Age determination and foraminiferal faunas in sediment core MD99-2275

A high-resolution study of palaeoceanographic changes off North Iceland during the time period 8600-5200 cal year BP is based on benthic and planktonic foraminiferal assemblages. The core material (MD99-2275) was obtained from about 440 m water depth on the eastern part of the North Icelandic shelf. Changes in the faunal composition are interpreted to be mainly caused by variations in the strength of the relatively warm, high-salinity Irminger Current and the cold East Icelandic Current, which have been shown to be linked to the climatic changes in the North Atlantic region. Environmental proxies at that site are particularly sensitive to palaeoceanographic changes due to its position close to the marine Polar Front. Benthic assemblages show that relatively cold conditions prevailed at the base of the record. An increase in the influence of Atlantic water masses at the sea floor is seen at around 8400 cal year BP, whereas the surface waters were relatively warm already at 8600 cal year BP. The warming was interrupted by a cold event at around 8100-8000 cal year BP, registered both in the bottom and surface waters and correlated with the so-called 8.2 kyr cooling event. Both the benthic and the planktonic faunal compositions indicate that the Irminger Current had maximum influence in the area between 8000 and about 7300 cal year BP, followed by a gradually decreasing influence through the remaining part of the studied time interval. It is suggested that the contribution of Atlantic water masses from the east and north-east to the Arctic Surface waters off North Iceland increased after around 7000 cal year BP, and that this was further intensified after 6200 cal year BP. At present, the Arctic Surface Water north of Iceland consists of Polar waters, intermittently with direct influence from the East Greenland Current, mixed with Atlantic waters derived from the eastern part of the Nordic Seas. A comparison of the mean values of selected environmental proxies in the interval 8600-5200 cal year BP with the upper part of the same core shows that the water masses north of Iceland were considerably warmer during the Holocene thermal maximum than during the last 2000 cal year. In general, results from core MD99-2275 are in accordance with other marine records from the North Icelandic shelf and the northern North Atlantic region, although a detailed comparison on a centennial time scale is hampered by problems with spatial as well as temporal changes in the marine reservoir ages in the region.

Minerals and geochemistry abundance and occurance, as well as K-Ar determinations for DSDP Site 92-597 basalts

Preliminary studies of hydrothermally altered massive basalts formed at the fast-spreading Mendoza Rise and recovered from DSDP Holes 597B and 597C indicate the presence of three secondary mineral assemblages which formed in the following order: (1) trioctahedral chlorite and talc, (2) goethite and smectite, and (3) calcite and celadonite. The sequential precipitation of these mineral assemblages denotes high water:rock ratios and time-varying conditions of temperature (early >200°C to late <30°C) and state of oxidation (early nonoxidative to late oxidative). A decrease in the relative proportion of oxidative mineral assemblages with depth to 70 m in Site 597 basement indicates a zone of oxidative alteration that became shallower with time as the deeper, more constricted fracture systems were filled by secondary mineralization. In this report we present the first results of the K-Ar dating of celadonite formation age; celadonite formation reflects end-stage hydrothermal alteration in Site 597 basement. Three celadonite dates obtained from Site 597 samples include 13.1 ± 0.3 m.y. from 17 m basement depth (Hole 597B), 19.9 ± 0.4 m.y. from 18 m basement depth (Hole 597C), and 19.3 ± 1.6 m.y. from 60 m basement depth (Hole 597C). The age of host rock crystallization (28.6 m.y.) and the K-Ar dates of celadonite formation establish that hydrothermal alteration in the upper 70 m of Site 597 basement continued for at least 10 m.y. and possibly as long as 16 m.y. after basalt crystallization at the ridge crest. Assuming a half-spreading rate of 55 km/m.y., we calculate that hydrothermal circulation was active in shallow basement at a distance of at least 550 km off ridge crest and possibly as far as 1000 km off ridge crest.

Nd isotope data for ODP Leg 208 holes

The flow of deep-water masses is a key component of heat transport in the modern climate system, yet the role of deep-ocean heat transport during periods of extreme warmth is poorly understood. The present mode of meridional overturning circulation is characterized by deep-water formation in both the North Atlantic and the Southern Ocean. However, a different mode of meridional overturning circulation operated during the extreme greenhouse warmth of the early Cenozoic, during which time the Southern Ocean was the dominant region of deep-water formation. The combination of general global cooling and tectonic evolution of the Atlantic basins over the past ~55 m.y. ultimately led to the development of a mode of overturning circulation characterized by both Southern Ocean and North Atlantic deep-water sources. The change in deep-water circulation mode may, in turn, have affected global climate; however, unraveling the causes and consequences of this transition requires a better understanding of the timing of the transition. New Nd isotope data from the southeastern Atlantic Ocean indicate that the initial transition to a bipolar mode of deep-water circulation occurred in the early Oligocene, ca. 33 Ma. The likely cause of significant deep-water production in the North Atlantic was tectonic deepening of the sill separating the Greenland-Norwegian Sea from the North Atlantic.

Physical properties and geochemistry at DSDP Leg 70 Holes

Ashes occurring both as distinct layers and mixed with pelagic sediments of the hydrothermal mounds lying south of the Galapagos Rift are mainly rhyolitic and basaltic. The ashes, of rhyolitic to intermediate composition, appear to belong to a calc-alkalic series and were probably derived from Plinian eruptions in Ecuador or Colombia. Basaltic ashes are made of nonvesicular sideromelane spalling shards and are of tholeiitic composition. They probably were derived locally from fault scarps. Most rhyolitic and basaltic glass shards studied are fresh except for hydration of the rhyolitic shards. Some shards are severely altered, however. Basaltic ash may be more common in pelagic sediments deposited near accretion zones and may be a source of silica and other elements released during diagenesis

Magnetic properties and incompatible element geochemistry of some igneous rocks at DSDP Leg 64 Holes

I received five unoriented samples of igneous rocks from four Sites of Leg 64 of the Deep Sea Drilling Project (DSDP). I have measured several magnetic properties, alkalis (K, Rb, and Cs), alkaline-earth (Ba and Sr) element concentrations, and 87Sr/86Sr ratios of these samples. This study reports the results.

Geochemical data derived from an absolutely dated shell-based chronology for the Irish Sea

The identification in various proxy records of periods of rapid (decadal scale) climate change over recent millennia, together with the possibility that feedback mechanisms may amplify climate system responses to increasing atmospheric CO2, highlights the importance of a detailed understanding, at high spatial and temporal resolutions, of forcings and feedbacks within the system. Such an understanding has hitherto been limited because the temperate marine environment has lacked an absolute timescale of the kind provided by tree-rings for the terrestrial environment and by corals for the tropical marine environment. Here we present the first annually resolved, multi-centennial (489-year), absolutely dated, shell-based marine master chronology. The chronology has been constructed by detrending and averaging annual growth increment widths in the shells of multiple specimens of the very long-lived bivalve mollusc Arctica islandica, collected from sites to the south and west of the Isle of Man in the Irish Sea. The strength of the common environmental signal expressed in the chronology is fully comparable with equivalent statistics for tree-ring chronologies. Analysis of the 14C signal in the shells shows no trend in the marine radiocarbon reservoir correction (DR), although it may be more variable before ~1750. The d13C signal shows a very significant (R**2 = 0.456, p < 0.0001) trend due to the 13C Suess effect.

Multi-proxy analyses of sediment core GeoB13801-2

Over the Uruguayan shelf and uppermost slope the coalescence of northward flowing Subantarctic Shelf Water and southward flowing Subtropical Shelf Water forms a distinct thermohaline front termed the Subtropical Shelf Front (STSF). Running in a SW direction diagonally across the shelf from the coastal waters at 32°S towards the shelf break at ca. 36°S, the STSF represents the shelf-ward extension of the Brazil-Malvinas Confluence zone. This study reconstructs latitudinal STSF shifts during the Holocene based on benthic foraminifera d18O and d13C, total organic carbon, carbonate contents, Ti/Ca, and grain-size distribution from a high-accumulation sedimentary record located at an uppermost continental-slope terrace. Our data provide direct evidence for: (1) a southern STSF position (to the South of the core site) at the beginning of the early Holocene (>9.4 cal ka BP) linked to a more southerly position of the Southern Westerly Winds in combination with restricted shelf circulation intensity due to lower sea level; (2) a gradual STSF northward migration (bypassing the core site towards the North) primarily forced by the northward migration of the Southern Westerly Winds from 9.4 cal ka BP onwards; (3) a relatively stable position of the front in the interval between 7.2 and 4.0 cal ka BP; (4) millennial-scale latitudinal oscillations close to 36°S of the STSF after 4.0 cal ka BP probably linked to the intensification in El Niño Southern Oscillation; and (5) a southward migration of the STSF during the last 200 years possibly linked to anthropogenic influences on the atmosphere.

Boron, carbonate carbon and oxygen isotope analyses of samples from the Yangtze Platform (China), Congo craton (Namibia), and Karatau microcontinent (Kazakhstan) of the Marinoan glaciation

Boron isotope patterns preserved in cap carbonates deposited in the aftermath of the younger Cryogenian (Marinoan, ca. 635 Ma) glaciation confirm a temporary ocean acidification event on the continental margin of the southern Congo craton, Namibia. To test the significance of this acidification event and reconstruct Earth's global seawater pH states at the Cryogenian-Ediacaran transition, we present a new boron isotope data set recorded in cap carbonates deposited on the Yangtze Platform in south China and on the Karatau microcontinent in Kazakhstan. Our compiled d11B data reveal similar ocean pH patterns for all investigated cratons and confirm the presence of a global and synchronous ocean acidification event during the Marinoan deglacial period, compatible with elevated postglacial pCO2 concentrations. Differences in the details of the ocean acidification event point to regional distinctions in the buffering capacity of Ediacaran seawater.

Geochemistry and ages at DSDP Hole 19-192A

Conventional K-Ar and 40Ar/39Ar age data on altered basalts from DSDP Hole 192A on Meiji Guyot, Emperor Seamount chain, indicate a minimum age for the volcano of 61.9 ± 5.0 m.y. The K-Ar data are consistent with the early Maestrichtian date of the overlying sediments, but do not provide either a positive or negative test of the hypothesis that Meiji is older than Emperor volcanoes to the south. The most prominent alteration affecting the age measurements is potassium metasomatism, particularly of feldspar phenocrysts. The K-Ar apparent ages of feldspar separates from the Meiji basalts show that more than half of the potassium metasomatism occurred within the last 25 m.y. or so, and that if the potassium replacement rate has been constant, then the alteration of the Meiji basalts did not begin for 10 to 20 m.y. after the volcano formed.

Sedimentary climate indicators of sediment core MD08-3167 and GeoB1711-4, southwestern Africa

The past climate evolution of southwestern Africa is poorly understood and interpretations of past hydrological changes are sometimes contradictory. Here we present a record of leaf-wax dD and View the MathML source taken from a marine sediment core at 23°S off the coast of Namibia to reconstruct the hydrology and C3 versus C4 vegetation of southwestern Africa over the last 140 000 years (140 ka). We find lower leaf-wax dD and higher View the MathML source (more C4 grasses), which we interpret to indicate wetter Southern Hemisphere (SH) summer conditions and increased seasonality, during SH insolation maxima relative to minima and during the last glacial period relative to the Holocene and the last interglacial period. Nonetheless, the dominance of C4 grasses throughout the record indicates that the wet season remained brief and that this region has remained semi-arid. Our data suggest that past precipitation increases were derived from the tropics rather than from the winter westerlies. Comparison with a record from the Congo Basin indicates that hydroclimate in southwestern Africa has evolved in antiphase with that of central Africa over the last 140 ka.

Geochemistry and K-Ar dates of the Mazagan granodiorite at V30-225, VA79-96KD and DSDP Hole 79-544A, off Moroccan coast

Gneissic granodiorite was recovered by drilling at the base of the Mazagan escarpment, 100 km west of the Casablanca, Morocco, at 4000 m water depth. Coarse, predeformative muscovite yielded dates of -515 Ma, fine-grained muscovite of -455 Ma, biotite -360 and 335 Ma, and feldspar -315 Ma. These dates are tentatively correlated with the microscopic results. We assume a minimum age of middle Cambrian for the granodiorite, an Ordovician deformation and mylonitization, and a Late Carboniferous overprint under upper greenschist facies conditions.

Hydrological and meteorological records from the Vernagtferner Basin - Vernagtbach station, for the years 2002 to 2012

In November 2001, two separate Campbell loggers ("Meteologger" and "Hydrologger", both type CR23X) were installed at the Vernagtbach site in the Oetztal Alps, Austria (Latitude: 46.85; Longitude: 10.82; Elevation: 2640 m). On these loggers, 10-minutes centred averages for the meteorological data and 5-minutes centred averages for the hydrological data are recorded. The meteorological parameters comprise air temperature, humidity of the air, air pressure, four radiation components, wind direction and speed, precipitation and snow height. For air temperature, two records are published, recorded with a ventilated and an unventilated Pt-100 in a Stevenson screen; for precipitation, three time series are available: (I) the cumulative record of a weighing gauge for the whole year, (II) single events derived from (I), and (III) single events from a tipping bucket; (II) and (III) are only provided for the period 1, May to 31, October of each year. Wind records are also given with a time step of one hour, as only these records include several statistics of speed and direction. Hydrological parameters are recorded on the "Hydrologger", they comprise water stage, discharge, water temperature and electrolytic conductivity of the water. An identifying number gives the kind of instrument used in the water stage time series. Daily photographs of the glacier are provided and analysed with respect to precipitation type.

Mineral composition of mid-ocean-ridge basalts from ODP Leg 187 sites

The chemical compositions of olivine, plagioclase, pyroxene, and spinel in lavas collected during Ocean Drilling Program Leg 187 in the Australian Antarctic Discordance, Southeast Indian Ridge (41°-46°S, 126°-135°E) were analyzed, and modeling of the theoretical equilibrium petrogenetic conditions between olivine and melt was conducted. The cores of larger olivine phenocrysts, particularly in the isotopic Indian-type mid-ocean-ridge basalt (MORB), are not equilibrated with melt compositions and are considered to be xenocrystic. Larger plagioclase phenocrysts with compositionally reversed zonation are also xenocrystic. The compositions of primary magma were calculated using a "maximum olivine fractionation" model for primitive MORB that should fractionate only olivine. Olivine compositions equilibrated with calculated primary magma and compositions of calculated primary magma suggest that (1) isotopic Pacific-type MORB is more fractionated than Indian-type MORB, (2) Pacific-type MORB was produced by higher degrees of partial melting than Indian-type MORB, and (3) primary magma for Indian-type MORB was segregated from mantle at 10 kbar (~30 km depth), whereas that for Pacific-type MORB was segregated at 15 kbar (~45 km depth).

Element stratigraphy across the Cretaceous-Tertiary boundary in ODP Hole 119-738C

Neutron activation analyses of iridium and other chemical elements were performed across a 1-m-thick, partly nonbioturbated, clay-rich interval at the Cretaceous/Tertiary boundary in ODP Hole 738C. The results show that the boundary interval holds one of the highest Ir enrichments (320 ng Ir/cm2) of all known Cretaceous/Tertiary boundary layers. Iridium concentrations are highest (18 ppb Ir, whole-rock samples) a few centimeters above the base of the clayrich interval and gradually tail off upsection. Compared with background levels the most Ir-rich interval also shows strongly enhanced concentrations of Cr (215 ppm) and slightly elevated Co concentrations (13 ppm). The Ir-rich interval shows low As (< 15 ppm) and Sb (<0.8 ppm) concentrations, a fact that is congruent with absence of abundant authigenic sulfides in the sediment. Irregularly distributed Fe enrichments and a greenish gray color of the Fe-rich intervals may indicate the presence of glauconitic clay minerals and suboxic, slightly reducing conditions during deposition. Rare earth element (REE) abundance patterns change considerably across the Cretaceous/Tertiary boundary interval, reflecting either a change in Cretaceous/Tertiary boundary seawater REE composition or the occurrence of different REE fractionation processes due to changing depositional environment. Element-vs.-element ratios of Hf, Ta, Th, U, Cs, and Sc are similar between the most Ir-rich layers of the boundary section and other levels with lower Ir concentrations. This may imply that the clay fraction of the Ir-rich layers of the Cretaceous/Tertiary boundary interval is made up predominantly of locally derived material. Calculated calcite-free abundances of Hf, Ta, Th, U, Cs, and Sc, on the other hand, are reconcilable with an extraneous origin of the bulk of the clay in the most Ir-rich layers. The Ir in the Cretaceous/Tertiary boundary clay-rich zone in Hole 738C is most likely derived from an earth-impacting asteroid; however, the origin of the clay-rich zone remains enigmatic.

Sr/Ca ratios and oxygen isotopes from sclerosponges

We investigate aragonitic skeletons of the Caribbean sclerosponge Ceratoporella nicholsoni from Jamaica, 20 m below sea level (mbsl), and Pedro Bank, 125 mbsl. We use d18O and Sr/Ca ratios as temperature proxies to reconstruct the Caribbean mixed layer and thermocline temperature history since 1400 A.D. with a decadal time resolution. Our age models are based on U/Th dating and locating of the radiocarbon bomb spike. The modern temperature difference between the two sites is used to tentatively calibrate the C. nicholsoni Sr/Ca thermometer. The resulting calibration points to a temperature sensitivity of Sr/Ca in C. nicholsoni aragonite of about -0.1 mmol/mol/K. Our Sr/Ca records reveal a pronounced warming from the early 19th to the late 20th century, both at 20 and 125 mbsl. Two temperature minima in the shallow water record during the late 17th and early 19th century correspond to the Maunder and Dalton sunspot minima, respectively. Another major cooling occurred in the late 16th century and is not correlatable with a sunspot minimum. The temperature contrast between the two sites decreased from the 14th century to a minimum in the late 17th century and subsequently increased to modern values in the early 19th century. This is interpreted as a long-term deepening and subsequent shoaling of the Caribbean thermocline. The major trends of the Sr/Ca records are reproduced in both specimens but hardly reflected in the d18O records.