Sea surface temperature reconstruction of ODP Site 175-1087

Successful application of the alkenone palaeothermometer, the UK'37 index, relies upon the assumption that fossil alkenone synthesisers responded to growth-temperature changes in a similar manner to the modern producers, chiefly the coccolithophores Emiliania huxleyi and Gephyrocapsa oceanica. We compare coccolith and UK'37 data from ODP Site 1087 in the south-east Atlantic between 1500 and 500 ka, and show that evolutionary events and changes in species dominance within the coccolithophore populations had little impact on the UK'37 record. The relative abundances of the C37 and C38 alkenones also closely resembled those found in modern populations, and suggest a similar temperature sensitivity of UK'37 during the early and mid-Pleistocene to that found at present. These results support the application of the UK'37 index to reconstruct sea-surface temperatures (SSTs) throughout the Quaternary. The UK'37 record at ODP Site 1087 contains an SST signal that documents the emergence of the 100-kyr cycles that characterise the late Quaternary ice volume records. This is preceded by significant cooling at ODP Site 1087, marked by a negative shift in SSTs and a positive shift in the planktonic delta18O some 250-kyr earlier, at ca 1150-1000 ka. This results in a permanent fall in average SSTs of around 1.5 °C. The predicted increase in aridity onshore as a result of this cooling can be identified in a number of published records from southern Africa, and may have played a role in some important evolutionary events of the mid-Pleistocene.

Sea surface temperature record of ODP Site 202-1233

We present the first high-resolution alkenone-derived sea surface temperature (SST) reconstruction in the southeast Pacific (Ocean Drilling Program Site 1233) covering the major part of the last glacial period and the Holocene. The record shows a clear millennial-scale pattern that is very similar to climate fluctuations observed in Antarctic ice cores, suggesting that the Southern Hemisphere high-latitude climate changes extended into the midlatitudes, involving simultaneous changes in air temperatures over Antarctica, sea ice extent, extension of the Antarctic Circumpolar Current, and westerly atmospheric circulation. A comparison to other midlatitude surface ocean records suggests that this "Antarctic" millennial-scale pattern was probably a hemisphere-wide phenomenon. In addition, we performed SST gradient reconstructions over the complete latitudinal range of the Pacific Eastern Boundary Current System for different time intervals during the last 70 kyr. The main results suggest an equatorward displaced subtropical gyre circulation during marine isotope stages 2 and 4.

(Table 2) Abundance and biomass of zooplankton in the eastern Black Sea in the beginning of September 1996

On the basis of analyses of samples collected in the eastern Black Sea in September 1996 trends of increase in surface zooplankton biomass and general decrease in Mnemiopsis biomass were revealed.

Alkenone-derived UK'37 data and sea surface temperatures (SST) of sediment cores from the Gulf of Taranto (Italy)

Auxiliary data include one file with alkenone-derived UK'37 data and sea surface temperatures (SST). On these data Figs. 7 and 8 of the manuscript are based. The SST are derived from UK'37 by using the transfer function: SST = 29.876 UK'37 - 1.334 of Conte et al. (2006). The data are against the ages (in A.D.) of samples derived from cores GT91-1 (39[deg]59'23"N, 17[deg]45'25"E), GT89-3 and GT90-3 (both 39[deg]45'43"N, 17[deg]53'55"E ). Also included are composite records for UK'37 and SST. For creating the composite records, GT-89-3 was taken as reference core. In the overlapping period the GT89-3 data seem in general lower than the GT91-1 data. To accommodate for this in the composite record, the average difference (0.0343 UK'37 units; equivalent to 1.023 [deg]C) was subtracted from the GT91-1 record. Hereafter, for each depth in the overlapping interval the respective values (UK'37 or SST) of GT89-3 and GT91-1 were averaged. We have also averaged with 16 additional alkenone measurements, from 1793 to 1851, performed in the GT90-3 core.

Sea-surface temperature reconstruction of sediments from the North Pacific and North Atlantic

Holocene climate variability is investigated in the North Pacific and North Atlantic realms, using alkenone-derived sea-surface temperature (SST) records as well as a millennial scale simulation with a coupled atmosphere-ocean general circulation model (AOGCM). The alkenone SST data indicate a temperature increase over almost the entire North Pacific from 7 cal kyr BP to the present. A dipole pattern with a continuous cooling in the northeastern Atlantic and a warming in the eastern Mediterranean Sea and the northern Red Sea is detected in the North Atlantic realm. Similarly, SST variations are opposite in sign between the northeastern Pacific and the northeastern Atlantic. A 2300 year long AOGCM climate simulation reveals a similar SST seesaw between the northeastern Pacific and the northeastern Atlantic on centennial time scales. Our analysis of the alkenone SST data and the model results suggests fundamental inter-oceanic teleconnections during the Holocene.

Age model and sediment description of DSDP Hole 90-594, Chatham Ridge east of New Zealand

Detailed sedimentological investigations were performed on sediments from DSDP-Site 594 (Chatham Rise, east of New Zealand) in order to reconstruct the evolution of paleoclimate and paleoceanographic conditions in the Southwest Pacific during the last 6 million years. The results can be summarized as follows: (1) High accumulation rates of biogenic opal and carbonate and the dominance of smectites in the clay fraction suggest increased oceanic productivity and an equable dominantly humid climate during the late Miocene. (2) During Pliocene times, decreasing contents of smectites and increasing feldspar/quartz ratios point to an aridification in the source area of the terrigenous sediments, culmunating near 2.5 Ma. At that time, accumulation rates of terrigenous components distinctly increased probably caused by increased sediment supply due to intensified atmospheric and oceanic circulation, lowered sea level, and decreased vegetation cover. (3) A hiatus (1.45 to 0.73 Ma) suggests intensified intermediate-water circulation. (4) Major glacial/interglacial cycles characterize the upper 0.73 Ma. During glacial times, oceanic productivity and terrigenous sediment supply was distinctly increased because of intensified atmospheric and oceanic circulations and lowered sea level, whereas during interglacials productivity and terrigenous sediment supply were reduced. (5) An increased content of amphibols in the sediments of Site 594 indicates increased volcanic activities during the last 4.25 Ma.

(Table 2) Abundance and biomass of zooplankton in the eastern Black Sea in the beginning of September 1996

On the basis of analyses of samples collected in the eastern Black Sea in September 1996 trends of increase in surface zooplankton biomass and general decrease in Mnemiopsis biomass were revealed.

Sea-surface temperature reconstruction of sediment core JT96-09PC

Changes of sea surface temperature (SST) in the subarctic NE Pacific over the last 16,000 calendar years before present (16 kyr BP) have been inferred from the study of C37 alkenone unsaturation in a sediment core from the western Canadian continental slope. Between 16.0 and 11.0 kyr, three distinct cold phases (6-7°C) interrupt two warmer periods (9-10°C). Within the 2sigma range of the radiocarbon based time control, the observed SST oscillations correspond to the Oldest Dryas, the Bolling, the Older Dryas, the Allered, and the Younger Dryas periods in the GISP2 d180 record. These results represent the first high resolution marine paleotemperature estimates off the northern West coast of North America and imply that the climate of this region may be very strongly coupled to that of the North Atlantic. Given the fast rates of SST change (1°C/40-80 yr), such coupling must be controlled by atmospheric transmission of the climate signal.

Sea surface temperature reconstruction of sediment profile W8709A-8

Assessment of changes in surface ocean conditions, in particular, sea-surface temperature (SST), is essential to understand long-term changes in climate especially in regions where continental climate is strongly influenced by oceanographic processes. To evaluate changes in SST in the northeast Pacific, we have analyzed long-chain alkenones of prymnesiophyte origin at 38 depths in a piston and associated trigger core collected beneath the contemporary core of the California Current System at 42°N, ~270 km off the coast of Oregon/California. The samples span 30,000 years of deposition at this location. Unsaturation patterns (UK'37) in the alkenone series display a statistically significant difference (p <<0.001) between interglacial (0.44 ± 0.02, n = 11) and glacial (0.29 ± 0.04, n = 20) intervals of the cores. Detailed examination of other compositional features of the C37, C38, C39 alkenone series and a related C36 alkenoate series measured downcore suggests the published UK'37 - temperature calibration (UK'37 = 0.034 * T + 0.039 ) , defined for cultures of a strain of Emiliania huxleyi isolated from the subarctic Pacific, provides best estimates of winter SST at our study site. This inference is purely statistical and does not imply, however, that the phytoplankton source of these biomarkers is most productive in winter or at the ocean surface. The temperature record for UK'37 implies (1) an ~4°C shift occurred in winter SST from ~7.5 ± 1.1°C at the last glacial maximum to ~11.7 ± 0.7°C in the present interglacial period, and (2) this warming trend was confined to the time frame 14-10 Ka within the glacial to interglacial transition period. These conclusions are corroborated entirely by results from an independent SST transformation of radiolarian species assemblage data obtained from the same core materials.

Carbon sources in the North Sea evaluated by means of carbon isotope tracers

A multitracer approach is applied to assess the impact of boundary fluxes (e.g., benthic input from sedi- ments or lateral inputs from the coastline) on the acid-base buffering capacity, and overall biogeochemistry, of the North Sea. Analyses of both basin-wide observations in the North Sea and transects through tidal basins at the North-Frisian coastline, reveal that surface distributions of the d13C signature of dissolved inorganic carbon (DIC) are predominantly controlled by a balance between biological production and respiration. In particular, variability in metabolic DIC throughout stations in the well-mixed southern North Sea indi- cates the presence of an external carbon source, which is traced to the European continental coastline using naturally occurring radium isotopes (224Ra and 228Ra). 228Ra is also shown to be a highly effective tracer of North Sea total alkalinity (AT) compared to the more conventional use of salinity. Coastal inputs of meta- bolic DIC and AT are calculated on a basin-wide scale, and ratios of these inputs suggest denitrification as a primary metabolic pathway for their formation. The AT input paralleling the metabolic DIC release prevents a significant decline in pH as compared to aerobic (i.e., unbuffered) release of metabolic DIC. Finally, long- term pH trends mimic those of riverine nitrate loading, highlighting the importance of coastal AT production via denitrification in regulating pH in the southern North Sea.

Concentration of hydrogen sulfide in waters of the Black Sea in the layer of its coexistence with oxygen

About 100 parallel determinations of hydrogen sulfide by the volumetric and photometric methods were made in the layer of coexistence of oxygen with hydrogen sulfide (C layer). Thiosulfates were determined simultaneously. Regardless of locations of the stations, determinations by two methods coincided for the entire range of depths of occurrence of the C layer upper boundary. Within the C layer hydrogen sulfide readings obtained by these two independent methods agreed; thiosulfates were not found by direct measurements. Difference in the readings appears at the lower boundary of the C layer and below it, accompanied by appearance of thiosulfates. It is therefore concluded that it is correct to determine the upper boundary of the C layer by the iodometric method and to use concentration of hydrogen sulfide obtained by this method in the C layer to calculate rate of chemical oxidation of hydrogen sulfide in quasistationary processes.