Chemistry of zeolithe and clays from Central Kerguelen Plateau basalts

Ocean Drilling Program Leg 120 recovered basement samples that consisted of zeolite-facies metabasalts at Sites 747, 749, and 750 on the Kerguelen Plateau. These basalts were metamorphosed in the low to intermediate zones of the zeolite facies, as indicated by the presence of diagnostic zeolites and the absence of chlorite, epidote, prehnite, pumpellyite, and wairakite. Chabazite, natrolite, thompsonite, mesolite, stilbite, huelandite, and smectites occur as amygduloidal fillings in basalts from Holes 747C and 750B, whereas only stilbite, laumontite, and pure and mixed-layered smectites were identified in amygduloidal basalts from Hole 749C. In the lower sections of Hole 749C, only laumontite and mixed-layered smectites coexist. Based on calculations with published experimental phase equilibria, the absence of wairakite in basalts from Hole 749C and of laumontite in basalts from Holes 747C and 750B suggests that metamorphic temperatures did not exceed approximately 225° and 120°C, respectively. The presence of well-developed zeolite mineral assemblages and the absence of carbonate and clay mineral assemblages restricts XCO2 in the fluid to approximately <=0.0075. Low- to intermediate-zone zeolite-facies mineral assemblages in basalts from the Kerguelen Plateau can be accounted for by metamorphism in an active geothermal area such as present-day Iceland.

Geochemistry of lavas and dikes from the upper oceanic crust of Hess Deep Rift, eastern Pacific Ocean

Strontium isotopes are useful tracers of fluid-rock interaction in marine hydrothermal systems and provide a potential way to quantify the amount of seawater that passes through these systems. We have determined the whole-rock Sr-isotopic compositions of a section of upper oceanic crust that formed at the fast-spreading East Pacific Rise, now exposed at Hess Deep. This dataset provides the first detailed comparison for the much-studied Ocean Drilling Program (ODP) drill core from Site 504B. Whole-rock and mineral Sr concentrations indicate that Sr-exchange between hydrothermal fluids and the oceanic crust is complex, being dependent on the mineralogical reactions occurring; in particular, epidote formation takes up Sr from the fluid increasing the 87Sr/86Sr of the bulk-rock. Calculating the fluid-flux required to shift the Sr-isotopic composition of the Hess Deep sheeted-dike complex, using the approach of Bickle and Teagle (1992, doi:10.1016/0012-821X(92)90221-G) gives a fluid-flux similar to that determined for ODP Hole 504B. This suggests that the level of isotopic exchange observed in these two regions is probably typical for modern oceanic crust. Unfortunately, uncertainties in the modeling approach do not allow us to determine a fluid-flux that is directly comparable to fluxes calculated by other methods.

Heavy mineral content and grain sizes of sediment samples from foreshore to dune around Skagen, north Denmark

Aufbau und Ausdehnung der Schwermineral-Anreicherungen (Ilmenit, Granat, Amphibol) am Strand südlich Skagens wurden in langen Schürfgräben untersucht. Die Seifenlagen ziehen durchgehend vom Kliff-Fuß bis zur mittleren Meereshöhe hin und liegen meist diskordant auf der alten Strandschichtung. Ihre strandparallele Ausdehnung beträgt bis zu 100 m. Aufgebaut werden sie aus dünnen Schwermineral-Lamellen, die in kleinerem Umfang überall in den Strandablagerungen zu finden sind und hier das Gefüge nachzeichnen (Rippeln, Strandwallschichtung, Schichtstörungen). Die Seifenbildung geht in einem Gebiet mit verstärktem Küstenabtrag vor sich (Lee-Erosion südlich der Hafenmolen von Skagen). Dieses deutet darauf hin, daß die Schwerminerale bei Aufarbeitung bereits vorhandener Sedimente infolge ihres unterschiedlichen hydraulischen Verhaltens Zurückbleiben und schließlich angereichert werden. Die Korngrößenverteilung der Minerale in verschiedenen Sedimentproben zeigen, daß mit steigender Schwermineral-Anreicherung eine Kornverfeinerung und Zunahme der spezifisch schwersten Minerale (opake Erzminerale und Zirkon) auftritt. In ähnlicher Weise werden die Sortierungswerte besser. Die Aufbereitung des Sedimentes wird, in Anlehnung an v. ENGELHARDT (1939), mit einem doppelten Sortierungsvorgang durch die Wasserbewegung am Strand erklärt. Beim Absinken des Sandes nach dem Brecherschwall tritt eine Vorsortierung ein, die den Abtransport der leichteren und größeren Minerale im Sog begünstigt. Verbindungen zu Vorstellungen der Aufbereitungstechnik (Rundherdverfahren) und Hydrodynamik ('laminare Unterschicht') werden hergestellt. Die Dünensande Skagens sind infolge ihres hohen Schwermineralgehaltes und günstiger Äquivalentgrößen der einzelnen Minerale besonders bedeutsam für die Seifenbildung am Strand.

Mineralogy and inorganic geochemistry of sediments at DSDP Leg 65 Holes

During Leg 65, 15 holes were drilled at four sites located on young crust in the mouth of the Gulf of California. Quaternary to upper Pliocene hemipelagic sediments above and interlayered within the young basaltic basement were cored. The influence of hot lava, high temperature gradients, and hydrothermal activity on the mineralogy and geochemistry of the terrigenous sediments near contacts with basalts might therefore be expected. The purpose of the present study was to determine the mineralogy and inorganic geochemistry of these sediments and to analyze the nature and extent of low temperature alteration. To this end we studied the mineralogy and inorganic geochemistry of 75 sediment samples, including those immediately overlying uppermost basalts and those from layers alternating with basalts within the basement. We separated three size fractions - <2 µm (clay), 2-20 µm (intermediate), and >20 µm (coarse) - and applied the following mineralogical determinations: x-ray diffraction (XRD), infrared spectroscopy, transmission and scanning electron microscopy, and optical microscopy (for coarse fractions, using thin sections and smear slides). We calculated the percentages of clay minerals using Biscaye's (1964) method, and used routine wet chemical analyses to determine bulk composition and quantitative spectral analyses for trace elements.

Mineral and chemical compositions of sedimentary and volcano-sedimentary rocks drilled in DSDP Legs 43 and 44

Sedimentary cover on the bottom of the Northwest Atlantic Ocean is underlain by Late Jurassic - Cretaceous tholeiite-basalt formation. It consists of come sedimentary formations with different lithologic features and age. Their composition, stratigraphic position and, distribution are described on materials of deep-sea drilling. Mineralogical and geochemical studies of DSDP Leg 43 and Leg 44 holes lead to new ideas about composition and genesis of some sediment types of and their associations. High metal contents in the chalk formation of black clays on the Bermuda Rise probably result from exhalations. Connection of red-colored and speckled deposits with hiatuses in sedimentation is shown. Main stages of geological history of the North American Basin are reflected in accumulation of the followed formations: ancient carbonate formation (Late Jurassic - Early Cretaceous), formation of black clays rich in organic matter (Cretaceous), formation of speckled clays (Late Cretaceous), siliceous-clayey turbidite formation (Eocene), hemipelagic and pelagic clayey formation (Neogene), and terrigenous turbidite formation (Pleistocene).

Petrography and mineral compositions of gabbros at DSDP Leg 60 Holes

The compositions, mineralogies, and textures of gabbros recovered in polymict breccias in Hole 453 indicate that they are the cumulus assemblages of calc-alkalic crystal fractional on that occurred beneath the West Mariana Ridge. They are among a class of gabbros known only from other calc-alkalic associations (e.g., the Lesser Antilles and the Peninsular Ranges batholith of Southern California) and differ from gabbros of stratiform complexes, ophiolites, and the ocean crust. Particularly abundant in the Hole 453 breccias are olivine-bearing gabbros with extremely calcic Plagioclase (An94-97) but with fairly iron-rich olivines (Fo76-77). Other gabbros contain biotite and amphibole and occur in breccias with fairly high-grade greenschist facies (amphibole-chlorite-stilpnomelane) metabasalts. One unusual gabbro has experienced almost complete subsolidus recrystallization to an assemblage of aluminous magnesio-hornblende, anorthite, and green hercynitic spinel. This reaction, the extremely calcic Plagioclase, the occurrence of biotite and amphibole, and the association with greenschist facies metamorphic rocks suggest that crystallization of the gabbros occurred at elevated P(H2O). Comparisons with other calc-alkalic gabbro suites suggest pressures in excess of 4 kbar (about 12 km depth). The gabbros were exposed by the early stages of opening of the Mariana Trough and imply that considerable uplift may have attended rifting. They were also subjected to hydrothermal alteration after breccia formation, resulting in formation of chlorite, epidote, actinolite, and prehnite. Temperatures of at least 200°C - and probably 350°C - were reached, and most likely could not have been attained without extrusion or intrusion of magmas nearby, even though no such rocks were cored.

Geochemistry of metamorphic rocks from the Mariana and Izu-Ogasawara forearcs

During Leg 125, two serpentinite seamounts were drilled in the Mariana and Izu-Ogasawara forearcs. Together with abundant serpentinized peridotites, low-grade metamorphic rocks were recovered from both seamounts. The metamorphic rocks obtained from Hole 778A on Conical Seamount on the Mariana forearc contain common blueschist facies minerals, lawsonite, aragonite, blue amphibole, and sodic pyroxene. Approximate metamorphic conditions of these rocks are 150° to 250° C and 5 to 6 kb. These rocks are considered to have been uplifted by diapirism of serpentinite from a deeper portion within the subduction zone. This discovery presents direct evidence that blueschist facies metamorphism actually takes place within a subduction zone and provides new insight about trench-forearc tectonics. The diagnostic mineral assemblage of the metamorphic rocks from Holes 783A and 784A on Torishima Forearc Seamount, in the Izu-Ogasawara region, is actinolite + prehnite + epidote, with a subassemblage of chlorite + quartz + albite + H2O, which is typical of low-pressure type, prehnite-actinolite facies of Liou et al. (1985). This metamorphism may represent ocean-floor metamorphism within trapped oceanic crust or in-situ metamorphism that occurred at depths beneath the island-arc.

Geochemistry on rocks from Shackleton Range

During the GEISHA expedition (Geologische Expedition in die Shackleton Range 1987/88), the Pioneers Escarpment was visited and sampled extensively for the first time. Most of the rock types encountered represent amphibolite facies metamorphics, but evidence for granulite facies conditions was found in cores of garnet. These conditions must have been at least partly reached during the peak of metamorphism. For the Pioneers Escarpment a varicolored succession of sedimentary and bimodal volcanic origin is typical. It comprises: quartzites muscovite quartzite, sericite quartzite, fuchsite quartzite, garnet-quartz schists etc.; pelites: mica schists and plagioclase or plagioclase-microcline gneisses, aluminous schists; marls and carbonates: grey meta-limestones, carbonaceous quartzites, but also pure white, often fine-grained, saccharoidal marble, or a variety of tremolite marble, olivine (forsterite) marble, diopside-clinopyroxene-tremolite marble, etc.; basic volcanic rocks: amphibole fels, amphibolite schist, garnet amphibolite, and acidic to intermediate volcanic rocks: garnet-biotite schist, epidote-biotite-plagioclase gneiss, microcline gneiss. These rocks are considered to be a supracrustal unit, called the Pioneers Group. In the easternmost parts of the Pioneers Escarpment, e.g. at Vindberget, nonmetamorphic shales, sandstones and greywackes crop out, which are cover rocks of possibly Jurassic age. These metasediments, which represent a quartz-pelite-carbonate (QPC) association, indicate that deposition took place on a stable shelf, i.e. on the submerged rim of a craton. Marine shallow-water sedimentation including marls and aluminous clays form the protoliths. The volcanics may be part of a bimodal volcanics-arkose-conglomerate (BVAC) association. Geochemical analyses support the assumption of volcanic protoliths. This is demonstrated especially by the elevated amounts of the immobile, incompatible high-field-strength elements (HFSE) Nb, Ta, Ti, Y, and Zr encountered in some of the gneisses. Microscopic investigation suggests the existence of ortho-amphibolites. This is confirmed by the geochemistry. A bimodal volcanic association is evident. The amphibolites plot in both the tholeiite and calc-alkaline fields. The acidic volcanics are mainly rhyolitic. The sediments and volcanics were subjected to conditions of 10-11 kbar and 600°C during the peak of metamorphism, i.e. granulite facies metamorphism, which can be deduced from the Fe mole ratios of 0.71-0.73 in the garnet cores. Due to the relatively low temperatures, no anatectic melting took placc. The rims of the garnets show a Fe mole ratio of 0.84-0.86, and the coexisting mineral association garnet-biotite-staurolite-kyanite indicate amphibolite facies. The thermobarometry shows P-T conditions of 5-6 kbar and 570-580°C for this stage. The metamorphic history indicates deep burial at depths down to 35 km (subduction?) i.e. high pressure metamorphism, followed by pressure release due to uplift associated with retrograde metamorphism. This may have happened during a pre-Ross metamorphic event or orogeny. The Ross Orogeny at about 500 Ma probably just led to the weak greenschist facies overprint that is evident in the rocks of the Pioneers Group. Finally, sedimentation resumed in the area of the present Shackleton Range, or at least in the eastern part of the Pioneers Escarpment, probably when detritus from erosion of the basement (Read Group and Pioneers Group) was deposited, forming sandstones and greywackes of possibly Jurassic age. There is no indication that these sediments belong to the former Turnpike Bluff Group.

Mineral quantification of a Jordan Cretaceous outcrop (Section GM3, Ghawr Al Mazar, Ghor al Mazrar)

Cyclic fluctuations in global sea level during epochs of warm greenhouse climate have remained enigmatic, because absence or subordinate presence of polar ice during these periods precludes an explanation by glacio-eustatic forcing. An alternative concept suggests that the water-bearing potential of groundwater aquifers is equal to that of ice caps and that changes in the dynamic balance of aquifer charge versus discharge, as a function of the temperature-related intensity of the hydrological cycle, may have driven eustasy during warm climates. However, this idea has long been neglected for two reasons: 1) the large storage potential of subsurface aquifers was confused with the much smaller capacity of rivers and lakes and 2) empirical data were missing that document past variations in the hydrological cycle in relation to eustasy. In the present study we present the first empirical evidence for changes in precipitation, continental weathering intensity and evaporation that correlate with astronomically (long obliquity) forced sea-level cycles during the warmest period of the Cretaceous (Cenomanian-Turonian). We compare sequence-stratigraphic data with changes in the terrigenous mineral assemblage in a low-latitude marine sedimentary sequence from the equatorial humid belt at the South-Tethyan margin (Levant carbonate platform, Jordan), thereby avoiding uncertainties from land-ocean correlations. Our data indicate covariance between cycles in weathering and sea level: predominantly chemical weathering under wet climate conditions is reflected by dominance of weathering products (clays) in deposits that represent sea-level fall (aquifer charge > discharge). Conversely, preservation of weathering-sensitive minerals (feldspars, epidote and pyroxenes) in transgressive sediments reflects decreased continental weathering due to dryer climate (aquifer discharge > charge). Based on our results we suggest that aquifer-eustasy represents a viable alternative to glacio-eustasy as a driver of cyclic 3rd-order sea-level fluctuations during the middle Cretaceous greenhouse climate, and it may have been a pervasive process throughout Earth history.

Results of biological and geological bottom investigations carried out during Cruise 43 of R/V Akademik Kurchatov in the South Atlantic

The book is devoted to investigations of benthic fauna and geology of the Southern Atlantic Ocean. These works have been carried out in terms of exploring biological structure of the ocean and are of great importance for development of this fundamental problem. They are based on material collected during Cruise 43 of R/V Akademik Kurchatov in 1985-1986 and Cruise 43 of R/V Dmitry Mendeleev in 1989. Problems of quantitative distribution, group composition and trophic structure of benthos in the Southern Scotia Sea, along the east-west Transatlantic section along 31°30'S, and offshore Namibia in the area of the Benguela upwelling are under consideration in the book. Authors present new data on fauna of several groups of deep-sea bottom animals and their zoogeography. Much attention is paid to analysis of morphological structure of the Scotia Sea floor considered in terms of plate tectonics. Bottom sediments along the Transatlantic section and facial variation of sediments in the area of South Shetland Islands and of the continental margin of Namibia are under consideration.

Chemical and mineral composition of rocks and sediments from the Amirante Arc

New geological and geophysical data on the Amirante Arc, which locates to the south of the Seychelles Islands, are presented. These data were obtained by Pacific Oceanological Institute during the 33-rd cruise of R/V Professor Bogorov in 1990. The Amirante Arc represents a seamount chain, which has submeridional strike and total length about 400 km. To the west of the Amirante Arc there are a deep sea trench and a back-arc basin, i.e. this area is characterized by structural elements associated with the subduction zone of Western Pacific type. According to our data the Amirante Arc is composed by tholeiites of ocean plateau type. This facts are evidences that the Amirante Arc differs from typical Pacific island arcs. This gives an opportunity to distinguish a special type of oceanic structures, i.e. non-volcanic (amagmatic) ridges. The Amirante Ridge has been probably formed as a result of oceanic crust heaping due to horizontal displacements of its blocks in the process of spreding ridge formation in the Indian Ocean during Cretaceous-Paleogene.

Geochemistry of the sheeted dike complex at Pito Deep

Alteration of sheeted dikes exposed along submarine escarpments at the Pito Deep Rift (NE edge of the Easter microplate) provides constraints on the crustal component of axial hydrothermal systems at fast spreading mid-ocean ridges. Samples from vertical transects through the upper crust constrain the temporal and spatial scales of hydrothermal fluid flow and fluid-rock reaction. The dikes are relatively fresh (average extent of alteration is 27%), with the extent of alteration ranging from 0 to >80%. Alteration is heterogeneous on scales of tens to hundreds of meters and displays few systematic spatial trends. Background alteration is amphibole-dominated, with chlorite-rich dikes sporadically distributed throughout the dike complex, indicating that peak temperatures ranged from <300°C to >450°C and did not vary systematically with depth. Dikes locally show substantial metal mobility, with Zn and Cu depletion and Mn enrichment. Amphibole and chlorite fill fractures throughout the dike complex, whereas quartz-filled fractures and faults are only locally present. Regional variability in alteration characteristics is found on a scale of <1-2 km, illustrating the diversity of fluid-rock interaction that can be expected in fast spreading crust. We propose that much of the alteration in sheeted dike complexes develops within broad, hot upwelling zones, as the inferred conditions of alteration cannot be achieved in downwelling zones, particularly in the shallow dikes. Migration of circulating cells along rides axes and local evolution of fluid compositions produce sections of the upper crust with a distinctive character of alteration, on a scale of <1-2 km and <5-20 ka.

Heavy and light minerals in turbidites from DSDP Hole 19-183, the Aleutian abyssal plain

The Aleutian abyssal plain is a fossil abyssal plain of Paleogene age in the western Gulf of Alaska. The plain is a large, southward-thinning turbidite apron now cut off from sediment sources by the Aleutian Trench. Turbidite sedimentation ceased about 30 m.y. ago, and the apron is now buried under a thick blanket of pelagic deposits. Turbidites of the plain were recovered at site 183 of the Deep Sea Drilling Project on the northern edge of the apron. The heavy-mineral fraction of sand-sized samples is mostly amphibole and epidote with minor pyroxene, garnet, and sphene. The light-mineral fraction is mostly quartzose debris and feldspars. Subordinate lithic fragments consist of roughly equal amounts of metamorphic, plutonic, sedimentary, and volcanic grains. The sand compositions are arkoses in many sandstone classifications, although if fine silt is included with clay as matrix, the sand deposits are feldspathic or lithofeldspathic graywacke. The sands are apparently first-cycle products of deep dissection into a plutonic terrane, and they contrast sharply with arc-derived volcanic sandstones of similar age common on the adjacent North American continental margin. The turbidite sands are stratigraphically remarkably constant in composition, which indicates derivation from virtually the same terrane through a time span approaching 20 m.y. Comparison of Aleutian plain data with the compositions of coeval sedimentary rocks from the northeast Pacific margin shows that the Kodiak shelf area includes possible proximal equivalents of the more distal turbidites. Derivation from the volcaniclastic Mesozoic flysch of the Shumagin-Kodiak shelf is unlikely; more probably the sediments were derived from primary plutonic sources. The turbidites also resemble deposits in the Chugach Mountains and the younger turbidites of the Alaskan abyssal plain and could conceivably have been derived from the coast ranges of southeastern Alaska or western British Columbia. The Aleutian plain sediment most likely was not derived from as far south as the Oregon-Washington continental margin, where coeval sedimentary deposits are dominantly volcaniclastic.