Major- and trace-elements at DSDP Legs 68-70 Holes

The basalts recovered from the Costa Rica Rift by drilling at Deep Sea Drilling Project Sites 501, 504, and 505 during Legs 68, 69 and 70 of the Glomar Challenger are the most depleted in the most-hygromagmaphile elements (Th, Ta, Nb, and La) of all MORB recovered to date by the Glomar Challenger. The invariant ratios Nb/Ta, Zr/Hf, and Y/Tb show "chondritic values" (expected for Nb/Ta because of the very low concentrations in these elements). Four samples from a single unit are exceptions: they present a flat to slightly enriched, extended Coryell-Masuda plot, and at the same time their La/Ta ratio is 9 (normalized ratio = 1) instead of 19 (normalized ratio = 2), the value for all other samples. Only one of these two values of the La/Ta ratio had been found so far within a single hole, and moreover within large areas of the oceanic crust (several holes or dredges). The present result shows that local heterogeneity of the upper mantle with respect to the La/Ta ratio may exist.

Clay and silica minerals of ODP Site 123-765

Sediments recovered from Site 765 can be divided into seven mineral associations, based on differences in clay mineralogy. These clay mineral associations correlate with the lithologic units and reflect the rift-to-drift history of the passive Australian margin. In general, the Lower to mid-Cretaceous sediments represent altered volcanic material and detrital aluminosilicates that were deposited during the early formation of the Argo Basin. The predominant clay mineral is randomly interstratified illite/smectite (I/S) that contains less than 10% illite layers. The transformation of smectite to illite is suggested by an increase in the percentage of illite layers in the basal sediments (from <10% to 40%) that corresponds to the silica transformation of opal-CT to quartz. This mixed-layered illite/smectite has an average composition of (K0.14 Na0.29 C0.07)(Al0.88 Mg0.43 Fe0.61 Ti0.06)(Si3.88 Al0.12)(O)10(OH)2. The highly smectitic composition of the I/S and its association with bentonite layers and zeolite minerals suggest that much of the I/S was derived from the alteration of volcanic material. The condensed middle to Upper Cretaceous sediments consist of palygorskite and detrital I/S that contains 30% to 60% illite layers. The condensed Paleogene sediments contain no palygorskite and are dominated by detrital clay minerals or by highly smectitic I/S associated with bentonite layers and zeolite minerals. The overlying, rapidly deposited Neogene clayey calcareous turbidites consist of three distinct clay mineral associations. Middle Miocene sediments contain palygorskite, kaolinite, and a tentatively identified mixed-layered illite/smectite/chlorite (I/S/C) or saponite. Upper Miocene sediments contain abundant sepiolite and kaolinite and lesser amounts of detrital I/S. Detrital I/S and kaolinite dominate the clay mineralogy of Pliocene and Pleistocene sediments. The fibrous, magnesium-rich clay minerals sepiolite and palygorskite appear to be authigenic and occur intimately associated with authigenic dolomite. The magnesium required to form these Mg-rich minerals was supplied by diffusion from the overlying seawater, and silica was supplied by the dissolution of associated biogenic silica.

Geochemical composition of bentonite layers and U-Pb ages of detrital zircons from the Paleogene Basilika Formation (Svalbard) and Mount Lawson Formation (Ellesmere Island)

Major and trace element composition as well as Sm-Nd isotopes of whole-rock samples and clay fractions (<2 µm) of bentonite layers and U-Pb ages of detrital zircons from the Paleogene Basilika Formation (Svalbard) and Mount Lawson Formation (Ellesmere Island).

Documentation of manganese nodules in some finish lakes

The paper gives a detailed study of the iron-manganese ores found in the lakes of Western Finland.

Investigations on seven sediment cores from the New Ireland Basin, east of Papua New Guinea

Sediment cores were recovered from the New Ireland Basin, east of Papua New Guinea, in order to investigate the late Quaternary eruptive history of the Tabar-Lihir-Tanga-Feni (TLTF) volcanic chain. Foraminifera d18O profiles were matched to the low-latitude oxygen isotope record to date the cores, which extend back to the early part of d18O Stage 9 (333 ka). Sedimentation rates decrease from >10 cm/1000 yr in cores near New Ireland to ~2 cm/1000 yr further offshore. The cores contain 36 discrete ash beds, mostly 1-8 cm thick and interpreted as either fallout or distal turbidite deposits. Most beds have compositionally homogeneous glass shard populations, indicating that they represent single volcanic events. Shards from all ash beds have the subduction-related pattern of strong enrichment in the large-ion lithophile elements relative to MORB, but three distinct compositional groups are apparent: Group A beds are shoshonitic and characterised by >1300 ppm Sr, high Ce/Yb and high Nb/Yb relative to MORB, Group B beds form a high-K series with MORB-like Nb/Yb but high Ce/Yb and well-developed negative Eu anomalies, whereas Group C beds are transitional between the low-K and medium-K series and characterised by flat chondrite-normalised REE patterns with low Nb/Yb relative to MORB. A comparison with published data from the TLTF chain, the New Britain volcanic arc and backarc including Rabaul, and Bagana on Bougainville demonstrates that only Group A beds share the distinctive phenocryst assemblage and shoshonitic geochemistry of the TLTF lavas. The crystal- and lithic-rich character of the Group A beds point to a nearby source, and their high Sr, Ce/Yb and Nb/Yb match those of Tanga and Feni lavas. A youthful stratocone on the eastern side of Babase Island in the Feni group is the most probable source. Group A beds younger than 20 ka are more fractionated than the older Group A beds, and record the progressive development of a shallow level magma chamber beneath the cone. In contrast, Group B beds represent glass-rich fallout from voluminous eruptions at Rabaul, whereas Group C beds represent distal glass-rich fallout from elsewhere along the volcanic front of the New Britain arc.