Rare earth element contents and sources in phosphorites from Pacific seamounts

Distribution of rare earth elements (REE) was studied in phosphorites collected from seamounts at depths from about 400 to 3600 m. In general phosphorites are characterized by high REE con¬tent, by a strong negative Ce anomaly, by a slight positive Gd anomaly, and by slight enrichment in heavy REE, which is also characteristic of seawater, where, to certain extent, composition of REE depends on depth. Comparison of REE composition in phosphorites and in seawater from the Northwest Pacific by means of Q-mode factor analysis revealed that REE have been transported into the phosphorites from various water depths following submergence of the seamounts. This corresponds to paleotectonic reconstructions, but is only partially consistent with age determinations of phosphorites.

Halogene concentrations and iodine isotopic composition in pore water on Hydrare Ridge, Cascadia continental margin

We report iodine and bromine concentrations in a total of 256 pore water samples collected from all nine sites of Ocean Drilling Program Leg 204, Hydrate Ridge. In a subset of these samples, we also determined iodine ages in the fluids using the cosmogenic isotope 129I (T1/2 = 15.7 Ma). The presence of this cosmogenic isotope, combined with the strong association of iodine with methane, allows the identification of the organic source material responsible for iodine and methane in gas hydrates. In all cores, iodine concentrations were found to increase strongly with depth from values close to that of seawater (0.0004 mM) to concentrations >0.5 mM. Several of the cores taken from the northwest flank of the southern summit show a pronounced maximum in iodine concentrations at depths between 100 and 150 meters below seafloor in the layer just above the bottom-simulating reflector. This maximum is especially visible at Site 1245, where concentrations reach values as high as 2.3 mM, but maxima are absent in the cores taken from the slope basin sites (Sites 1251 and 1252). Bromine concentrations follow similar trends, but enrichment factors for Br are only 4-8 times that of seawater (i.e., considerably lower than those for iodine). Iodine concentrations are sufficient to allow isotope determinations by accelerator mass spectrometry in individual pore water samples collected onboard (~5 mL). We report 129I/I ratios in a few samples from each core and a more complete profile for one flank site (Site 1245). All 129I/I ratios are below the marine input ratio (Ri = 1500x10**-15). The lowest values found at most sites are between 150 and 250x10**-15, which correspond to minimum ages between 40 and 55 Ma, respectively. These ages rule out derivation of most of the iodine (and, by association, of methane) from the sediments hosting the gas hydrates or from currently subducting sediments. The iodine maximum at Site 1245 is accompanied by an increase in 129I/I ratios, suggesting the presence of an additional source with an age younger than 10 Ma; there is indication that younger sources also contribute at other sites, but data coverage is not yet sufficient to allow a definitive identification of sources there. Likely sources for the older component are formations of early Eocene age close to the backstop in the overriding wedge, whereas the younger sources might be found in recent sediments underlying the current locations of the gas hydrates.

(Table 3) Geochemistry at DSDP Leg 79 Holes

Detailed mineralogical and geochemical studies were performed on samples from selected time intervals recovered during Leg 79 on the Mazagan Plateau. The uppermost Albian and Cenomanian sediments of Sites 545 and 547 can be correlated on the basis of mineralogy and geochemistry; these sediments illustrate differential settling processes and the existence of hot climates with alternating humid and dry seasons in the African coastal zone. The upper Aptian to Albian black shales of Site 545 point to an irregular alternation of tectonic activity and relaxation stages, allowing different behaviors in the reworking of soils, crystalline rocks, and sediments born in peri-marine basins. The barren lower Mesozoic reddish sediments and evaporitic series of Sites 546 and 547 are characterized by a strong physical erosion of sialic landscapes, without clear evidence of post-depositional metamorphic events. At Site 546 strong early diagenetic processes in a confined evaporitic environment affect both the mineralogy and the geochemistry of pre-Miocene rocks.

Planktonic foraminiferal (Globigerinoides ruber) Mg/Ca ratios and SSTs of sediment cores GeoB9501-4 and GeoB9501-5

Multidecadal variations in Atlantic sea surface temperatures (SST) influence the climate of the Northern Hemisphere. However, prior to the instrumental time period, information on multidecadal climate variability becomes limited, and there is a particular scarcity of sufficiently resolved SST reconstructions. Here, we present an eastern tropical North Atlantic reconstruction of SSTs based on foraminiferal (Globigerinoides ruber pink) Mg/Ca ratios that resolves multidecadal variability over the past 1700 years. Spectral power in the multidecadal band (50 to 70 years period) is significant over several time intervals suggesting that the Atlantic Multidecadal Oscillation (AMO) has been influencing local SST. Since our data exhibit high scatter the absence of multidecadal variability in the remaining record does not exclude the possibility that SST variations on this time scale might have been present without being detected in our data. Cooling by ~0.5 °C takes place between about AD 1250 and AD 1500; while this corresponds to the inception of the Little Ice Age (LIA), the end of the LIA is not reflected in our record and SST remains relatively low. This transition to cooler SSTs parallels the previously reconstructed shift in the North Atlantic Oscillation towards a low pre-20th century mean state and possibly reflects common solar forcing.