Granulometry, mineralogy and organic matter content of permafrost core 5011-3

The combination of permafrost history and dynamics, lake level changes and the tectonical framework is considered to play a crucial role for sediment delivery to El'gygytgyn Crater Lake, NE Russian Arctic. The purpose of this study is to propose a depositional framework based on analyses of the core strata from the lake margin and historical reconstructions from various studies at the site. A sedimentological program has been conducted using frozen core samples from the 141.5 m long El'gygytgyn 5011-3 permafrost well. The drill site is located in sedimentary permafrost west of the lake that partly fills the El'gygytgyn Crater. The total core sequence is interpreted as strata building up a progradational alluvial fan delta. Four macroscopically distinct sedimentary units are identified. Unit 1 (141.5-117.0 m) is comprised of ice-cemented, matrix-supported sandy gravel and intercalated sandy layers. Sandy layers represent sediments which rained out as particles in the deeper part of the water column under highly energetic conditions. Unit 2 (117.0-24.25 m) is dominated by ice-cemented, matrix-supported sandy gravel with individual gravel layers. Most of the Unit 2 diamicton is understood to result from alluvial wash and subsequent gravitational sliding of coarse-grained (sandy gravel) material on the basin slope. Unit 3 (24.25-8.5 m) has ice-cemented, matrix-supported sandy gravel that is interrupted by sand beds. These sandy beds are associated with flooding events and represent near-shore sandy shoals. Unit 4 (8.5-0.0 m) is ice-cemented, matrix-supported sandy gravel with varying ice content, mostly higher than below. It consists of slope material and creek fill deposits. The uppermost metre is the active layer (i.e. the top layer of soil with seasonal freeze and thaw) into which modern soil organic matter has been incorporated. The nature of the progradational sediment transport taking place from the western and northern crater margins may be related to the complementary occurrence of frequent turbiditic layers in the central lake basin, as is known from the lake sediment record. Slope processes such as gravitational sliding and sheet flooding occur especially during spring melt and promote mass wasting into the basin. Tectonics are inferred to have initiated the fan accumulation in the first place and possibly the off-centre displacement of the crater lake.

(Table 2) Chlorine geochemistry and mineralogy of altered oceanic crust samples

Bulk chlorine concentrations and chlorine stable isotope compositions were determined for hydrothermally altered basalt (extrusive lavas and sheeted dikes) and gabbro samples (n = 50) from seven DSDP/ODP/IODP drill sites. These altered oceanic crust (AOC) samples span a range of crustal ages, tectonic settings, alteration type, and crustal depth. Bulk chlorine concentrations range from < 0.01 wt.% to 0.09 wt.%. In general, higher chlorine concentrations coincide with an increase in temperature of alteration and amphibole content. d37Cl values of whole rock AOC samples range from -1.4 to +1.8 per mil. High d37Cl values (>=~0.5 per mil) are associated with areas of higher amphibole content. This observation is consistent with theoretical calculations that estimate amphibole should be enriched in 37Cl compared to co-existing fluid. Negative to near zero d37Cl values are found in areas dominated by clay minerals. Chlorine geochemistry is a rough indicator of metamorphic grade and mineralogy. AOC is a major Cl host in the subducting oceanic lithospheric slab. Here we show that bulk chlorine concentrations are ~3 times higher than previous estimates resulting in a greater contribution of Cl to the mantle.

Mineralogy of sediments at DSDP Leg 67 Hole

Seven sites were drilled during Leg 67 along a transect across the Middle America Trench off Guatemala: four (Sites 494, 496, 497, and 498) on continental slope, two (Sites 499 and 500) on Trench floor, and one (Site 495) on the Cocos Plate. We studied the mineralogy of sediments from Sites 494, 495, 496, 499, and 500. Our objective was to investigate the origin and source of separate minerals and mineral assemblages, giving special attention to the influence of the alteration of basalts on the sediment mineralogy, which we expected to be particularly important in layers just above oceanic basement.

Clay mineralogy of ODP Leg 178 sites

The clay mineral compositions of upper Miocene to Quaternary sediments recovered at Ocean Drilling Program (ODP) Leg 178, Sites 1095 and 1096, from the continental rise west of the Antarctic Peninsula were analyzed in order to reconstruct the Neogene and Quaternary Antarctic paleoclimate and ice dynamics. The clay mineral assemblages are dominated by smectite, illite, and chlorite. Kaolinite occurs only in trace amounts. Analysis of a surface-sample data set facilitates the assignment of these clay minerals to particular source areas on the Antarctic Peninsula and, thus, the reconstruction of transport pathways. In the ODP cores, clay mineral composition cyclically alternates between two end-member assemblages. One assemblage is characterized by <20% smectite and >40% chlorite. The other assemblage has >20% smectite and <40% chlorite. Illite fluctuates between 30% and 50% without a significant affinity to one end-member assemblage. By comparison with a Quaternary sediment sequence from gravity core PS1565, the clay mineral fluctuations can be ascribed to glacial and interglacial periods, respectively. The cyclic changes in the clay mineral composition suggest that glacial-interglacial cycles, repeated ice advances and retreats, and changes in the Antarctic ice volume were already a main control of the global climate in late Miocene time. Throughout the late Neogene and Quaternary, the clay mineral records in the drift sediments exhibit only slight long-term changes predominantly attributed to local changes in glacial erosion and supply of source rocks. The absence of clear long-term trends associated with major climatic or glaciological changes points to an onset of vast glaciation in the Antarctic Peninsula region before ~9 Ma and to relative stability of the Antarctic ice sheet since then.