Carbon and carbonate concentrations of recent and Pleistocene sediments of the Norwegian-Greenland Sea

Surface sediment samples from the Norwegian-Greenland Sea were investigated to reconstruct the spatial distribution of recent carbonate dissolution on the seafloor. Additionally, carbonate dissolution records of Ocean Drilling Program sites 985 and 987 are presented to outline the development of Pleistocene carbonate preservation. Today, well-preserved carbonate tests can be observed along the inflow of warm Atlantic surface water, extending as far as into the northernmost Norwegian-Greenland Sea. Increased dissolution is indicated along the continental margins and in the deepest parts of the Greenland Basin. Factors favoring carbonate preservation were found to be supersaturation of the water column with respect to calcium carbonate, high carbonate rain and probably excess alkalinity of bottom waters supplied by the arctic river discharge. Supralysoklinal dissolution is most important for recent carbonate dissolution in the Norwegian-Greenland Sea, whereas the deepest parts of the Greenland Basin reaches the calcite saturation horizon. Pleistocene dissolution records show some prominent peaks of extreme carbonate dissolution. During the Brunhes chron, carbonate dissolution maxima can be related to meltwater pulses, which probably inhibited deep-water formation in the Norwegian-Greenland Sea during deglaciation events. Long-term severe carbonate dissolution is evident during the late Matuyama chron. This can be probably related to low carbonate rain, due to a more eastwards located East Greenland Current and the nearly absence of the not yet polar adapted Neogloboquadrina pachyderma sin. during that period. Extreme dissolution events during the late Matuyama indicate strongly reduced deep-water formation.

Profile of sediment echo sounding with links to ParaSound data files and swath sonar multibeam bathymetry during METEOR cruise M70/2b

Two highly active mud volcanoes located in 990-1,265 m water depths were mapped on the northern Egyptian continental slope during the BIONIL expedition of R/V Meteor in October 2006. High-resolution swath bathymetry and backscatter imagery were acquired with an autonomous underwater vehicle (AUV)-mounted multibeam echosounder, operating at a frequency of 200 kHz. Data allowed for the construction of ~1 m pixel bathymetry and backscatter maps. The newly produced maps provide details of the seabed morphology and texture, and insights into the formation of the two mud volcanoes. They also contain key indicators on the distribution of seepage and its tectonic control. The acquisition of high-resolution seafloor bathymetry and acoustic imagery maps with an AUV-mounted multibeam echosounder fills the gap in spatial scale between conventional multibeam data collected from a surface vessel and in situ video observations made from a manned submersible or a remotely operating vehicle.

Ocean bottom seismometer sgy-files of refraction seismic profiles from Professor Logachev cruise TTR16/3

Over the last decade pockmarks have proven to be important seabed features that provide information about fluid flow on continental margins. Their formation and dynamics are still poorly constrained due to the lack of proper three dimensional imaging of their internal structure. Numerous fluid escape features provide evidence for an active fluid-flow system on the Norwegian margin, specifically in the Nyegga region. In June-July 2006 a high-resolution seismic experiment using Ocean Bottom Seismometers (OBS) was carried out to investigate the detailed 3D structure of a pockmark named G11 in the region. An array of 14 OBS was deployed across the pockmark with 1 m location accuracy. Shots fired from surface towed mini GI guns were also recorded on a near surface hydrophone streamer. Several reflectors of high amplitude and reverse polarity are observed on the profiles indicating the presence of gas. Gas hydrates were recovered with gravity cores from less than a meter below the seafloor during the cruise. Indications of gas at shallow depths in the hydrate stability field show that methane is able to escape through the water-saturated sediments in the chimney without being entirely converted into gas hydrate. An initial 2D raytraced forward model of some of the P wave data along a line running NE-SW across the G11 pockmark shows, a gradual increase in velocity between the seafloor and a gas charged zone lying at ~300 m depth below the seabed. The traveltime fit is improved if the pockmark is underlain by velocities higher than in the surrounding layer corresponding to a pipe which ascends from the gas zone, to where it terminates in the pockmark as seen in the reflection profiles. This could be due to the presence of hydrates or carbonates within the sediments.

Active methane seepage in the Southern Ocean, off the sub-Antarctic island of South Georgia

An extensive submarine cold-seep area was discovered on the northern shelf of South Georgia during R/V Polarstern cruise ANT-XXIX/4 in spring 2013. Hydroacoustic surveys documented the presence of 133 gas bubble emissions, which were restricted to glacially-formed fjords and troughs. Video-based sea floor observations confirmed the sea floor origin of the gas emissions and spatially related microbial mats. Effective methane transport from these emissions into the hydrosphere was proven by relative enrichments of dissolved methane in near-bottom waters. Stable carbon isotopic signatures pointed to a predominant microbial methane formation, presumably based on high organic matter sedimentation in this region. Although known from many continental margins in the world's oceans, this is the first report of an active area of methane seepage in the Southern Ocean. Our finding of substantial methane emission related to a trough and fjord system, a topographical setting that exists commonly in glacially-affected areas, opens up the possibility that methane seepage is a more widespread phenomenon in polar and sub-polar regions than previously thought.

Sr, Nd, and Pb isotope geochemistry of ODP Hole 104-642E

ODP Leg 104 recovered 914 m of volcanics at Site 642 on the Vøring Plateau in the Norwegian Sea. The upper series of these volcanics correlates with seaward-dipping seismic reflectors (DRS), and is tholeiitic in character. The lower series underlies the DRS and is broadly andesitic in character. Rb-Sr, Sm-Nd, and Pb isotopic analyses show that upper series samples have isotopic features characteristic of MORB, except for one dike sample that has a Pb isotopic composition that may indicate interaction of its parent magma with older continental crust. The five most silicic samples from the lower series, which occur high up in the sequence, define a 63 ± 19 Ma Rb-Sr whole-rock isochron age, and have an initial 87Sr/86Sr of 0.7116 ± 0.0004. Other lower series samples have lower initial 87Sr/86Sr, but all are greater than any upper series rock. The combined evidence of initial 87Sr/86Sr, initial epsilon-Nd values, Sm-Nd model ages, Pb isotopic compositions, and petrographic features clearly indicate that lower series rocks were derived, at least in part, from continental crustal source materials. That the DRS is underlain by rocks of continental character is an important observation, constraining models for the development of DRS-type passive continental margins.

Age determination and geochemical composition of sediment core DA04-31P

There is limited knowledge pertaining to the history of the Greenland Ice Sheet (GIS) during the last glacial-interglacial transition as it retreated from the continental margins to an inland position. Here we use multiproxy data, including ice-rafted debris (IRD); planktonic isotopes; alkenone temperatures; and tephra geochemistry from the northern Labrador Sea, off southwest Greenland, to investigate the deglacial response of the GIS and evaluate its implications for the North Atlantic deglacial development. The results imply that the southern GIS retreated in three successive stages: (1) early deglaciation of the East Greenland margins, by tephra-rich IRD that embrace Heinrich Event 1; (2) progressive retreat during Allerød culminating in major meltwater releases (d18O depletion of 1.2 per mil) at the Allerød-Younger Dryas transition (12.8-13.0 kyr B.P.); and (3) a final stage of glacial recession during the early Holocene (~9-11 kyr B.P.). Rather than indicating local temperatures of ambient surface water, the alkenones likely were transported to the core site by the Irminger Current. We attribute the timing of GIS retreat to the incursion of warm intermediate waters along the base of grounded glaciers and below floating ice shelves on the continental margin. The results lend support to the view that GIS meltwater presented a forcing factor for the Younger Dryas cooling.

Composition of marine phosphorites and phosphate-bearing sediments

The book deals with behavior of phosphorus and its concentration in oceanic phosphorites. The major stages of marine geochemical cycle of phosphorus including its supply to sedimentary basins, precipitation from sea water, distribution and speciation in bottom sediments, diagenetic redistribution, and relation to other elements are under consideration. Formation of recent phosphorites as a culmination of phosphate accumulation in marine and oceanic sediments is examined. Distribution, structure, mineral and chemical compositions of major phosphorite deposits of various age on continental margins, as well as on submarine plateaus, uplifts and seamounts and some islands are described. A summary of trace element abundances in oceanic phosphorites is presented. Problems of phosphorite origin are discussed.

(Supplementary Table 1) Proportions of methane (C1) to ethane (C2) and the stable isotope composition of methane (d13CCH4) of gas and oil collected by gas bubble sampler during cruise M 114 in the southern Gulf of Mexico

Hydrocarbon seepage is a widespread process at the continental margins of the Gulf of Mexico. We used a multidisciplinary approach, including multibeam mapping and visual seafloor observations with different underwater vehicles to study the extent and character of complex hydrocarbon seepage in the Bay of Campeche, southern Gulf of Mexico. Our observations showed that seafloor asphalt deposits previously only known from the Chapopote Knoll also occur at numerous other knolls and ridges in water depths from 1230 to 3150 m. In particular the deeper sites (Chapopopte and Mictlan knolls) were characterized by asphalt deposits accompanied by extrusion of liquid oil in form of whips or sheets, and in some places (Tsanyao Yang, Mictlan, and Chapopote knolls) by gas emission and the presence of gas hydrates in addition. Molecular and stable carbon isotopic compositions of gaseous hydrocarbons suggest their primarily thermogenic origin. Relatively fresh asphalt structures were settled by chemosynthetic communities including bacterial mats and vestimentiferan tube worms, whereas older flows appeared largely inert and devoid of corals and anemones at the deep sites. The gas hydrates at Tsanyao Yang and Mictlan Knolls were covered by a 5-to-10 cm-thick reaction zone composed of authigenic carbonates, detritus, and microbial mats, and were densely colonized by 1-2 m-long tube worms, bivalves, snails, and shrimps. This study increased knowledge on the occurrences and dimensions of asphalt fields and associated gas hydrates at the Campeche Knolls. The extent of all discovered seepage structure areas indicates that emission of complex hydrocarbons is a widespread, thus important feature of the southern Gulf of Mexico.