this layer varying from 1.4 to 8.6% of subsurface PAR.

Geochemistry of tetrapyrrole, tetraterpenoid, and perylene pigments in sediments from the Gulf of California

Results and discussion cover pigment analyses of 36 sediment samples recovered by Deep Sea Drilling Project Leg 64, and six samples from the Leg 64 site-survey cruise in the Guaymas Basin (Scripps Institution of Oceanography, Leg 3). Pigments investigated were tetrapyrroles, tetraterpenoids, and the PAH compound perylene. Traces of mixed nickel and copper ETIO-porphyrins were ubiquitous in all sediment samples, except for the very surface (i.e., <2 m sub-bottom), and their presence is taken as an indication of minor influxes of previously oxidized allochthonous (terrestrial) organic matter. Phorbides and chlorins isolated from Site 479 sediment samples (i.e., the oxygen-minimum locale, northeast of the Guaymas Basin) well represent the reductive diagenesis ("Treibs Scheme"; see Baker and Palmer, 1978; Treibs, 1936) of chlorophyll derivatives. Three forms of pheophytin-a, plus a variety of phorbides, were found to give rise to freebase porphyrins, nickel phylloerythrin, and nickel porphyrins, with increasing depth of burial (increasing temperature). Sediments from Sites 481, 10G, and 18G yielded chlorophyll derivatives characteristic of early oxidative alterations. Included among these pigments are allomerized pheophytin-a, purpurin-18, and chlorin-p6. The high thermal gradient imposed upon the late Quaternary sediments of Site 477 greatly accelerated chlorophyll diagenesis in the adjacent overlying sediments, that is, the production of large quantities of free-base desoxophylloerythroetioporphyrin (DPEP) occurred in a section (477-7-5) presently only 49.8 meters sub-bottom. Present depth and age of these sediments are such that only chlorins and phorbides would be expected. Carotenoid (i.e., tetraterpenoids) concentrations were found to decrease rapidly with increasing sub-bottom depth. Less deeply buried sediments (e.g., 0-30 m) yielded mixtures of carotenes and oxygen-substituted carotenoids. Oxygencontaining (oxy-, oxo-, epoxy-) carotenoids were found to be lost preferentially with increased depth of burial. Early carotenoid diagenesis is suggested as involving interacting reductions and dehydrations whereby dehydro-, didehydro-, and retro-carotenes are generated. Destruction of carotenoids as pigments may involve oxidative cleavage of the isoprenoid chain through epoxy intermediates, akin to changes in the senescent cells of plants. Perylene was found to be a common component of the extractable organic matter from all sediments investigated. The generation of alkyl perylenes was found to parallel increases in the existing thermal regime at all sites. Igneous sills and sill complexes within the sediment profile of Site 481 altered (i.e., scrambled) the otherwise straightforward thermally induced alkylation of perylene. The degree of perylene alkylation is proposed as an indicator of geothermal stress for non-contemporaneous marine sediments.

Diatoms and laminae of Mediterranean sapropels

The origins of sapropels (sedimentary layers rich in organic carbon) are unclear, yet they may be a key to understanding the influence of climate on ocean eutrophication, the mechanisms of sustaining biological production in stratified waters and the genesis of petroleum source rocks (Rohling, 1994, doi:10.1016/0025-3227(94)90202-X; Castradori, 1993, doi:10.1029/93PA00756; Calvert et al., 1992, doi:10.1038/359223a0). Recent microfossil studies of foraminifera (Rohling, 1994, doi:10.1016/0025-3227(94)90202-X) and calcareous nannofossils (Castradori, 1993, doi:10.1029/93PA00756) have focused attention on a deep chlorophyll maximum as a locus for the high production inferred (Calvert et al., 1992, doi:10.1038/359223a0) for sapropel formation, but have not identified the agent responsible. Here we report the results of a high-resolution, electron-microscope-based study of a late Quaternary laminated sapropel in which the annual flux cycle has been preserved. We find that much of the production was by diatoms, both mat-forming and other colonial forms, adapted to exploit a deep nutrient supply trapped below surface waters in a stratified water column. Reconstructed organic-carbon and opal fluxes to the sediments are comparable to those at high-productivity sites in today's oceans, and calculations based on diatom Si/C ratios suggest that the high organic-carbon content of sapropels may be entirely accounted for by sedimenting diatoms. We propose that this style of production may have been common in ancient Palaeogene and Cretaceous seas, environments for which conventional appeals to upwelling-driven production to account for the occurrence of diatomites, and some organic-carbon-rich sediments, have never seemed wholly appropriate.